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Acta Metall Sin  2024, Vol. 60 Issue (6): 802-816    DOI: 10.11900/0412.1961.2023.00045
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Phase Transformation Behaviors in the Heat-Affected Zones of Ferritic Heat-Resistant Steels Enabled by In Situ CSLM Observation
SHEN Yang1,2, GU Zhengman1, WANG Cong1()
1 School of Metallurgy, Northeastern University, Shenyang 110819, China
2 Jiangxi Key Laboratory of Forming and Joining Technology for Aerospace Components, Nanchang Hangkong University, Nanchang 330063, China
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SHEN Yang, GU Zhengman, WANG Cong. Phase Transformation Behaviors in the Heat-Affected Zones of Ferritic Heat-Resistant Steels Enabled by In Situ CSLM Observation. Acta Metall Sin, 2024, 60(6): 802-816.

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Abstract  

Fossil-fired thermal power generation has dominated China's electricity production for a long time, contributing to around 70% of the total capacity. Developing long-life ultra-supercritical thermal power units is essential for improving coal-fired power generation efficiency, reducing harmful gas emissions, and achieving national energy conservation and emission reduction targets. The assembly and manufacture of advanced heat-resistant steel grades are required to address the above demands, serving as crucial components driving the technological advancement of thermal power units. Heat-resistant steel grades P11, P22, and P91, which are Cr-Mo based ferritic, possess a range of highly attractive properties, such as excellent mechanical properties, excellent corrosion resistance, and relatively low construction costs. These steel grades are widely used in pressure vessels and pipelines focused on high-temperature applications. Fusion welding techniques are invariably necessary to weld such heat-resistant-grade steels before they are positioned in high-temperature service. However, it is worth noting that drastic solid-state phase transformations in the heat-affected zones (HAZs) during thermal welding cycles can profoundly influence the heterogeneous microstructures of welded joints, determining their final mechanical properties to a large extent. Furthermore, it seriously threatens the safe and stable operation of thermal power plants. High-temperature confocal scanning laser microscopy (CSLM) revolutionized traditional metallographic experiments, enabling real-time morphology and quantitative analysis tracking. This innovation has facilitated investigations into the kinetic phase transformation process and microstructure evolution in steels at high temperatures. In this work, the kinetics of phase transformation and microstructural evolution in the HAZs of P11, P22, and P91 ferritic heat-resistant steels during continuous cooling processes were systematically investigated using CSLM. The results revealed that bainite laths preferentially nucleate in the order of increasing difficulty in the energy barrier on austenite grain boundaries, inclusions, internal grain distortion areas, previous bainite laths, and grain interiors. Meanwhile, the growth characteristics of bainite/martensite laths were documented as the phase transformation progressed. It is revealed that bainite laths attach to prior austenite grain boundaries and the previous bainite, while martensite laths grow radially inside the prior austenite grains. Both bainite and martensite laths cease growing when they encounter grain boundaries or other laths, eventually forming an interlocking microstructure. Additionally, the growth rates of bainite/martensite laths in the HAZs of P11, P22, and P91 ferritic heat-resistant steels exhibited considerable variations as the temperature decreased. The analysis revealed that as the temperature decreased, the growth rate of laths in the coarse-grained heat-affected zone was considerably higher than that in the fine-grained heat-affected zone, which can be attributed to the increase in the degree of supercooling and prior austenite grain size.

Key words:  ferritic heat-resistant steel      heat-affected zone      solid-state phase transformation      in situ observation      high-temperature confocal scanning laser microscope     
Received:  07 February 2023     
ZTFLH:  TG111.5  
Fund: National Key Research and Development Program of China(2022YFE0123300);National Natural Science Foundation of China(U20A20277;52050410341;52150610494);Jiangxi Provincial Natural Science Foundation(20232BAB214054)
Corresponding Authors:  WANG Cong, professor, Tel: 15702435155, E-mail: wangc@smm.neu.edu.cn

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https://www.ams.org.cn/EN/10.11900/0412.1961.2023.00045     OR     https://www.ams.org.cn/EN/Y2024/V60/I6/802

SteelCMnPSSiCrMoVNNbNiFe
P110.1300.5400.01700.00300.5901.1200.5720.0030.00490.0030.590Bal.
P220.1410.5570.00490.00150.0922.3950.9670.0140.00490.0200.157Bal.
P910.1000.4500.01700.00500.3008.1500.9500.2100.04400.0600.170Bal.
Table 1  Chemical compositions of P11, P22, and P91 ferritic heat-resistant steels (mass fraction / %)
SteelNormalizingTempering
P11930oC, 52 min760oC, 91 min
P22930oC, 48 min750oC, 84 min
P911060oC, 30 min760oC, 60 min
Table 2  Heat treatment processes of P11, P22, and P91 ferritic heat-resistant steels
Fig.1  Thermal cycles employed for in situ observation under CSLM (CSLM—high-temperature confocal scanning laser microscope, CGHAZ—coarse-grained heat-affected zone, FGHAZ—fine-grained heat-affected zone)
Fig.2  CSLM images of the growth of bainite laths in the CGHAZ of P11 ferritic heat-resistant steel (a-i) (B1-B7 represent growing bainite laths, the same in Figs.3-5; Insets show partial enlarged bainite laths)
Fig.3  CSLM images of the growth of bainite laths in the FGHAZ of P11 ferritic heat-resistant steel (a-i) (Insets show partial enlarged bainite laths)
Fig.4  CSLM images of the growth of bainite laths in the CGHAZ of P22 ferritic heat-resistant steel (a-i) (Insets show partial enlarged bainite laths)
Fig.5  CSLM images of the growth of bainite laths in the FGHAZ of P22 ferritic heat-resistant steel (a-i) (Insets show partial enlarged bainite laths)
Fig.6  CSLM images of the growth of martensite laths in the CGHAZ of P91 ferritic heat-resistant steel (a-f) (M1-M11 represent growing martensite laths, the same below)
Fig.7  CSLM images of the growth of martensite laths in the FGHAZ of P91 ferritic heat-resistant steel (a-f)
Fig.8  Relationships between growth rate and temperature for bainite laths and martensite laths
Fig.9  Invers pole figures (IPFs) (a-c) and kernel average misorientation (KAM) maps (d-f) of the CGHAZ in P11 (a, d), P22 (b, e), and P91 (c, f) ferritic heat-resistant steels
Bainite lath (i)ΔT / oCV / (μm·s-1)
1123.79.4
2136.213.6
3158.98.4
4162.662.5
5162.99.3
6172.952.9
7179.371.2
8183.8128.2
9192.6162.4
10203.1174.9
Table 3  Calculated values of the degree of supercooling (ΔT) and growth rate (V) of bainite laths in P11 ferritic heat-resistant steel
SteelCGHAZFGHAZ
P1189.519.0
P2261.211.2
P9139.59.4
Table 4  Prior austenite grain sizes of the CGHAZ and FGHAZ in P11, P22, and P91 ferritic heat-resistant steels (μm)
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