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Acta Metall Sin  2018, Vol. 54 Issue (10): 1343-1349    DOI: 10.11900/0412.1961.2017.00522
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Hydrogen-Induced Cracking Resistance of Novel Cu-Bearing Pipeline Steels
Xianbo SHI, Wei YAN, Wei WANG, Yiyin SHAN, Ke YANG()
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
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Xianbo SHI, Wei YAN, Wei WANG, Yiyin SHAN, Ke YANG. Hydrogen-Induced Cracking Resistance of Novel Cu-Bearing Pipeline Steels. Acta Metall Sin, 2018, 54(10): 1343-1349.

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Abstract  

Hydrogen-induced cracking (HIC) resistance of pipeline steels is one of the most important properties for sour gas service pipelines. For the conventional pipeline steels, the strength level mainly depends on the Mn content. However, as the Mn content increases, the unfavorable microstructures such as large size martensite/austenite (M/A) islands, bainite or martensite will be generated, which will deteriorate the HIC resistance of the steels. Therefore, it is hard to simultaneously improve strength level and HIC resistance for pipeline steel. The nature of HIC in pipeline steel is hydrogen embrittlement, which is essentially the redistribution of H atoms into the matrix of steel. So, how to make the distribution of H atoms in the steel as evenly as possible without causing local enrichment is a key factor to improve the HIC of pipeline steels. In this work, the susceptibilities of HIC of traditional X80 and novel Cu-bearing pipeline steels were studied with comparison. The results showed that the X80 pipeline steel behaved bad HIC resistance. The hydrogen-induced cracks mainly expanded along the interface between M/A islands and the matrix. However, the novel Cu-bearing pipeline steels with different Cu contents exhibited excellent HIC resistance, showing no cracks were produced after HIC test. It was analyzed that nano-sized Cu-rich precipitates in the Cu-bearing pipeline steels are speculated to act as the beneficial hydrogen traps, and these uniformly dispersed fine Cu-rich phases in matrix provide many sites for the distribution of H atoms, which helps to avoid the localized high concentration H atoms enrichment leading to hydrogen embrittlement. Taking nano-sized Cu-rich phases as a type of beneficial hydrogen traps provides a new way for the development of new pipeline steels with high strength and excellent HIC resistance.

Key words:  pipeline steel      Cu      hydrogen-induced cracking      Cu-rich phase      hydrogen trap     
Received:  06 December 2017     
ZTFLH:  TG142.1  
Fund: Supported by Shenyang Science and Technology Research Funding (No.18-013-0-53)

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2017.00522     OR     https://www.ams.org.cn/EN/Y2018/V54/I10/1343

Steel C Si Mn Mo Cu Ni Cr S P Nb+V+Ti Fe
1.0Cu 0.031 0.14 1.09 0.31 1.06 0.32 0.32 0.0011 0.005 0.05 Bal.
1.5Cu 0.019 0.12 1.03 0.31 1.46 0.31 0.31 0.0011 0.005 0.05 Bal.
2.0Cu 0.023 0.13 1.06 0.30 2.00 0.30 0.30 0.0010 0.005 0.05 Bal.
X80 0.046 0.10 1.68 0.19 0.30 0.20 0.29 0.0013 0.005 0.12 Bal.
Table 1  Chemical compositions of the experimental steels (mass fraction / %)
Fig.1  Schematic of specimen for hydrogen-induced cracking (HIC) test and the faces to be examined (unit: mm)
Fig.2  Corrosion morphologies of X80 steel (a), as-aged 1.0Cu steel (b), as-rolled 1.5Cu steel (c), as-aged 1.5Cu steel (d) and as-aged 2.0Cu steel (e), and SEM images of X80 steel (f) and as-aged 2.0Cu steel (g)
Fig.3  OM images of HIC in X80 steel (a) and near the surface of X80 steel (b)
Fig.4  Hydrogen-induced crack propagation paths in 1.0Cu (a) and X80 (b) steels (Arrows in Fig.4b show cracks expanded along the interface between martensite/austenite (M/A) islands and the matrix)
Fig.5  SEM (a, b) and OM (c, d) images show the microstructures of M/A islands in X80 steel (a, c) and 1.0Cu steel (b, d)
Fig.6  TEM images of as-rolled 1.5Cu steel (a) and as-aged 1.5Cu steel (b) (Arrows in Fig.6b show the nano-sized Cu-rich precipitations)
[1] Park G T, Koh S U, Jung H G, et al.Effect of microstructure on the hydrogen trapping efficiency and hydrogen induced cracking of linepipe steel[J]. Corros. Sci., 2008, 50: 1865
[2] Koh S U, Jung H G, Kang K B, et al.Effect of microstructure on hydrogen-induced cracking of linepipe steels[J]. Corrosion, 2008, 64: 574
[3] Beidokhti B, Dolati A, Koukabi A H.Effects of alloying elements and microstructure on the susceptibility of the welded HSLA steel to hydrogen-induced cracking and sulfide stress cracking[J]. Mater. Sci. Eng., 2009, A507: 167
[4] Shi X B, Yan W, Wang W, et al.HIC and SSC behavior of high-strength pipeline steels[J]. Acta Metall. Sin.(Engl. Lett.), 2015, 28: 799
[5] Shi X B, Yan W, Wang W, et al.Effect of microstructure on hydrogen induced cracking behavior of a high deformability pipeline steel[J]. J. Iron. Steel. Res. Int., 2015, 22: 937
[6] Shi X B, Wang W, Yan W, et al.Effect of martensite/austenite (M/A) constituent on H2S resistance of high strength pipeline steels[J]. J. Chin. Soc. Corros. Prot., 2015, 35: 129(史显波, 王威, 严伟等. M/A组元对高强度管线钢抗H2S性能的影响[J]. 中国腐蚀与防护学报, 2015, 35: 129)
[7] Pressouyre G M.A classification of hydrogen traps in steel[J]. Metall. Trans., 1979, 10A: 1571
[8] Pressouyre G M, Bernstein I M.An example of the effect of hydrogen trapping on hydrogen embrittlement[J]. Metall. Trans., 1981, 12A: 835
[9] Yamasaki S, Takahashi T.Evaluation method of delayed fracture property of high strength steels[J]. Tetsu Hagané, 1997, 83: 454(山崎真吾, 高橋稔彦. 高強度鋼の耐遅れ破壊特性の定量的評価方法[J]. 鉄と鋼, 1997, 83: 454)
[10] Szost B A, Vegter R H, Rivera-Díaz-del-Castillo P E J. Developing bearing steels combining hydrogen resistance and improved hardness[J]. Mater. Des., 2013, 43: 499
[11] Takahashi J, Kawakami K, Kobayashi Y, et al.The first direct observation of hydrogen trapping sites in TiC precipitation-hardening steel through atom probe tomography[J]. Scr. Mater., 2010, 63: 261
[12] Takahashi J, Kawakami K, Tarui T.Direct observation of hydrogen-trapping sites in vanadium carbide precipitation steel by atom probe tomography[J]. Scr. Mater., 2012, 67: 213
[13] Zhao M C, Yang K.Strengthening and improvement of sulfide stress cracking resistance in acicular ferrite pipeline steels by nano-sized carbonitrides[J]. Scr. Mater., 2005, 52: 881
[14] Shi X B, Xu D K, Yan M C, et al.Study on microbiologically influenced corrosion behavior of novel Cu-bearing pipeline steels[J]. Acta Metall. Sin., 2017, 53: 153(史显波, 徐大可, 闫茂成等. 新型含Cu管线钢的微生物腐蚀行为研究[J]. 金属学报, 2017, 53: 153)
[15] Shi X B, Yan W, Yan M C, et al.Effect of Cu addition in pipeline steels on microstructure, mechanical properties and microbiologically influenced corrosion[J]. Acta Metall. Sin.(Engl. Lett.), 2017, 30: 601
[16] Herbsleb G, Poepperling R K, Schwenk W.Occurrence and prevention of hydrogen induced stepwise cracking and stress corrosion cracking of low alloy pipeline steels[J]. Corrosion, 1980, 36: 247
[17] Taira T, Tsukada K, Kobayashi Y.Sulfide corrosion cracking of linepipe for sour gas service[J]. Corrosion, 1981, 37: 5
[18] Yoshino Y.Low alloy steels in hydrogen sulfide environment[J]. Corrosion, 1982, 38: 156
[19] Craig B D.Effect of copper on the protectiveness of iron sulfide films[J]. Corrosion, 1984, 40: 471
[20] Mendibide C, Sourmail T.Composition optimization of high-strength steels for sulfide stress cracking resistance improvement[J]. Corros. Sci., 2009, 51: 2878
[21] Jiao Z B, Luan J H, Zhang Z W, et al.Synergistic effects of Cu and Ni on nanoscale precipitation and mechanical properties of high-strength steels[J]. Acta Mater., 2013, 61: 5996
[22] Hejazi D, Hap A J, Yazdipour N, et al.Effect of manganese content and microstructure on the susceptibility of X70 pipeline steel to hydrogen cracking[J]. Mater. Sci. Eng., 2012, A551: 40
[23] Chu W Y.Hydrogen Damaged and Delayed Fracture [M]. Beijing: Metallurgy Industry Press, 1988: 1(褚武扬. 氢损伤和滞后断裂 [M]. 北京: 冶金工业出版社, 1988: 1)
[24] Zhao M C, Shan Y Y, Xiao F R, et al.Investigation on the H2S-resistant behaviors of acicular ferrite and ultrafine ferrite[J]. Mater. Lett., 2002, 57: 141
[25] Zhao M C, Tang B, Shan Y Y.Role of microstructure on sulfide stress cracking of oil and gas pipeline steels[J]. Metall. Mater. Trans., 2003, 34A: 1089
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