Polyamorphic Transitions in Metallic Glasses

doi:10.11900/0412.1961.2020.00465

Acta Metall Sin

2021, Vol. 57

Issue (4): 491-500 DOI: 10.11900/0412.1961.2020.00465

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Polyamorphic Transitions in Metallic Glasses

ZENG Qiaoshi(

), YIN Ziliang, LOU Hongbo(

)

Center for High Pressure Science & Technology Advanced Research, Shanghai 201203, China

Cite this article:

ZENG Qiaoshi, YIN Ziliang, LOU Hongbo. Polyamorphic Transitions in Metallic Glasses. Acta Metall Sin, 2021, 57(4): 491-500.

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Abstract

Metallic glasses possess densely packed and disordered atomic structures linked by non-directional metallic bonds. Within these structures, the superior properties of conventional glasses and crystalline metals can be combined with excellent physical, chemical, and mechanical properties for widespread applications. Metallic glasses also offer a unique model system for fundamental studies on amorphous materials. For these reasons, they have attracted global interest. Phase-transition studies can deepen people's understanding of the atomic structures of materials and can realize materials with tunable properties. The polyamorphic transitions in conventional amorphous materials are not expected in metallic glasses because the latter are already densely packed. However, in situ high-pressure synchrotron X-ray probing techniques have recently detected polyamorphic transitions in metallic glasses. This new phenomenon, its underlying mechanism, and the related property changes have recently sparked much excitement. This paper reviews the recent progress in polyamorphic transitions in metallic glasses and the influence of such transitions on their atomic structure and properties.

Key words: metallic glass polyamorphic transition high-pressure technique synchrotron X-ray technique

Received: 18 November 2020

ZTFLH:

TG139.8

Fund: National Natural Science Foundation of China(51871054)

About author: LOU Hongbo, assistant professor, Tel: (021)80177132, E-mail: hongbo.lou@hpstar.ac.cn
ZENG Qiaoshi, professor, Tel: (021)80177102, E-mail: zengqs@hpstar.ac.cn

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	Qiaoshi ZENG
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https://www.ams.org.cn/EN/10.11900/0412.1961.2020.00465 OR https://www.ams.org.cn/EN/Y2021/V57/I4/491

Fig.1 Discontinuous changes of volume and bulk modulus as a function of pressure discovered in Ce-based metallic glasses

Fig.2 The volume change as a function of pressure determined by X-ray transmission microscopy (TXM) and XRD^[63]

Fig.3 The electronic structure origin of polyamorphic transition in the Ce₇₅Al₂₅ metallic glass^[74]

Fig.4 Differential structure factor (a) and differential pair distribution functions (PDFs) (b) of the La_43.4Pr_18.6Al₁₄Cu₂₄ metallic glass under different pressures (Q—momentum transfer, S(Q)—structure factor, r—distance)^[95]

Fig.5 Relative resistance of the Yb_62.5Zn₁₅Mg_17.5Cu₅ metallic glass as a function of pressure (The inset shows the microphotograph of the sample with four Pt electrodes in chamber between two anvils at about 5 GPa conditions. R_p—resistance at high pressure, R₀—resistance at 0 GPa, LDAS—low-density amorphous state, HDAS—high-density amorphous state)^[102]

Fig.6 Bulk modulus (a), shear modulus (b), Poisson's ratio (c), and Young's modulus (d) of the Ce₆₈Al₁₀-Cu₂₀Co₂ metallic glass as a function of pressure (Arrows indicate the critical pressures of the polyamorphic transition)^[80]

Fig.7 Crystallization onset temperatures (T_x)of Ce₇₅Al₂₅ and La₇₅Al₂₅ metallic glasses as functions of pressure^[104]

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