Acta Metall Sin  1988, Vol. 24 Issue (4): 348-353    DOI:

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EFFECT OF HYDROGEN ABSORPTION ON MAGNETIC PROPERTIES OF AMORPHOUS Fe_(90-x)V_xZr_(10) ALLOYS

DUO Liang;XU Zuxiong;MA Ruzhang Beijing University of Iron and Steel TechnologyInstitute of High Energy Physics;Academia Sinica; Zhongguancun; Beijing

DUO Liang;XU Zuxiong;MA Ruzhang Beijing University of Iron and Steel TechnologyInstitute of High Energy Physics;Academia Sinica; Zhongguancun; Beijing. EFFECT OF HYDROGEN ABSORPTION ON MAGNETIC PROPERTIES OF AMORPHOUS Fe_(90-x)V_xZr_(10) ALLOYS. Acta Metall Sin, 1988, 24(4): 348-353.

Abstract References Related Articles Recommended Metrics Download:  PDF(482KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The amorphous Fe_(90-x)V_xZr_(10) alloy after electrolytic hydrogenation pro-cedure was studied by means of Mossbauer effect, magnetic measuement, X-ray dif-fraction and second ion mass spectroscopy (SIMS) techniques. The experimental re-sults show that the magnetic properties of amorphous Fe_(90-x)V_xZr_(10) alloy are highlysensitive to presence of hydrogen. The isomer shift (IS) has a small positive changeand the magnetic properties transfer from paramagnetic to ferromagnetic state byhydrogenation. The effect of hydrogen absorption is also to raise Fe magnetic mo-ment and Curie temperature T_C from 257 to 384 K. Finally, the considerable in-crease of magnetic properties of amorphous Fe_(90-x)V_xZr_(10) alloy by hydrogenation is at-tributable to the change of hydridization effect between outer electrons of Zr atomsand 3d-electrons of Fe atoms. It may be concluded that the hydrogen atoms is loca-lized around Zr atoms when hydrogen atoms enter inside of alloy. Key words:  Amorphous alloy      hydrogen absorption      magnetic property      Received:  18 April 1988      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1988/V24/I4/348 1 Dkamoto T, Fuji H, Matsushima T, Audo Y. Tran Jpn Inst Met, 1980; 21: 889 2 Fuji H, Okamoto T, Wallace W E. J Magn Magn Mater, 1985; 46: 245 3 Coey J M D, Ryan D. J Appl Phys, 1982; 53: 7804 4 Forester D W. J Non-Cryst Solids, 1984; 61&62: 685 S Schelleng J H, Forester D W, Lubitz P, Vittotia C. J Appl Phys, 1984; 55: 1805 6 Wey J M D, Ryan D. J Appl Phys, 1984; 55: 1800 7 Buschow K H J, Sherwood R L. J Appl Phys, 1978; 49: 1480 8 Buschow K H J. J Magn Magn Mater, 1982; 29: 99 9 Smit P H, Busschow K H J. Phys Rev, 1981; B21: 3839 10 Fujimori H. J Appl Phys, 1982; 53: 7792 12 马如璋,多良,徐祖雄,丁维清.材料科学进展,1987;1(3) :491 [1] ZHANG Deyin, HAO Xu, JIA Baorui, WU Haoyang, QIN Mingli, QU Xuanhui. Effects of Y2O3 Content on Properties of Fe-Y2O3 Nanocomposite Powders Synthesized by a Combustion-Based Route[J]. 金属学报, 2023, 59(6): 757-766. [2] LIU Shuaishuai, HOU Chaonan, WANG Engang, JIA Peng. Plastic Rheological Behaviors of Zr61Cu25Al12Ti2 and Zr52.5Cu17.9Ni14.6Al10Ti5 Amorphous Alloys in the Supercooled Liquid Region[J]. 金属学报, 2022, 58(6): 807-815. [3] LI Jinfu, LI Wei. Structure and Glass-Forming Ability of Al-Based Amorphous Alloys[J]. 金属学报, 2022, 58(4): 457-472. [4] ZHANG Jinyong, ZHAO Congcong, WU Yijin, CHEN Changjiu, CHEN Zheng, SHEN Baolong. Structural Characteristic and Crystallization Behavior of the (Fe0.33Co0.33Ni0.33)84 -x Cr8Mn8B x High-Entropy-Amorphous Alloy Ribbons[J]. 金属学报, 2022, 58(2): 215-224. [5] HAN Luhui, KE Haibo, ZHANG Pei, SANG Ge, HUANG Huogen. Kinetic Crystallization Behavior of Amorphous U60Fe27.5Al12.5 Alloy[J]. 金属学报, 2022, 58(10): 1316-1324. [6] XIANG Zhaolong, ZHANG Lin, XIN Yan, AN Bailing, NIU Rongmei, LU Jun, MARDANI Masoud, HAN Ke, WANG Engang. Effect of Cr Content on Microstructure of Spinodal Decomposition and Properties in FeCrCoSi Permanent Magnet Alloy[J]. 金属学报, 2022, 58(1): 103-113. [7] HU Xiang, GE Jiacheng, LIU Sinan, FU Shu, WU Zhenduo, FENG Tao, LIU Dong, WANG Xunli, LAN Si. Combustion Mechanism of Fe-Nb-B-Y Amorphous Alloys with an Anomalous Exothermic Phenomenon[J]. 金属学报, 2021, 57(4): 542-552. [8] LIU Riping, MA Mingzhen, ZHANG Xinyu. New Development of Research on Casting of Bulk Amorphous Alloys[J]. 金属学报, 2021, 57(4): 515-528. [9] ZHU Min, OUYANG Liuzhang. Kinetics Tuning and Electrochemical Performance of Mg-Based Hydrogen Storage Alloys[J]. 金属学报, 2021, 57(11): 1416-1428. [10] HUANG Huogen, ZHANG Pengguo, ZHANG Pei, WANG Qinguo. Comparison of Glass Forming Ability Between U-Co and U-Fe Base Systems[J]. 金属学报, 2020, 56(6): 849-854. [11] YU Lei,LUO Haiwen. Effect of Partial Recrystallization Annealing on Magnetic Properties and Mechanical Properties of Non-Oriented Silicon Steel[J]. 金属学报, 2020, 56(3): 291-300. [12] GENG Yaoxiang, WANG Yingmin. Local Structure-Property Correlation of Fe-Based Amorphous Alloys: Based on Minor Alloying Research[J]. 金属学报, 2020, 56(11): 1558-1568. [13] XU Xiuyue, LI Yanhui, ZHANG Wei. Fabrication of Nanoporous PtRuFe by Dealloying Amorphous Fe(Pt, Ru)B Ribbons and Their Methanol Electrocatalytic Properties[J]. 金属学报, 2020, 56(10): 1393-1400. [14] Jing BAI, Shaofeng SHI, Jinlong WANG, Shuai WANG, Xiang ZHAO. First-Principles Calculations of Phase Stability and Magnetic Properties of Ni-Mn-Ga-Ti FerromagneticShape Memory Alloys[J]. 金属学报, 2019, 55(3): 369-375. [15] JIN Chenri, YANG Suyuan, DENG Xueyuan, WANG Yangwei, CHENG Xingwang. Effect of Nano-Crystallization on Dynamic Compressive Property of Zr-Based Amorphous Alloy[J]. 金属学报, 2019, 55(12): 1561-1568. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed