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Acta Metall Sin  1993, Vol. 29 Issue (10): 76-81    DOI:
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INFLUENCE OF INTERSTITIAL CARBON ATOMS ON FORMATION, STRUCTURE AND MAGNETIC PROPERTIES OF (Er_(1-x)Sm_x)_2Fe_(17)C_y COMPOUNDS
SHEN Baogen;KONG Linshu;CAO Lei;WANG Fangwei;ZHAN Wenshan;GUO Huiqun;ZHAO Jiangao State Key Laboratory of Magnetism; Institute of Physics; Academia Sinica
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SHEN Baogen;KONG Linshu;CAO Lei;WANG Fangwei;ZHAN Wenshan;GUO Huiqun;ZHAO Jiangao State Key Laboratory of Magnetism; Institute of Physics; Academia Sinica. INFLUENCE OF INTERSTITIAL CARBON ATOMS ON FORMATION, STRUCTURE AND MAGNETIC PROPERTIES OF (Er_(1-x)Sm_x)_2Fe_(17)C_y COMPOUNDS. Acta Metall Sin, 1993, 29(10): 76-81.

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Abstract  The (Er_(1-x)Sm_x)_2Fe_(17)C_y(x=0.2, y≤3.0; x=0.5, y≤2.0) compounds with a2:17-type single phase structure were prepared by melt-spinning. The formation, structure,stability and intrinsic magnetic properties of these carbides were studied. The experimental re-sults show that these carbidek are stable at high temperatures. With increasing carbon concen-tration x, their crystal structure changes from the hexagonal Th_2Ni_17-type to rhombohedralTh_2Zn_(17)-type. The introduction of interstitial carbon atoms results in the expansion of theunit cell volumes and the increase of the room temperature saturation magnetization andCurie temperature. The (Er_(1-x)Sm_x)_2Fe_17C_y carbides with y≥1.0 are found to have an easyc-axis anisotropy at room temperature.
Key words:  (Er_(1-x)Sm_x)_2Fe_(17)C_y      interstitial carbides      magnetic properties      thermal stability     
Received:  18 October 1993     
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