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| INFLUENCES OF KF-AlF3 SOLVENT COMPOSITIONS ON THE INTERFACIAL REACTIONS BETWEEN ALUMINUM AND KBF4 |
| WANG Qingliang1, ZHAO Hongsheng2, SHEN Li2,LI Zhengguang2, ZHAO Jiuzhou1 |
1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2. Baotou Aluminum Co., Ltd., Baotou 014046 |
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Cite this article:
WANG Qingliang, ZHAO Hongsheng, SHEN Li,LI Zhengguang, ZHAO Jiuzhou. INFLUENCES OF KF-AlF3 SOLVENT COMPOSITIONS ON THE INTERFACIAL REACTIONS BETWEEN ALUMINUM AND KBF4. Acta Metall Sin, 2012, 48(6): 739-743.
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Abstract Al-B alloys are widely used in industries. Their manufacturing has attracted great attentions. Generally, the Al-B master alloys are manufactured by reacting KBF4 with molten aluminum. A lot of work has been done to investigate the effects of reaction technologies on the manufacturing of Al--B alloys. But little attentions were paid to the reaction mechanisms at the interface between the aluminum melt and the fluoride salt. The interfacial reactions between Al and KBF4 play a critical role in the production of Al--B master alloys. Investigations on the interfacial reactions in four different KF-AlF3 solvents were carried out. It was demonstrated that a boride layer formed at the interface for all the four solvents. There existed AlF3 between the boride layer and the aluminum melt when the eutectic KF-AlF3 solvent or the hypereutectic solvents were used. AlF3 formed by the reaction between BF3 and Al.
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Received: 15 February 2012
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