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金属学报  2026, Vol. 62 Issue (3): 431-444    DOI: 10.11900/0412.1961.2025.00057
  研究论文 本期目录 | 过刊浏览 |
高温无氧轧制Cu/1060Al/Cu三层复合材料的力学和导电性能
蒋志达1,2, 胥杨洋1,2, 于佳新1,2, 刘文才1,2(), 朱浩文1,2, 吴国华1,2, 尚郑平3
1.上海交通大学 材料科学与工程学院 轻合金精密成型国家工程研究中心 上海 200240
2.上海交通大学 材料科学与工程学院 金属基复合材料全国重点实验室 上海 200240
3.江苏中色复合材料有限公司 无锡 214000
Mechanical and Conductive Properties of Cu/1060Al/Cu Three-Layer Composite Prepared by High-Temperature Oxygen-Free Rolling
JIANG Zhida1,2, XU Yangyang1,2, YU Jiaxin1,2, LIU Wencai1,2(), ZHU Haowen1,2, WU Guohua1,2, SHANG Zhengping3
1.National Engineering Research Center of Light Alloy Net Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2.State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
3.Jiangsu Zhongse Composites Co. Ltd., Wuxi 214000, China
引用本文:

蒋志达, 胥杨洋, 于佳新, 刘文才, 朱浩文, 吴国华, 尚郑平. 高温无氧轧制Cu/1060Al/Cu三层复合材料的力学和导电性能[J]. 金属学报, 2026, 62(3): 431-444.
Zhida JIANG, Yangyang XU, Jiaxin YU, Wencai LIU, Haowen ZHU, Guohua WU, Zhengping SHANG. Mechanical and Conductive Properties of Cu/1060Al/Cu Three-Layer Composite Prepared by High-Temperature Oxygen-Free Rolling[J]. Acta Metall Sin, 2026, 62(3): 431-444.

全文: PDF(4422 KB)   HTML
摘要: 

为了解决传统冷轧工艺制备Cu/Al层状复合材料时常出现的界面结合性能差和氧化物生成问题,本工作采用高温无氧轧制工艺制备了Cu/1060Al/Cu三层复合材料,并对其力学性能和导电性能进行了系统研究。结果表明,经过2道次轧制和350 ℃、2 h退火的Cu/1060Al/Cu三层复合材料具有最优的综合性能,其屈服强度、抗拉强度和延伸率分别为107 MPa、178 MPa和67%。三层复合材料在界面层的耦合作用和两侧Cu层对Al层的牵制作用下,拉伸断裂模式为协同断裂。Cu/1060Al/Cu三层复合材料的电导率达到70.1%IACS,满足其作为导体材料的电导率指标要求。通过Ansys系统模拟了通交变电流时三层复合板内电流密度分布的变化情况。模拟结果表明,控制电流密度分布形式的主要因素是电流频率,通高频电流时电流密度分布具备趋肤效应的典型特征。在相同的电流频率下,交变电流密度随Cu层占比的增加而逐渐增加。在设计Cu层占比时,单侧Cu层占比的合理区间为10.0%~17.5%。

关键词 Cu/Al层状复合材料高温无氧轧制力学性能导电性能Ansys模拟    
Abstract

Cu/Al laminated composites combine the lightweight advantage of aluminum with the high electrical and thermal conductivity of copper, and are widely used in the new energy, communication, electric power, and related industries. Traditionally, cold rolling has been the primary method for producing these composites; however, it often results in poor interfacial bonding and promotes the formation of oxides at the interface. In contrast, the high-temperature oxygen-free rolling process can significantly improve composite preparation by enabling precise layer temperature control and creating an anaerobic environment. This process typically forms a mechanical bonding interface, necessitating subsequent annealing to achieve a metallurgical bond that enhances interfacial integrity and optimizes performance. Therefore, developing an annealing process that complements the rolling method is essential. Based on this context, a Cu/1060Al/Cu three-layer composite was fabricated using T2 copper and 1060 aluminum as base materials. The effects of rolling passes and annealing parameters on the mechanical properties and conductivity of the composite were investigated. In addition, the current density distribution within the composite was simulated using Ansys software. After annealing at 350 oC for 2 h, the interface layer of the Cu/1060Al/Cu composite became uniform and continuous, with microcracks in the rolled interface layer effectively eliminated. According to strength-plasticity product calculations, the composite exhibited optimal overall performance after two rolling passes, achieving a yield strength of 107 MPa, tensile strength of 178 MPa, and elongation of 67%. Under the combined influence of the interface layer and the constraining effect of the copper layers on both sides of the aluminum core, the composite displayed a collaborative tensile fracture mode. The measured conductivity of the Cu/1060Al/Cu composite reached 70.1%IACS satisfying the requirements for conductor applications. The current density distribution in the annealed Cu/1060Al/Cu composite primarily varied with current frequency, demonstrating the skin effect characteristics typical of alternating current. The current density decreased with increasing frequency and increased with a higher proportion of the copper layer. Notably, increasing the copper layer proportion does not always lead to better performance. It is necessary to comprehensively consider electrical conductivity and material usage when determining the copper layer proportion. An appropriate range for the single-sided copper layer proportion is 10.0%-17.5%.

Key wordsCu/Al laminated composites    high-temperature oxygen-free rolling    mechanical property    conductive property    Ansys simulation
收稿日期: 2025-02-28     
ZTFLH:  TG335.8  
基金资助:国家重点研发计划项目(2021YFB3701303);国家自然科学基金项目(U2037601)
通讯作者: 刘文才,liuwc@sjtu.edu.cn,主要从事轻质金属材料研究
Corresponding author: LIU Wencai, professor, Tel: 15921573539, E-mail: liuwc@sjtu.edu.cn
作者简介: 蒋志达,男,1999年生,硕士
Raw materialCuAlFeSPbSiTi
T2Cu99.990-0.0030.0050.002--
1060Al-99.8000.050--0.1000.050
表1  原材料的化学成分 (mass fraction / %)
图1  Cu/1060Al/Cu三层复合材料高温无氧轧制工艺示意图
图2  Cu/1060Al/Cu三层复合材料取样位置示意图和具体尺寸
图3  Cu/1060Al/Cu三层复合材料通电时电流密度分布情况模拟的仿真模型
图4  轧制态Cu/1060Al/Cu三层复合材料界面的SEM像和EDS面分布图
图5  Cu/1060Al/Cu三层复合材料经1和3道次轧制后Al/Al界面的OM像
图6  退火态Cu/1060Al双层复合材料和不同道次轧制后退火态Cu/1060Al/Cu三层复合材料界面的SEM像
Rolling passPointCuAlPhase
One pass171.3928.61Cu9Al4
253.1946.81CuAl
330.5669.44CuAl2
Two passes469.8530.15Cu9Al4
558.8241.18CuAl
632.2967.71CuAl2
Three passes771.6828.32Cu9Al4
853.7246.28CuAl
931.4768.53CuAl2
表2  不同道次轧制后Cu/1060Al/Cu三层复合材料界面层化合物的成分及种类 (atomic fraction / %)
图7  不同道次轧制后退火前后Cu/1060Al/Cu三层复合材料的应力-应变曲线
MaterialProcess

YS

MPa

UTS

MPa

EL

%

PTD

MPa·%

Cu/Al two-layer compositeTwo-pass rolling + annealing82138638694

Cu/1060Al/Cu three-layer composite

One-pass rolling86155507750
Two-pass rolling94161589338
Three-pass rolling107181417421
One-pass rolling + annealing811317910349
Two-pass rolling + annealing1071786711926
Three-pass rolling + annealing114171478037
表3  复合材料在不同工艺状态下的力学性能
图8  轧制态Cu/1060Al/Cu三层复合材料拉伸断裂机理示意图
图9  退火态Cu/1060Al/Cu三层复合材料拉伸断裂机理示意图
Rolling pass

d

mm

Length

mm

Cross-sectional area

mm2

Resistance

μΩ

Resistivity

μΩ·mm

Conductivity
MS·m-1%IACS
One pass425078.9560.1 ± 0.10.023642.274.0
Two passes225040.66147.8 ± 0.20.024041.673.0
Three passes125018.35340.6 ± 0.40.025040.070.1
表4  不同道次轧制后退火态Cu/1060Al/Cu三层复合材料的直流电阻测试参数和结果
图10  单侧Cu层厚度占比为10.0%时Cu/1060Al/Cu三层复合材料在220 V交流电下的电流密度分布
图11  单侧Cu层厚度占比为17.5%时Cu/1060Al/Cu三层复合材料在220 V交流电下的电流密度分布
图12  单侧Cu层厚度占比为25.0%时Cu/1060Al/Cu三层复合材料在220 V交流电下的电流密度分布
图13  不同单侧Cu层厚度占比下Cu/Al/Cu三层复合材料交流阻抗测试结果
[1] Chen D G, Zhang H M, Li H N, et al. Study on microstructure and properties of ultra-thin Cu/Al composite sheets using the cold-rolled composite method at the microscale [J]. Metals, 2023, 13: 780
doi: 10.3390/met13040780
[2] Lin H R, Tian Y Z, Sun S J, et al. Microstructural evolution and mechanical properties of laminated Cu/Al composites processed by accumulative roll-bonding and annealing [J]. Acta Metall. Sin. (Engl. Lett.), 2021, 34: 925
doi: 10.1007/s40195-020-01179-w
[3] Zhang J P, Huang H G, Zhao R D, et al. Cast-rolling force model in solid-liquid cast-rolling bonding (SLCRB) process for fabricating bimetal clad strips [J]. Trans. Nonferrous Met. Soc. China, 2021, 31: 626
doi: 10.1016/S1003-6326(21)65524-3
[4] Liu X H, Fu H D, He X Q, et al. Numerical simulation analysis of continuous casting cladding forming for Cu-Al composites [J]. Acta. Metall. Sin., 2018, 54: 470
doi: 10.11900/0412.1961.2017.00460
[4] 刘新华, 付华栋, 何兴群 等. Cu/Al复合材料连铸直接成形数值模拟研究 [J]. 金属学报, 2018, 54: 470
doi: 10.11900/0412.1961.2017.00460
[5] Eizadjou M, Manesh H D, Janghorban K. Mechanism of warm and cold roll bonding of aluminum alloy strips [J]. Mater. Des., 2009, 30: 4156
doi: 10.1016/j.matdes.2009.04.036
[6] Manesh H D, Taheri A K. Study of mechanisms of cold roll welding of aluminium alloy to steel strip [J]. Mater. Sci. Technol., 2004, 20: 1064
doi: 10.1179/174328413X13789824293461
[7] Li X B, Zu G Y, Ding M M, et al. Interfacial microstructure and mechanical properties of Cu/Al clad sheet fabricated by asymmetrical roll bonding and annealing [J]. Mater. Sci. Eng., 2011, A529: 485
[8] Hosseini S A, Hosseini M, Manesh H D. Bond strength evaluation of roll bonded bi-layer copper alloy strips in different rolling conditions [J]. Mater. Des., 2011, 32: 76
doi: 10.1016/j.matdes.2010.06.032
[9] Wang L, Du Q L, Li C, et al. Enhanced mechanical properties of lamellar Cu/Al composites processed via high-temperature accumulative roll bonding [J]. Trans. Nonferrous Metal. Soc. China, 2019, 29: 1621
doi: 10.1016/S1003-6326(19)65069-7
[10] Nambu S, Michiuchi M, Inoue J, et al. Effect of interfacial bonding strength on tensile ductility of multilayered steel composites [J]. Compos. Sci. Technol., 2009, 69: 1936
doi: 10.1016/j.compscitech.2009.04.013
[11] Huang M, Xu C, Fan G H, et al. Role of layered structure in ductility improvement of layered Ti-Al metal composite [J]. Acta Mater., 2018, 153: 235
doi: 10.1016/j.actamat.2018.05.005
[12] Ebrahimi M, Liu G P, Wang Q D, et al. Evaluation of interface structure and high-temperature tensile behavior in Cu/Al8011/Al5052 trilayered composite [J]. Mater. Sci. Eng., 2020, A798: 140129
[13] Ebrahimi M, Liu G P, Li C W, et al. Characteristic investigation of trilayered Cu/Al8011/Al1060 composite: interface morphology, microstructure, and in-situ tensile deformation [J]. Prog. Natl. Sci., 2021, 31: 679
doi: 10.1016/j.pnsc.2021.08.005
[14] Huang H J, Yuan X G, Jia Z, et al. Study on the electric conduction properties of copper and aluminum cladding plate with size changing [A]. Proceedings of 2009 China Casting Week [C]. Weihai: Chinese Mechanical Engineering Society, Foundary Institution of Chinese Mechanical Engineering Society, 2009: 668
[14] 黄宏军, 袁晓光, 贾 真 等. 铜铝复合板尺寸对导电性能的影响 [A]. 2009中国铸造活动周论文集 [C]. 威海: 中国机械工程学会, 中国机械工程学会铸造分会, 2009: 668
[15] Wang Y Y, Wang C X, Liu P, et al. Study on the thermoelectric properties of copper/aluminum composite [J]. J. Funct. Mater., 2018, 49: 1151
doi: 10.3969/j.issn.1001-9731.2018.01.028
[15] 王艳艳, 王聪兴, 刘 平 等. Cu/Al复合材料热电性能的研究 [J]. 功能材料, 2018, 49: 1151
doi: 10.3969/j.issn.1001-9731.2018.01.028
[16] Luo Y B, Liu X H, Xie J X. Effects of running conditions on the conductivity of copper cladding aluminum flat bars [J]. J. Univ. Sci. Technol. Beijing, 2009, 31: 1430
[16] 罗奕兵, 刘新华, 谢建新. 工作条件对铜包铝扁排导电性能的影响 [J]. 北京科技大学学报, 2009, 31: 1430
[17] Liang C L, Lin K L. The microstructure and property variations of metals induced by electric current treatment: A review [J]. Mater. Charact., 2018, 145: 545
doi: 10.1016/j.matchar.2018.08.058
[18] Huang H J, Jia Z, Yuan X G, et al. Simulation of the electric characteristics of Cu-Al-Cu cladding plate [J]. Spec. Cast. Nonferrous Alloys, 2007, 27: 354
[18] 黄宏军, 贾 真, 袁晓光 等. 铜-铝-铜复合板导电特性的模拟 [J]. 特种铸造及有色合金, 2007, 27: 354
[19] Zuo X J, Yuan X G, Dong F Y, et al. Effect of service condition on copper aluminum composite electrical performance [J]. Hot Work. Technol., 2017, 46(14): 135
[19] 左晓姣, 袁晓光, 董福宇 等. 服役条件对铜铝冷轧复合导电排性能的影响 [J]. 热加工工艺, 2017, 46(14): 135
[20] Zou J C, Gao X Y, Wang D, et al. Gradient alternating deformation mechanism of two metals and interface bonding mechanism of Cu/Al cold rolling composite process [J]. Mater. Charact., 2023, 201: 112989
doi: 10.1016/j.matchar.2023.112989
[21] Naseri M, Reihanian M, Borhani E. Bonding behavior during cold roll-cladding of tri-layered Al/brass/Al composite [J]. J. Manuf. Process., 2016, 24: 125
doi: 10.1016/j.jmapro.2016.08.008
[22] Fan J H, Li P F, Liang X J, et al. Interface evolution during rolling of Ni-clad stainless steel plate [J]. Chin. J. Mater. Res., 2021, 35: 493
doi: 10.11901/1005.3093.2020.168
[22] 范金辉, 李鹏飞, 梁晓军 等. 镍-不锈钢复合板轧制过程中界面的结合机制 [J]. 材料研究学报, 2021, 35: 493
doi: 10.11901/1005.3093.2020.168
[23] Jiang Z D, Zhu H W, Sun J W, et al. Microstructure and mechanical properties of high-temperature free-oxygen rolled Cu/1060Al bimetallic composite materials [J]. J. Mater. Res. Technol., 2024, 29: 1262
doi: 10.1016/j.jmrt.2024.01.184
[24] Dong H, Zhu D, Yang T Y, et al. Interface-dominated microstructure development and mechanical and electrical properties of Al/Cu multilayered composites prepared via multicomponent accumulative roll bonding [J]. J. Alloys Compd., 2025, 1017: 179149
doi: 10.1016/j.jallcom.2025.179149
[25] Ding F L, Guo Q Y, Hu B, et al. Influence of softening annealing on microstructural heredity and mechanical properties of medium-Mn steel [J]. Microstructures, 2022, 2: 2022009
doi: 10.20517/microstructures.2022.01
[26] Li X B, Yang Y, Xu Y S, et al. Deformation behavior and crack propagation on interface of Al/Cu laminated composites in uniaxial tensile test [J]. Rare Met., 2020, 39: 296
doi: 10.1007/s12598-018-0998-x
[27] Chang D X, Wang P, Zhao Y Y. Effects of asymmetry and annealing on interfacial microstructure and mechanical properties of Cu/Al laminated composite fabricated by asymmetrical roll bonding [J]. J. Alloys Compd., 2020, 815: 152453
doi: 10.1016/j.jallcom.2019.152453
[28] Yang Y Y, Chen H S, Zhou J, et al. Study on interface behavior and mechanical properties of Al/Cu laminated tubes fabricated by strong staggered spinning at room temperature [J]. J. Mater. Res. Technol., 2023, 25: 7307
doi: 10.1016/j.jmrt.2023.07.129
[29] Lei Z Q, Zhang B, Liu G L, et al. Study on microstructure evolution and fracture behavior of Al/Al/Cu multilayer composites [J]. J. Mater. Res. Technol., 2023, 25: 5307
doi: 10.1016/j.jmrt.2023.07.014
[30] Mo T Q, Chen Z J, Li B X, et al. Tailoring of interface structure and mechanical properties in ARBed 1100/7075 laminated composites by cold rolling [J]. Mater. Sci. Eng., 2019, A755: 97
[31] Xu R R, Liang N N, Zhuang L M, et al. Microstructure and mechanical behaviors of Al/Cu laminated composites fabricated by accumulative roll bonding and intermediate annealing [J]. Mater. Sci. Eng., 2022, A832: 142510
[32] Wang T, Li S, Ren Z K, et al. A novel approach for preparing Cu/Al laminated composite based on corrugated roll [J]. Mater. Lett., 2019, 234: 79
doi: 10.1016/j.matlet.2018.09.060
[33] Karimi A, Alizadeh M. Mechanical and electrical properties of Al/18Cu/3WC/3MoS2 multilayered hybrid composites fabricated by accumulative roll bonding [J]. Ceram. Int., 2024, 50: 25379
doi: 10.1016/j.ceramint.2024.04.269
[34] Zhao N. Numerical simulation on the forming process of Cu/A1 composite tube and distribution of current across the section [D]. Shenyang: Shenyang University of Technology, 2008
[34] 赵 娜. 铜铝复合管成形数值模拟及电流通过截面分布规律 [D]. 沈阳: 沈阳工业大学, 2008
[35] Sheng L Y. The study on the electrical properties and the cold rolling technique for copper and aluminum composite laminates [D]. Shenyang: Shenyang University of Technology, 2005
[35] 盛立远. 铜铝轧制复合板导电特性及复合技术的研究 [D]. 沈阳: 沈阳工业大学, 2005
[36] Jia Z. Research on the electric conductivity and interfacial thermal stability of Cu/A1 clad plate [D]. Shenyang: Shenyang University of Technology, 2007
[36] 贾 真. 铜铝复合母线排的电学性能及界面稳定性的研究 [D]. 沈阳: 沈阳工业大学, 2007
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