COMPOSITION DESIGN OF Ni–Nb–(Zr, Ta, Ag) TERNARY BULK METALLIC GLASSES BASED ON CLUSTER FORMULA OF Ni–Nb EUTECTIC

doi:10.3724/SP.J.1037.2011.00074

Acta Metall Sin

2011, Vol. 47

Issue (8): 1003-1008 DOI: 10.3724/SP.J.1037.2011.00074

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COMPOSITION DESIGN OF Ni–Nb–(Zr, Ta, Ag) TERNARY BULK METALLIC GLASSES BASED ON CLUSTER FORMULA OF Ni–Nb EUTECTIC

YUAN Liang, QIANG Jianbing, PANG Chang, WANG Yinmin, WANG Qing, DONG Chuang

Key Laboratory of Materials Modification (Dalian University of Technology), Ministry of Education, Dalian 116024

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YUAN Liang QIANG Jianbing PANG Chang WANG Yinmin WANG Qing DONG Chuang. COMPOSITION DESIGN OF Ni–Nb–(Zr, Ta, Ag) TERNARY BULK METALLIC GLASSES BASED ON CLUSTER FORMULA OF Ni–Nb EUTECTIC. Acta Metall Sin, 2011, 47(8): 1003-1008.

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Abstract A cluster–plus–glue atom model was employed to design Ni–Nb based ternary bulk metallic glasses. The binary eutectic point Ni_59.5Nb_40.5 was first interpreted by the model in form of a cluster formula [(Ni_0.5Nb_0.5)–Ni₆Nb₆]Ni₃, where the cluster is (Ni_0.5Nb_0.5)–centered icosahedron derived from a eutectic phase Ni₆Nb₇ (Fe₇W₆ type). It was then pointed out that the best binary glass former Ni₆₂Nb₃₈ could be interpreted based on the eutectic cluster formula by replacing the cluster center Nb_0.5 with Ni_0.5, namely [Ni–Ni₆Nb₆]Ni₃=Ni_62.5Nb_37.5. To further improve the glass–forming ability, Zr, Ta and Ag are selected as alloying additions to partially replace Nb in the [Ni–Ni6Nb6]Ni3 cluster formula, and glassy rods with a critical size of 3 mm are achieved at appropriate ternary compositions by copper–mould suction–casting. DTA measurements indicate these bulk metallic glasses exhibit high thermal stabilities, among which the [Ni–Ni₆Nb₅Ta]Ni₃ alloy has the highest T_g (glass transition temperature)of 935 K and T_x (crystallization temperature) of 952 K. Room–temperature compressive curves of [Ni–Ni₆Nb₅Zr]Ni₃ and [Ni–Ni₆Nb₅Ta]Ni₃ alloys show they have limited plasticity with a elongation of about 0.3%, fracture strength of the [Ni–Ni₆Nb₅Zr]Ni₃ and [Ni–Ni₆Nb₅Ta]Ni₃ BMGs are about 3.2 GPa and 3.4 GPa, respectively.

Key words: Ni–Nb-based bulk metallic glasses composition design cluster–plus–glue atom model

Received: 14 February 2011

ZTFLH:

TG139.8

Fund:

Supported by National Science Foundation of China (Nos.50901012 and 51041011), National Basic Research Program of China (No.2007CB613902) and Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (No.707015)

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	YUAN Liang
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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2011.00074 OR https://www.ams.org.cn/EN/Y2011/V47/I8/1003

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