INFLUENCE OF CARBONATION ON THE CORROSION PERFORMANCE OF STEEL HRB335 IN SIMULATED CONCRETE PORE SOLUTION

doi:10.3724/SP.J.1037.2010.00508

Acta Metall Sin

2011, Vol. 47

Issue (1): 17-24 DOI: 10.3724/SP.J.1037.2010.00508

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INFLUENCE OF CARBONATION ON THE CORROSION PERFORMANCE OF STEEL HRB335 IN SIMULATED CONCRETE PORE SOLUTION

SHI Jinjie, SUN Wei, GENG Guoqing

College of Materials Science and Engineering, Jiangsu Key Laboratory of Construction Materials, Southeast University, Nanjing 211189

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SHI Jinjie SUN Wei GENG Guoqing. INFLUENCE OF CARBONATION ON THE CORROSION PERFORMANCE OF STEEL HRB335 IN SIMULATED CONCRETE PORE SOLUTION. Acta Metall Sin, 2011, 47(1): 17-24.

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Abstract Electrochemical impedance spectroscopy, cyclic voltammetry and potentiodynamic polarization were used to investigate the effect of the decrease in pH values of simulated concrete pore (SCP) solutions due to carbonation on the corrosion of steel HRB335. The results indicated that the stability and corrosion inhibition of passive film on the steel surface decrease with decreasing pH value of SCP solutions. In SCP solutions with pH values of 12.5 and 11.5, the stability of passive film is in a competitive balance, the competition results from the dissolution of passive film due to the decreasing pH and the protective effect of calcium-iron containing protective layer CaFe₂O₄ or deposit CaCO₃ formed on the steel surface. When the pH value decreased unceasingly (pH=10.5, 10.0), the stability of passive film decreased gradually, and the active uniform corrosion occurred on the steel surface.

Key words: steel corrosion carbonation simulated concrete pore solution electrochemical impedance spectroscopy cyclic voltammetry

Received: 26 September 2010

ZTFLH:

TG 174

Fund:

Supported by National Basic Research Program of China (No.2009CB623203), High Technology Research and Development Program of China (No.2008AA030704) and The Scientific Research Foundation of Graduate School of Southeast University (No.YBJJ1017)

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2010.00508 OR https://www.ams.org.cn/EN/Y2011/V47/I1/17

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