XPS STUDIES OF OXIDATION BEHAVIOR OF NICKEL AND THERMAL STABILITY OF SURFACE OXIDES

Acta Metall Sin

1988, Vol. 24

Issue (5): 431-435 DOI:

Current Issue | Archive | Adv Search

XPS STUDIES OF OXIDATION BEHAVIOR OF NICKEL AND THERMAL STABILITY OF SURFACE OXIDES

ZHAO Liangzhong;PAN Chenghuang Institute of Chemistry. Academia Sinica; Beijing

Cite this article:

ZHAO Liangzhong;PAN Chenghuang Institute of Chemistry. Academia Sinica; Beijing. XPS STUDIES OF OXIDATION BEHAVIOR OF NICKEL AND THERMAL STABILITY OF SURFACE OXIDES. Acta Metall Sin, 1988, 24(5): 431-435.

Download:

PDF(466KB)
Export: BibTeX | EndNote (RIS)

Abstract Surface oxidation of polycrystalline nickel foil in air and purewater at different temperatures and the thermal stability of the surface oxides havebeen investigated by means of XPS. In addition to NiO, Ni_2O_3 is formed especiallyafter long periods of air exposure. Nickel surfaces are much less reactive to purewater than to air. The thermal stability of the surface oxides is related to oxidativetemperature. The surface species of oxides formed by air exposure at temperaturesbelow 120℃ can be reduced into nickel metal after heating the sample in vacuumat 300℃ for only 10 minutes (in the case of room temperature) to 1 hour (in thecase of 120℃). This reduction is caused by reaction with surface carbon contami-nants. However, the surface species of nickel oxides formed by air exposure withheating at temperatures above 200℃ can not be reduced into metal after heatingthe sample in vacuum at 300℃ for 1 hour.

Key words: XPS nickel surface oxides thermal stability

Received: 18 May 1988

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

URL:

https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y1988/V24/I5/431

1 Ritchie I M, Scott G H, Fensham P J. Surf Sci, 1970; 19: 230 and references cited therein
2 Kim K S, Winograd N. Surf Sci, 1974; 43: 625．
3 Srinivasan A, Jagannathan K, Hegde M S, Rao C N R. Indian J Chem. 1979; 18A: 463
4 Schon G, Lundin S T, J Electron Spectrosc, 1972/73; 1: 105
5 Hirokawa K, Honda F, Oku M. J Electron Spectrosc, 1975; 6: 333
6 Cochran S J, Larkins F P. J Chem Soc, Faraday Trans, I, 1985; 81: 2179
7 Kim K S, Davis R E. J Electron Spectrosc, 1972/73; 1: 251
8 Larkins F P, Fensham P J. Trans Faraday Soc, 1970; 66: 1755
9 Deren J, Stoch J. J Catal, 1970; 18: 249
10 Norton P R, Tapping R L, Goodale J W. Surf Sci, 1977; 65: 13
11 Benndorf C, Nobl C, Thieme F. Surf Sci, 1982; 121: 249
12 Benndorf C, Nobl C. Surf Sci, 1984; 138: 292
13 Mathteu H J, Datta M, Landolt D. J Vac Sci Technol, 1985; A3 (2) : 331
14 Clark D T, Thomas H R, Dilks A, Shuttleworth D. J Electron Spectrosc, 1977; 10: 455
15 Holloway P H, Outlaw R A. Surf Sci, 1981; 11: 300&

[1]	WANG Lei, LIU Mengya, LIU Yang, SONG Xiu, MENG Fanqiang. Research Progress on Surface Impact Strengthening Mechanisms and Application of Nickel-Based Superalloys[J]. 金属学报, 2023, 59(9): 1173-1189.
[2]	JIANG He, NAI Qiliang, XU Chao, ZHAO Xiao, YAO Zhihao, DONG Jianxin. Sensitive Temperature and Reason of Rapid Fatigue Crack Propagation in Nickel-Based Superalloy[J]. 金属学报, 2023, 59(9): 1190-1200.
[3]	YUAN Jianghuai, WANG Zhenyu, MA Guanshui, ZHOU Guangxue, CHENG Xiaoying, WANG Aiying. Effect of Phase-Structure Evolution on Mechanical Properties of Cr₂AlC Coating[J]. 金属学报, 2023, 59(7): 961-968.
[4]	FENG Aihan, CHEN Qiang, WANG Jian, WANG Hao, QU Shoujiang, CHEN Daolun. Thermal Stability of Microstructures in Low-Density Ti₂AlNb-Based Alloy Hot Rolled Plate[J]. 金属学报, 2023, 59(6): 777-786.
[5]	HAN En-Hou, WANG Jianqiu. Effect of Surface State on Corrosion and Stress Corrosion for Nuclear Materials[J]. 金属学报, 2023, 59(4): 513-522.
[6]	YU Shaoxia, WANG Qi, DENG Xiangtao, WANG Zhaodong. Preparation and Size Effect of GH3600 Nickel-Based Superalloy Ultra-Thin Strips[J]. 金属学报, 2023, 59(10): 1365-1375.
[7]	ZHU Guoliang, KONG Decheng, ZHOU Wenzhe, HE Jian, DONG Anping, SHU Da, SUN Baode. Research Progress on the Crack Formation Mechanism and Cracking-Free Design of γ' Phase Strengthened Nickel-Based Superalloys Fabricated by Selective Laser Melting[J]. 金属学报, 2023, 59(1): 16-30.
[8]	YANG Qinzheng, YANG Xiaoguang, HUANG Weiqing, SHI Duoqi. Propagation Behaviors of Small Cracks in Powder Metallurgy Nickel-Based Superalloy FGH4096[J]. 金属学报, 2022, 58(5): 683-694.
[9]	YU Chun, XU Jijin, WEI Xiao, LU Hao. Research Status of Ductility-Dip Crack Occurring in Nuclear Nickel-Based Welding Materials[J]. 金属学报, 2022, 58(4): 529-540.
[10]	NIE Jinfeng, WU Yuli, XIE Kewei, LIU Xiangfa. Microstructure and Thermal Stability of Heterostructured Al-AlN Nanocomposite[J]. 金属学报, 2022, 58(11): 1497-1508.
[11]	LI Wenya, ZHANG Zhengmao, XU Yaxin, SONG Zhiguo, YIN Shuo. Research Progress of Cold Sprayed Ni and Ni-Based Composite Coatings: A Review[J]. 金属学报, 2022, 58(1): 1-16.
[12]	WANG Yihan, YUAN Yuan, YU Jiabin, WU Honghui, WU Yuan, JIANG Suihe, LIU Xiongjun, WANG Hui, LU Zhaoping. Design for Thermal Stability of Nanocrystalline Alloys Based on High-Entropy Effects[J]. 金属学报, 2021, 57(4): 403-412.
[13]	WANG Xiaobo, WANG Yongzhe, CHENG Xudong, JIANG Rong. Thermal Stability of AlCrON-Based Solar Selective Absorbing Coating in Air[J]. 金属学报, 2021, 57(3): 327-339.
[14]	HUANG Songpeng, PENG Can, CAO Gongwang, WANG Zhenyao. Corrosion Behavior of Copper-Nickel Alloys Protected by BTA in Simulated Urban Atmosphere[J]. 金属学报, 2021, 57(3): 317-326.
[15]	XU Jinghui, LI Longfei, LIU Xingang, LI Hui, FENG Qiang. Thermal-Stress Coupling Effect on Microstructure Evolution of a Fourth-Generation Nickel-Based Single-Crystal Superalloy at 1100^oC[J]. 金属学报, 2021, 57(2): 205-214.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed