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Corrosion Behavior of AZ91D Magnesium Alloy in City Atmosphere |
LIN Cui; LI Xiaogang; LI Ming; WANG Fengping |
Corrosion and Protection Center; Key Laboratory for Corrosion; Erosion and Surface Technology of Beijing; University of Science and Technology Beijing; Beijing 100083 |
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Cite this article:
LIN Cui; LI Xiaogang; LI Ming; WANG Fengping. Corrosion Behavior of AZ91D Magnesium Alloy in City Atmosphere. Acta Metall Sin, 2004, 40(2): 191-196 .
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Abstract The surface morphology of corrosion layer, corrosion products and
structure of rust layer for AZ91D magnesium alloy in natural city
atmosphere were studied by SEM and XRD. The results show that
Mg(OH)2 layer forms at the initial corrosion period, then film
thickens and cracks appear with continued corrosion under cyclic
wet/dry conditions, in the end these cracks develop to reticulate
structure. The water vapour is easily condensed and the corrosives
gases, salt particles are easily absorbed in the cracks. Meanwhile,
the cracks provide the diffusion paths for oxygen and other corrosion pollutants
into matrix, which results in severe local corrosion. The
major corrosion products are Mg(OH)2, Al(OH)3,
Mg2CO3(OH)2•3H2O and Mg2(OH)3Cl•4H2O, which plays a partial role in
protecting the matrix, therefore slowing down the average corrosion rate of magnesium alloy in the latter periods.
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Received: 22 February 2003
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