Please wait a minute...
Acta Metall Sin  2015, Vol. 51 Issue (5): 569-579    DOI: 10.11900/0412.1961.2014.00447
Current Issue | Archive | Adv Search |
TENSILE AND HIGH CYCLE FATIGUE PROPERTIES OF Ti-47Al-2Cr-2Nb DIRECTIONALLY SOLIDIFIED BY COLD CRUCIBLE METHOD
Hongsheng DING(),Zibo SHANG,Yongzhe WANG,Ruirun CHEN,Jingjie GUO,Hengzhi FU
National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001
Cite this article: 

Hongsheng DING, Zibo SHANG, Yongzhe WANG, Ruirun CHEN, Jingjie GUO, Hengzhi FU. TENSILE AND HIGH CYCLE FATIGUE PROPERTIES OF Ti-47Al-2Cr-2Nb DIRECTIONALLY SOLIDIFIED BY COLD CRUCIBLE METHOD. Acta Metall Sin, 2015, 51(5): 569-579.

Download:  HTML  PDF(12400KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

TiAl-based alloys have recently received considerable attention as one of the promising candidates for application in aero engine blades by replacing the Ni-based superalloys because of their unique properties, such as high specific strength, high specific stiffness and good oxidation resistance. However, there are some shortcomings limiting the application of TiAl-based alloys, namely, their brittleness and poor processing properties. Nevertheless, aero engine blades usually suffer a variety of cyclic loadings during the period of services, which finally results in fatigue failure. According to statistics, fatigue failure, mainly high cycle fatigue (HCF), occupies almost 80% failure modes of gas turbine blades in aero engines. Consequently, more and more researches about fatigue behavior of blade materials have been done in the last tens of years. However, there are less relevant results about TiAl-based alloys, especially HCF properties. Recently, the advancement of directional solidification (DS) of TiAl-based alloys using cold crucible has revealed that the ductility can be enhanced at room and elevated temperature. For purpose to verify the influence of DS structures on the tensile and HCF properties, TiAl-based alloy in composition with Ti-47Al-2Cr-2Nb (atomic fraction, %) was prepared and evaluated in this work. Directionally solidified Ti-47Al-2Cr-2Nb alloy ingots with different withdrawal rates (1.0, 1.2 and 1.4 mm/min) were prepared by cold crucible method under alter electromagnetic field in a vacuum furnace. Based on these ingots, macro and microstructures have been characterized by methods of digital camera, OM, SEM and XRD. Furthermore, the tensile properties at room and high temperature (800 ℃) as well as HCF properties at room temperature have been measured respectively. So, the relationship between microstructures and mechanical properties of TiAl-based alloy, especially HCF properties, was demonstrated reasonably and mechanism in which HCF cracks propagated was discussed. The results show that the comprehensive mechanical properties of Ti-47Al-2Cr-2Nb alloy can be significantly improved after directionally solidified using cold crucible. The tensile strength reaches 652 MPa at room temperature with the maximum elongation of 1.5%. Meanwhile, the tensile strength at 800 ℃ attains 490 MPa with the elongation of 5.0%. Based on the data of HCF test at room temperature with the stress ratio of 0.1, the equations of stress amplitude-number of cycles to failure (S-N) curve at different withdrawal rates are calculated. The fatigue limits are 300 and 247 MPa with the withdrawal rates of 1.0 and 1.2 mm/min, respectively, namely, with the increase of withdrawal rate, the fatigue fracture resistance decreases. The mode of HCF fracture of directionally solidified Ti-47Al-2Cr-2Nb alloy behaves in brittle cleavage fracture. And micro-cracks which can propagate along and perpendicular to the lamellae at the same time are observed between α2/g lamellae and around B2 phases.

Key words:  Ti-47Al-2Cr-2Nb alloy      directional solidification      cold crucible      tensile property      high cycle fatigue     
Received:  09 August 2014     
Fund: National Natural Science Foundation of China (Nos.51171053 and 51471062) and National Basic Research Program of China (No.2011CB605504)

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2014.00447     OR     https://www.ams.org.cn/EN/Y2015/V51/I5/569

Withdrawal rate v mm/min Power kW Ingot length mm Dummy height (initiation/end) mm Primer height (initiation/end) mm Feeding length mm
1.0 49 110.3 56/51 84/80 228.5
1.2 49 114.0 56/60 84/88 234.1
1.2 49 109.8 56/57 84/87 224.8
1.2 49 110.1 56/64 84/86 231.5
1.2 49 110.0 56/52 84/82 228.1
1.4 49 99.6 56/50 84/82 202.8
Table 1  Prcoess parameters of directionally solidified (DS) Ti-47Al-2Cr-2Nb alloy
Fig.1  Macrostructures of directionally solidified Ti-47Al-2Cr-2Nb alloy ingots at withdrawal rates of 1.0 mm/min (a), 1.2 mm/min (b) and 1.4 mm/min (c) (S/L—solid/liquid)
Fig.2  BSE images of lamellar microstructures of DS growth parts in directionally solidified Ti-47Al-2Cr-2Nb ingots at withdrawal rates of 1.0 mm/min (a), 1.2 mm/min (b) and 1.4 mm/min (c)
Fig.3  Macrostructures of cross-section at DS growth parts of directionally solidified Ti-47Al-2Cr-2Nb ingots at withdrawal rates of 1.0 mm/min (a), 1.2 mm/min (b) and 1.4 mm/min (c)
v / (mm·min-1) D / mm q / (°) l / mm
1.0 251 36.4 1.81
1.2 198 49.3 1.42
1.4 135 67.2 1.16
Table 2  Grain size, lamellar orientation and interlamellar spacing of directionally solidified Ti-47Al-2Cr-2Nb alloy at different withdrawal rates
Fig.4  XRD spectra of different parts of directionally solidified Ti-47Al-2Cr-2Nb alloy at withdrawal rate of 1.2 mm/min
Fig.5  Tensile stress-strain curves of directionally solidified Ti-47Al-2Cr-2Nb alloy with different withdrawal rates at room temperature
Fig.6  Fracture morphologies of directionally solidified Ti-47Al-2Cr-2Nb alloy with withdrawal rate of 1.2 mm/min at room temperature showing fracture patterns along and through lamellae fracture (a), river pattern (b), fracture step of lamellae (c) and lamellar tearing (d)
Fig.7  Tensile stress-strain curves of directionally solidified Ti-47Al-2Cr-2Nb with different withdrawal rates at 800 ℃
Fig.8  Fracture morphologies of directionally solidfied Ti-47Al-2Cr-2Nb under withdrawal rate of 1.2 mm/min at 800 ℃ showing fracure behaviors of lamellar cracking (a), lamellar tearing (b), fracture step of lamellae (c) and dimple (d)
Fig.9  Morphologies of directionally solidfied Ti-47Al-2Cr-2Nb alloy after high cycle fatigue (HCF) fracture
Fig.10  Stress-number of cycle to failure (S-N) curves of directionally solidified Ti-47Al-2Cr-2Nb alloy at withdrawal rates of 1.0 and 1.2 mm/min, respectively (σmax—the max of stress, σUTS—ultimate tensile strength)
Fig.11  Derived S-N curves of directionally solidfied Ti-47Al-2Cr-2Nb alloy at withdrawal rates of 1.0 and 1.2 mm/min, respectively
Fig.12  Fracture morphologies of directionally solidified Ti-47Al-2Cr-2Nb alloy at withdrawal rate of 1.2 mm/min after high cycle fatigue (HCF)
Fig.13  Macromorphology of directionally solidified Ti-47Al-2Cr-2Nb alloy at withdrawal rate of 1.0 mm/min after HCF withour fracture (a) and BSE images of area A at longitudinal direction (b) and area B at transverse direction (c) in Fig.13a
Fig.14  Schematics of interlamellar (a) and translamellar (b) fatigue crack propagation modes of directionally solidified Ti-47Al-2Cr-2Nb alloy (s—stress; the little black arrows show the directions of crack propagation)
[1] Lin J P, Zhang L Q, Song X P, Ye F, Chen G L. Mater China, 2010; 29(2): 1 (林均品, 张来启, 宋西平, 叶 丰, 陈国良. 中国材料进展, 2010; 29(2): 1)
[2] Suresh S. Fatigue of Materials. Cambridge: Cambridge University Press, 1998; 2: 345
[3] He Y H, Su B. Aeroengine, 2005; 31(2): 51 (何玉怀, 苏 彬. 航空发动机, 2005; 31(2): 51)
[4] Li Q H, Wang Y R, Wang J J. Aeroengine, 2003; 29(4): 16 (李其汉, 王延荣, 王建军. 航空发动机, 2003; 29(4): 16)
[5] Li J S, Zhang T B, Chang H, Kou H C, Zhou L. Mater China, 2010; 29(3): 1 (李金山, 张铁邦, 常 辉, ?寇宏超, 周 廉. 中国材料进展, 2010; 29(3): 1)
[6] Chen G L,Lin J P. Physical Metallurgy for the Structural Ordered Intermetallics. Beijing: Metallurgical Industry Press, 1999: 285 (陈国良,林均品. 有序金属间化合物结构材料物理金属学基础. 北京: 冶金工业出版社, 1999: 285)
[7] Kim Y W. Trans Nonferrous Met Soc China, 1999; 9: 298
[8] Yamaguchi M, Inui H. Acta Mater, 2000; 48: 307
[9] Kim S W, Wang P, Oh M H, Wee D M, Kumarb K S. Intermetallics, 2004; 12: 499
[10] Chan K S, Kim Y W. Acta Metall, 1995; 43: 439
[11] Qian J H, Qi X Z. Chin J Rare Met, 2002; 26: 477 (钱九红, 祁学忠. 稀有金属, 2002; 26: 477 )
[12] Fu H Z, Ding H S, Chen R R, Bi W S. Rare Met Mater Eng, 2008; 37: 565 (傅恒志, 丁宏升, 陈瑞润, 毕维生. 稀有金属材料与工程, 2008; 37: 565)
[13] Wang Y L, Ding H S, Bi W S, Guo J J, Fu H Z. Rare Met Mater Eng, 2006; 35: 1597 (王艳丽, 丁宏升, 毕维生, 郭景杰, 傅恒志. 稀有金属材料与工程, 2006; 35: 1597)
[14] Fu H Z, Shen J, Hao Q T, Li S M, Li J S. Chin J?Nonferrous Met, 2002; 12: 1081? (傅恒志, 沈 军, 郝启堂, 李双明, 李金山. 中国有色金属学报, 2002; 12: 1081)
[15] Pericleous K, Bojarevics V, Djambazov G. Appl Math Model, 2006; 30: 1262
[16] Sastry S M L, Lipsitt H A. Metall Trans, 1977; 8A: 299
[17] Henaff G, Gloanec A L. Intermetallics, 2005; 13: 543
[18] Zhang W J, Deevi S C, Chen G L. Intermetallics, 2002; 10: 403
[19] Jones P E, Eylon D. Mater Sci Eng, 1999; A263: 296
[20] Jha S K, Larsen J M, Rosenberger A H. Acta Mater, 2005; 53: 1293
[21] Zhang Y G,Han Y F,Chen G L,Guo J T,Wan X J,Feng D. Structural Intermetallics. Beijing: National Defense Industry Press, 2001: 705 (张永刚,韩雅芳,陈国良,郭建亭,万小景,冯 涤. 金属间化合物结构材料. 北京: 国防工业出版社, 2001: 705)
[22] Gloanec A L, Milani T, Henaff G. Int J Fatigue, 2010; 32: 1015
[23] Meyers M A, Mishra A, Benson D J. Prog Mater Sci, 2006; 51: 427
[24] Xu R P, Fu H M, Gao Z T. J Mech Strength, 1994; 16(1): 58 (徐人平, 傅惠民, 高镇同. 机械强度, 1994; 16(1): 58)
[25] Mine Y J, Fujisaki H, Matsuda M, Takeyama M, Takashima K. Scr Mater, 2011; 65: 707
[26] Kumpfer J, Kim Y W, Dimiduk D M. Mater Sci Eng, 1995; A192-193: 465
[27] Tsutsumi M, Takano S. Intermetallics, 1996; 4: 77
[28] Cao R, Lin Y Z, Hu D. Eng Fract Mech, 2008; 75: 4343
[29] Jones P E, Eylon D. Mater Sci Eng, 1999; A263: 296
[30] Laird C. Fracture, 1984; 84: 261
[1] LI Jiarong, DONG Jianmin, HAN Mei, LIU Shizhong. Effects of Sand Blasting on Surface Integrity and High Cycle Fatigue Properties of DD6 Single Crystal Superalloy[J]. 金属学报, 2023, 59(9): 1201-1208.
[2] MA Dexin, ZHAO Yunxing, XU Weitai, WANG Fu. Effect of Gravity on Directionally Solidified Structure of Superalloys[J]. 金属学报, 2023, 59(9): 1279-1290.
[3] ZHANG Jian, WANG Li, XIE Guang, WANG Dong, SHEN Jian, LU Yuzhang, HUANG Yaqi, LI Yawei. Recent Progress in Research and Development of Nickel-Based Single Crystal Superalloys[J]. 金属学报, 2023, 59(9): 1109-1124.
[4] WANG Di, HE Lili, WANG Dong, WANG Li, ZHANG Siqian, DONG Jiasheng, CHEN Lijia, ZHANG Jian. Influence of Pt-Al Coating on Tensile Properties of DD413 Alloy at High Temperatures[J]. 金属学报, 2023, 59(3): 424-434.
[5] SU Zhenqi, ZHANG Congjiang, YUAN Xiaotan, HU Xingjin, LU Keke, REN Weili, DING Biao, ZHENG Tianxiang, SHEN Zhe, ZHONG Yunbo, WANG Hui, WANG Qiuliang. Formation and Evolution of Stray Grains on Remelted Interface in the Seed Crystal During the Directional Solidification of Single-Crystal Superalloys Assisted by Vertical Static Magnetic Field[J]. 金属学报, 2023, 59(12): 1568-1580.
[6] SUN Tengteng, WANG Hongze, WU Yi, WANG Mingliang, WANG Haowei. Effect ofIn Situ 2%TiB2 Particles on Microstructure and Mechanical Properties of 2024Al Additive Manufacturing Alloy[J]. 金属学报, 2023, 59(1): 169-179.
[7] LI Yanqiang, ZHAO Jiuzhou, JIANG Hongxiang, HE Jie. Microstructure Formation in Directionally Solidified Pb-Al Alloy[J]. 金属学报, 2022, 58(8): 1072-1082.
[8] CHEN Ruirun, CHEN Dezhi, WANG Qi, WANG Shu, ZHOU Zhecheng, DING Hongsheng, FU Hengzhi. Research Progress on Nb-Si Base Ultrahigh Temperature Alloys and Directional Solidification Technology[J]. 金属学报, 2021, 57(9): 1141-1154.
[9] LIU Xianfeng, LIU Dong, LIU Renci, CUI Yuyou, YANG Rui. Microstructure and Tensile Properties of Ti-43.5Al-4Nb-1Mo-0.1B Alloy Processed by Hot Canned Extrusion[J]. 金属学报, 2020, 56(7): 979-987.
[10] ZHANG Xiaoli, FENG Li, YANG Yanhong, ZHOU Yizhou, LIU Guiqun. Influence of Secondary Orientation on Competitive Grain Growth of Nickel-Based Superalloys[J]. 金属学报, 2020, 56(7): 969-978.
[11] LI Yuancai, JIANG Wugui, ZHOU Yu. Effect of Nanopores on Tensile Properties of Single Crystal/Polycrystalline Nickel Composites[J]. 金属学报, 2020, 56(5): 776-784.
[12] YU Chenfan, ZHAO Congcong, ZHANG Zhefeng, LIU Wei. Tensile Properties of Selective Laser Melted 316L Stainless Steel[J]. 金属学报, 2020, 56(5): 683-692.
[13] WANG Xi,LIU Renci,CAO Ruxin,JIA Qing,CUI Yuyou,YANG Rui. Effect of Cooling Rate on Boride and Room Temperature Tensile Properties of β-Solidifying γ-TiAl Alloys[J]. 金属学报, 2020, 56(2): 203-211.
[14] LI Jiarong,XIE Hongji,HAN Mei,LIU Shizhong. High Cycle Fatigue Behavior of Second Generation Single Crystal Superalloy[J]. 金属学报, 2019, 55(9): 1195-1203.
[15] XU Qingyan,YANG Cong,YAN Xuewei,LIU Baicheng. Development of Numerical Simulation in Nickel-Based Superalloy Turbine Blade Directional Solidification[J]. 金属学报, 2019, 55(9): 1175-1184.
No Suggested Reading articles found!