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Effect of Mn and V on Hot Corrosion of TiAl Alloy |
JIN Guangxi; QIAO Lijie; GAO Kewei; KIMURA Takashi; HASHIMOTO Kenki$ |
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Cite this article:
JIN Guangxi; QIAO Lijie; GAO Kewei; KIMURA Takashi; HASHIMOTO Kenki$. Effect of Mn and V on Hot Corrosion of TiAl Alloy. Acta Metall Sin, 2004, 40(2): 179-184 .
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Abstract The effect of Mn and V on hot corrosion of TiAl in (Na, K)2SO4
melt at 900 ℃ has been investigated. The results show that there is
a little effect of Mn on hot-corrosion resistance and the scale
structure of TiAl alloy. TiAl and TiAl-Mn alloys have a low hot-corrosion
rate because the outer layer of the scale is mainly protective
Al2O3. Adding V, however, could change the structure of the scale,
and then increased hot corrosion rate of the TiAl and TiAl-Mn alloys by
one order of magnitude. For TiAl-V and TiAl-Mn-V alloys, the scale is
mainly TiO2, and minor Al2O3 and V2O5.
V2O5 can induce cyclic acidic dissolution of Al2O3.
As a result, the scale of the TiAl-V and TiAl-Mn-V alloys peeled off
locally at the early stage of hot corrosion, and the alloys have a large
hot-corrosion rate.
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Received: 10 April 2003
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