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STRUCTURAL STABILITY OF Co/C MULTILAYERS |
JIANG Enyong;BAI Haili;WANG Cunda;U.BOGLI(Tianjin University;Tianjin 300072)(Department of Applied Physics;Tianjin University;Tianjin 300072)(Manuscript received 1995-12-08;in revised form 1996-06-12) |
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Cite this article:
JIANG Enyong;BAI Haili;WANG Cunda;U.BOGLI(Tianjin University;Tianjin 300072)(Department of Applied Physics;Tianjin University;Tianjin 300072)(Manuscript received 1995-12-08;in revised form 1996-06-12). STRUCTURAL STABILITY OF Co/C MULTILAYERS. Acta Metall Sin, 1996, 32(10): 1068-1074.
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Abstract Thermal behaviours of Co/C multilayers prepared by a dual-facing-target sputtering system were studied by using X-ray diffraction,transmission electron microscopy,Raman spectroscopy,and X-ray photoelectron spectroscopy.The changes observed in the annealed Co/C multilayers include an expansion of modulation period,crystallization in the Co layers,changes of reflectivity at grazing incidence and Co-C compound formation.Below annealing temperature of 400℃,the expansion in modulation period is mainly due to the graphitization of the amorphous carbon layers,and the enhancement of the reflectance is dominantly caused by Co-C separation that is interpreted as positive enthalpy of Co-C mixing.By 500℃,the crystallization and agglomeration of Co layers induce an enormous period expansion and a serious decrease in reflectivity.A small amount of carbide is found to form at this temperature as occurred in some other annealed metal-carbon multilayer systems.
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Received: 18 October 1996
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