电阻缝焊法制备铁基<strong>WC/</strong>金属双层涂层及其摩擦行为

doi:10.11900/0412.1961.2018.00271

金属学报

2019, Vol. 55

Issue (4): 537-546 DOI: 10.11900/0412.1961.2018.00271

本期目录 | 过刊浏览

电阻缝焊法制备铁基WC/金属双层涂层及其摩擦行为

王文琴^1,²,王昭漫¹,李玉龙¹,王德³(

),李淼¹,陈情¹

1. 南昌大学机电工程学院南昌 330031
2. 清华大学摩擦学国家重点实验室北京 100084
3. 江西省科学院应用物理研究所南昌 330029

Wear Behavior of Fe-WC/Metal Double Layer Coatings Fabricated by Resistance Seam Weld Method

Wenqin WANG^1,²,Zhaoman WANG¹,Yulong LI¹,De WANG³(

),Miao LI¹,Qing CHEN¹

1. School of Mechanical and Electrical Engineering, Nanchang University, Nanchang 330031, China
2. State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, China
3. Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330029, China

引用本文:

王文琴, 王昭漫, 李玉龙, 王德, 李淼, 陈情. 电阻缝焊法制备铁基WC/金属双层涂层及其摩擦行为[J]. 金属学报, 2019, 55(4): 537-546.
Wenqin WANG, Zhaoman WANG, Yulong LI, De WANG, Miao LI, Qing CHEN. Wear Behavior of Fe-WC/Metal Double Layer Coatings Fabricated by Resistance Seam Weld Method[J]. Acta Metall Sin, 2019, 55(4): 537-546.

全文: PDF(32341 KB) HTML

摘要:

通过电阻缝焊法，使用超硬铁基合金粉末(SHA)和2种粒度(3.5和55 μm)的WC粉末在Al7075板表面制备了铁基WC/金属双层涂层。采用SEM和EPMA等手段对双层涂层的显微组织进行了分析；采用纳米压痕仪对双层涂层中微小组织进行了纳米硬度测试；最后通过球盘摩擦(ball-on-disc)实验对比了WC和SUS304 2种磨球对双层涂层的摩擦磨损行为的影响。结果表明，该铁基WC/金属双层涂层的总厚度达600 μm，从涂层到基体的结构依次为：WC粉末/铁合金(耐磨层)+铁基/铝合金(金属中间层)+铝合金基体。当以WC为磨球时，使用微细和粗大WC粉末的涂层，其磨损机制分别为严重的磨粒磨损和脆性断裂伴随少量磨粒磨损；当以SUS304为磨球时，使用微细WC的涂层基本未发生磨损，而粗大WC粉末的涂层则发生少量磨粒磨损。以SUS304为磨球时，涂层的磨损率均低于以WC为磨球时涂层的磨损率。

关键词 ：电阻缝焊法, 双层涂层, 摩擦行为

Abstract：

Fe-WC/metal double layer coatings containing Fe-C-Si super hard alloy (SHA) particles and tungsten carbide (WC) particles were fabricated on Al7075 substrates by resistance seam welding method to improve the wear resistance of aluminum alloys. The micro-structure and phase compositions of the Fe-WC/metal double layer coatings with different WC particle sizes (fine and coarse) were investigated by SEM and EPMA. Nano-hardness of different phases in the coatings were investigated by nano-indentation test. Finally, the friction behavior of the two kinds of Fe-WC /metal double layer coatings were contrasted by ball-on-disc test using WC and SUS 304 balls. The results show that the thicknesses of Fe-WC composite/metal double layer coatings were about 600 μm. The microstructure of the coatings was: WC/Fe composite (wear resistance layer)+Fe/Al composite (metal interlayer)+Al7075 substrate. When WC ball was used as the static counterpart, the wear mechanism of the coatings with fine and coarse WC particles were severe abrasive wear and brittle fracture with little abrasive wear, respectively. When SUS304 was used as the static counterpart, the coating with fine WC powder was demonstrated difficulty to be abraded due to the protection of the iron oxide adhesive layer, and the other proved a little brittle fracture. Moreover, the wear rate of both coatings using SUS304 ball was lower than that of WC ball in the ball-on-disc test.

Key words： resistance seam welding double layer coatings wear behavior

收稿日期: 2018-06-27

ZTFLH:

TG174

基金资助:国家自然科学基金项目(No.51765041);清华大学摩擦学重点实验室开放基金(No.5KLTLF17B07);江西省重点研发计划项目(No.20171BBE50022)

作者简介: 王文琴，女，1987年生，博士

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图1 铁基WC/金属双层涂层断面显微组织的SEM像

图2 铁基WC/金属双层涂层断面的EPMA面扫描照片

图3 涂层F中间层各组织纳米硬度实验结果

图4 WC和SUS304为磨球时2种涂层的磨损率

图5 电阻缝焊法制备涂层F示意图

图6 以WC为磨球时摩擦实验后2种涂层表面形貌

图7 以 SUS304为磨球时摩擦实验后2种涂层表面形貌

图8 以WC为磨球时摩擦实验后2种涂层表面EDS元素分布图

图9 以SUS304为磨球时摩擦实验后2种涂层表面EDS元素分布图

图10 摩擦实验后2种涂层对应的WC磨球表面EDS元素分布图

图11 摩擦实验后涂层对应的SUS304磨球表面EDS元素分布图

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