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金属学报  2026, Vol. 62 Issue (4): 572-586    DOI: 10.11900/0412.1961.2024.00303
  研究论文 本期目录 | 过刊浏览 |
深海油气田输送用X65/Inconel 625双金属复合板热变形行为及热轧工艺
刘庚1,2, 单以银2,3(), 严伟2,3, 苏锐1,2, 任毅4, 史显波2,3
1.中国科学技术大学 材料科学与工程学院 沈阳 110016
2.中国科学院金属研究所 师昌绪先进材料创新中心 沈阳 110016
3.中国科学院金属研究所 沈阳材料科学国家研究中心 沈阳 110016
4.鞍钢集团 海洋装备用金属材料及其应用全国重点实验室 鞍山 114009
Thermal Deformation Behavior and Hot Rolling Process of X65/Inconel 625 Bimetal Composite Plate for Deep Sea Oil and Gas Field Transportation
LIU Geng1,2, SHAN Yiyin2,3(), YAN Wei2,3, SU Rui1,2, REN Yi4, SHI Xianbo2,3
1.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
2.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
4.State Key Laboratory of Metal Materials for Marine Equipment and Application, Ansteel Group Corporation, Anshan 114009, China
引用本文:

刘庚, 单以银, 严伟, 苏锐, 任毅, 史显波. 深海油气田输送用X65/Inconel 625双金属复合板热变形行为及热轧工艺[J]. 金属学报, 2026, 62(4): 572-586.
Geng LIU, Yiyin SHAN, Wei YAN, Rui SU, Yi REN, Xianbo SHI. Thermal Deformation Behavior and Hot Rolling Process of X65/Inconel 625 Bimetal Composite Plate for Deep Sea Oil and Gas Field Transportation[J]. Acta Metall Sin, 2026, 62(4): 572-586.

全文: PDF(5563 KB)   HTML
摘要: 

针对异质双金属复合材料在热轧过程中变形不协调严重影响性能和界面结合强度的问题,本工作对深海油气输送用X65/Inconel 625双金属复合板热轧工艺的精准调控进行研究。利用Gleeble-3800热模拟试验机对基材X65管线钢和内衬层Inconel 625耐蚀合金进行了热压缩实验,研究了双金属的流变应力、本构关系、热加工图、界面抗弯性能和微观组织特征等。结果表明,随着变形温度的升高和应变速率的降低,双金属的峰值应力差逐渐减小。在高温条件(≥ 950 ℃)下,X65钢的主要软化机制为动态回复,而Inconel 625合金为动态再结晶。理论分析与实验结果相结合可知,理想的双金属复合板的热轧工艺窗口为:1000 ℃终轧、70%压下量。在该参数下热轧后,界面平直且复合良好,具有较强的弯曲变形能力。复合板纵向屈服强度为469 MPa,抗拉强度为606 MPa,延伸率为30%,剪切强度为442 MPa。

关键词 双金属复合板热压缩热轧复合界面三点弯曲    
Abstract

The service environment of deep-sea oil and gas pipelines is becoming increasingly harsh, making it difficult for traditional single-metal pipeline steels to meet the unique demands of such environments. Bimetal composite materials leverage the advantages of bimetal components to achieve properties that are not possible with single metal materials. Hot rolling, a solid-phase bonding process that joins pipeline steel substrates and stainless steel at high temperatures, is an efficient method for creating strong interfaces. This technique is particularly suitable for the large-scale industrial production of bimetal clad plates, necessitating the establishment of an industrial production line. To overcome the challenge posed by deformation inconsistencies that adversely affect the properties and interface bonding strength of heterogeneous bimetal clad materials during hot rolling, the precise control of the hot rolling process for X65/Inconel 625 bimetal composite plates intended for deep-sea oil and gas transportation was investigated. Thermal compression tests on the X65 pipeline steel and Inconel 625 corrosion-resistant alloy were carried out using a Gleeble-3800 thermal simulation testing machine. The flow stress, constitutive relationships, thermal working diagram, interface bending resistance, and microstructure characteristics of the bimetallic materials were examined. The results indicate that the peak stress difference in the bimetallic materials decreases as the deformation temperature increases and the strain rate decreases. At high temperatures (≥ 950 oC), the primary softening mechanism for X65 steel is dynamic recovery, whereas that for Inconel 625 is dynamic recrystallization. Our findings suggest that the optimal hot rolling process for the bimetal clad plate should involve a final rolling temperature of 1000 oC and a reduction of 70%, based on theoretical analysis and experimental data. The interface is straight and well-combined, and demonstrates strong bending deformation ability. The bimetal clad plate achieves a rolling direction yield strength of 469 MPa, tensile strength of 606 MPa, elongation of 30%, and shear strength of 442 MPa.

Key wordsbimetal composite plate    thermal compression    hot rolling    composite interface    three-point bending
收稿日期: 2024-08-28     
ZTFLH:  TG 335.5  
基金资助:国家自然科学基金项目(52201093);工业和信息化部专项项目(2240STCZB2346);海洋装备国家重点实验室开放基金项目(SKLMEA-K202205)
通讯作者: 单以银,yyshan@imr.ac.cn,主要从事先进钢铁结构材料设计、制备、表征与使役行为研究
Corresponding author: SHAN Yiyin, professor, Tel: (024)23971517, E-mail: yyshan@imr.ac.cn
作者简介: 刘 庚,男,1997年生,博士生
图1  热压缩变形工艺示意图、热压缩方向和试样初始组织
图2  X65/Inconel 625双金属复合板对称组坯示意图
图3  显微组织取样位置及力学试样尺寸示意图
图4  不同变形条件下的真应力-应变曲线
图5  不同变形条件下X65钢和Inconel 625合金的峰值应力
图6  lnε˙与lnσp、lnε˙与σp、lnε˙与ln[sinh(ασp)]及ln[sinh(ασp)]与1000 / T之间的关系
Materialα / MPa-1n / MPaQ / (J·mol-1)A / S-1
X650.003308.208401.234 × 1035.6039 × 1018
Inconel 6250.002298.563627.884 × 1031.9405 × 1024
表1  X65钢和Inconel 625合金的本构方程参数
图7  峰值应力实验值与预测值的拟合结果
图8  修正后的峰值应力实验值与预测值的拟合结果
图9  不同应变下X65钢和Inconel 625合金的热加工图和失稳区域
图10  不同热变形条件下X65钢和Inconel 625合金的反极图(IPF)和大角度晶界(HAGB)图
图11  不同热变形条件下X65钢和Inconel合金的EBSD分析和1150 ℃、1 s-1条件下的真应力-应变曲线
图12  不同热变形条件下的局部取向差(KAM)统计结果和KAM图
图13  国内某钢厂在终轧温度为850 ℃时热轧后双金属复合板的宏观形貌
图14  终轧温度为1000 ℃时热轧后双金属复合板的宏观形貌
图15  双金属复合板界面附近显微组织的SEM像
图16  双金属复合板界面附近的IPF和局部应变分布(GOS)图
图17  双金属复合板的力学性能
图18  双金属复合板三点弯曲实验后的宏观和微观组织
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