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Acta Metall Sin  1990, Vol. 26 Issue (1): 153-154    DOI:
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OXIDATION OF Ti IN MOLTEN Cu UNDER WATERY ATMOSPHERE
XUE Xiangxin;DU Hegui Northeast University of Technology; Shenyang Department of Ferrous Metallurgy;Northeast University of Technology;Shenyang;110006
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XUE Xiangxin;DU Hegui Northeast University of Technology; Shenyang Department of Ferrous Metallurgy;Northeast University of Technology;Shenyang;110006. OXIDATION OF Ti IN MOLTEN Cu UNDER WATERY ATMOSPHERE. Acta Metall Sin, 1990, 26(1): 153-154.

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Abstract  An experimental study has been made of the oxidation of Ti in molten Cu-Tialloy under watery atmosphere at 1500℃. The results may be expressed as follows: [Ti]_(Cu)=0.92-0.69t 0≤t≤1.0 (h) [Ti]_(Cu)=0.02t~2-0.14t+0.35 1.0≤t≤6.0 (h) The apparent rate and orders of related reaction are: -d[Ti]_(Cu)/dt=0.69, pseudo-zeroth order, k=0.69 -d[Ti]_(Cu)/dt=0.14-0.04t, pseudo-0.85 order, k=0.39 The apparent mass transfer coefficient k'_(Ti)=0.16cm/h, and the relation of W~2 vs time: W~2=1.04×10~(-4)t
Key words:  Cu-Ti alloy      apparent mass transfer      oxidation     
Received:  18 January 1990     
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