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Acta Metall Sin  1992, Vol. 28 Issue (4): 49-57    DOI:
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EFFECT OF REACTIVE ELEMENTS Y AND Ce ON HIGH TEMPERATURE OXIDATION OF Fe-25Cr-40Ni ALLOY
YU Fanghua;YANG Guohua;HAN Rongdian;WENG HuimIN;SHEN Jianian Shanghai Institute of Nuclear Research; Academia Sinica; University of Science and Technology of China; Hefei; Corrosion Science Laboratory; Academia Sinica; Shengyang
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YU Fanghua;YANG Guohua;HAN Rongdian;WENG HuimIN;SHEN Jianian Shanghai Institute of Nuclear Research; Academia Sinica; University of Science and Technology of China; Hefei; Corrosion Science Laboratory; Academia Sinica; Shengyang. EFFECT OF REACTIVE ELEMENTS Y AND Ce ON HIGH TEMPERATURE OXIDATION OF Fe-25Cr-40Ni ALLOY. Acta Metall Sin, 1992, 28(4): 49-57.

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Abstract  Effect of reactive elements Y and Ce on high temperature oxidation ofFe-25Cr-40Ni alloy as well as on composition and microstructure of oxidized layer has beenstudied by ion backscattering and slow positron beam. The reactive element, not more than0.05%, may decrease the oxidation rate at early stage, accelerate the Cr_2O_3 growth, retard theFe and Ni oxides formation and improve the microstructure of oxidized layer. They enter theoxidized layer and concentrate within several tens nm from surface of outer layer. The resistancemechanism to oxidation for Ce seems to be different from Y. Ce may decrease the density of va-cancy defects in oxidized layer so that the diffusion outward of cations through vacancies is re-strained. While Y may affect the restraint of cations diffusion outward through vacancies at ear-ly stage to change into that along grain boundaries.
Key words:  ion backsatering      slow positron beam      high temperature oxidation      reactive element      FeCrNi alloy     
Received:  18 April 1992     
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