Please wait a minute...
金属学报  2005, Vol. 41 Issue (3): 312-316     
  论文 本期目录 | 过刊浏览 |
Ni-Al涂层对Ti-22Al-26Nb合金抗氧化性能的影响
郭明虎; 王启民; 柯培玲; 崔玉友;宫骏;孙超;闻立时
中国科学院金属研究所金属腐蚀与防护国家重点实验室;沈阳 110016
Effect of Ni-Al coating on high temperature oxidation behaviors of Ti-22Al-26Nb alloy
GUO Minghu; WANG Qimin; KE Peiling; CUI Yuyou; GONG Jun; SUN Chao; WEN Lishi
State Key Laboratory for Corrosion and Protection; Institute of Metal Research; The Chinese Academy of Sciences; Shenyang 110016
引用本文:

郭明虎; 王启民; 柯培玲; 崔玉友; 宫骏; 孙超 ; 闻立时 . Ni-Al涂层对Ti-22Al-26Nb合金抗氧化性能的影响[J]. 金属学报, 2005, 41(3): 312-316 .
, , , , , , . Effect of Ni-Al coating on high temperature oxidation behaviors of Ti-22Al-26Nb alloy[J]. Acta Metall Sin, 2005, 41(3): 312-316 .

全文: PDF(344 KB)  
摘要: 采用爆炸喷涂技术在Ti-22Al-26Nb(原子分数, %)基体上制备了Ni-68.5Al(原 子分数, %)合金涂层, 涂层在退火后与基体结合良好. XRD分析表明, 退火后涂层主 要由β-NiAl以及少量Al3Ti和Al3Nb组成. 研究了Ni-Al涂层对Ti-22Al-26Nb合金在 800 ℃静态空气中氧化性能的影响. Ti-22Al-26Nb 合金氧化后主要生成了疏松多孔的 TiO2,其抗高温氧化性能很差. 施加Ni-Al涂层后,高温下生成了一层致密的Al2O3, 氧化动力学曲线满足抛物线规律,抗氧化性能显著提高.
关键词 Ti-22Al-26Nb合金Ni-Al涂层高温氧化    
Abstract:Ni-68.5Al (atomic fraction, %) coatings were prepared on an orthorhombic alloy Ti-22Al-26Nb (atomic fraction, %) by detonation gun spraying (DS). After annealing, the Ni-Al coatings have a good adherence with the substrate, and XRD shows that the coatings mainly composed of $\beta$-NiAl. The influence of Ni-Al coatings on the isothermal oxidation behaviors of Ti-22Al-26Nb was studied in static air at 800 ℃. For the alloy Ti-22Al-26Nb without coating, under high temperature oxidation a mixed oxide scale formed and consisted of TiO2, AlNbO4 and Al2O3, in which TiO2 is the dominant oxide phase and exhibits relatively poor oxidation resistance. The high temperature oxidation resistance of the specimens coated with Ni-Al coatings is remarkably improved due to the formation of a dense and adherent Al2O3scale.
Key wordsTi-22Al-26Nb alloy    Ni-Al coating    high temperature oxidation
收稿日期: 2004-05-09     
ZTFLH:  TG111.5  
[1] Leyens C. Oxid Met, 1999; 52: 475
[2] Rowe R G. Microstructure/Property Relationships in Titanium Aluminides and Their Alloys. Warrendale, PA: TMS, 1997: 387
[3] Leyens C, Gedanitz H. Scr Mater, 1999; 41: 901
[4] Lu B, Yang R, Cui Y Y, Wang F H, Shao G S, Tsakiropou-los P. Acta Metall Sin, 2002; 38: 55 (卢斌,杨锐,崔玉友,王福会,邵国胜,Tsakiropoulos P.金属学报,2002;38:55)
[5] Lu B, Yang R, Cui Y Y, Li D. Metall Mater Trans, 1998; 29A: 1279
[6] Warrier S G, Krishnamurthy S, Smith P R. Metall Mater Trans, 2000; 31A: 2205
[7] Mendez H P, Clemens H, Knabl W. Gamma Titanium Aluminides 1999, Warrendale, PA: TMS, 1999: 187
[8] Tang Z, Wang F, Wu W. Intermetallics, 1999; 7: 1271
[9] Gil A, Niewolak L, Shemet V, Singheiser L, Quadakkers W J. Report Forschungtzentrum Julich, No.3847, Julich, German, 2001
[10] Grabke H J. Intermetetallics, 1999; 7: 1153
[11] Haynes J A. Scr Mater, 2001; 44: 1147
[12] Pint B A. Oxid Met, 1998; 49: 531
[13] Zhang, Y, Haynes J A, Pint B A, Wright I G, Lee W Y. Surf Coat Technol, 2003; 163: 19
[14] Parker D W. Adv Mater Proc, 1991; 139: 68
[15] Kharlamov Y A. Thin Solid Films, 1978; 54: 271
[16] Lou H Y, Wang F H. Vaccum, 1992; 43: 757
[17] Wang Q M, Guo M H, Ke P L, Sun C, Huang R F, Wen L S. Acta Metall Sin, 2004; 40: 1265 (王启民,郭明虎,柯培玲,孙超,黄荣芳,闻立时.金属学 报,2004;40:1265)
[18] Massalskl B. Binary Alloy Phase Diagrams. Vol.1, 2nd ed., Materials Park, OH: ASM International, 1990: 184
[19] Kharlamov Y A. Mater Sci Eng, 1987; 93: 1
[20] Lang E. Coatings for High Temperature Applications. New York: Applied Science Publishers, 1983: 1
[21] Leyens C. Oxid Met, 1999; 52: 475
[22] Doychak J, Ruhle M. Oxid Met, 1989; 31: 431
[23] Brumm M W, Grabke H J. Corros Sci, 1992; 33: 1677
[24] Rybicki G C, Smialek J L. Oxid Met, 1989; 31: 275
[25] Pint B A, Martin J R, Hobbs L W. Solid State Ionics, 1995; 78: 99
[1] 沈朝, 王志鹏, 胡波, 李德江, 曾小勤, 丁文江. 镁合金抗高温氧化机理研究进展[J]. 金属学报, 2023, 59(3): 371-386.
[2] 徐文国, 郝文江, 李应举, 赵庆彬, 卢炳聿, 郭和一, 刘天宇, 冯小辉, 杨院生. 微量AlTiInconel 690合金高温氧化行为的影响[J]. 金属学报, 2023, 59(12): 1547-1558.
[3] 解磊鹏, 孙文瑶, 陈明辉, 王金龙, 王福会. 制备工艺对FGH4097高温合金微观组织与性能的影响[J]. 金属学报, 2022, 58(8): 992-1002.
[4] 丛鸿达, 王金龙, 王成, 宁珅, 高若恒, 杜瑶, 陈明辉, 朱圣龙, 王福会. 新型无机硅酸盐复合涂层制备及其在高温水蒸气环境的氧化行为[J]. 金属学报, 2022, 58(8): 1083-1092.
[5] 杨亮, 吕皓天, 万春磊, 巩前明, 陈浩, 张弛, 杨志刚. 综述:活性元素作用机理——氧化物“钉扎”模型[J]. 金属学报, 2021, 57(2): 182-190.
[6] 赵明雨,甄会娟,董志宏,杨秀英,彭晓. 新型耐磨耐高温氧化NiCrAlSiC复合涂层的制备及性能研究[J]. 金属学报, 2019, 55(7): 902-910.
[7] 高博, 王磊, 宋秀, 刘杨, 杨舒宇, 千叶晶彦. 预氧化对Co-Al-W基高温合金高温氧化和热腐蚀行为的影响[J]. 金属学报, 2019, 55(10): 1273-1281.
[8] 白银, 刘正东, 谢建新, 包汉生, 陈正宗. 预氧化处理对G115钢高温蒸气氧化行为的影响[J]. 金属学报, 2018, 54(6): 895-904.
[9] 曾宇翔,郭喜平,乔彦强,聂仲毅. Zr含量对Nb-Ti-Si基超高温合金组织及抗氧化性能的影响[J]. 金属学报, 2015, 51(9): 1049-1058.
[10] 骆蕾,沈以赴,李博, 胡伟叶. 搅拌摩擦焊搭接法制备TC4钛合金表面Al涂层及其高温氧化行为[J]. 金属学报, 2013, 49(8): 996-1002.
[11] 于大千,卢旭阳,马军,姜肃猛,刘山川,宫骏,孙超. 梯度NiCrAlY涂层的1000和1100 ℃氧化行为研究[J]. 金属学报, 2012, 48(6): 759-768.
[12] 肖旋 许辉 秦学智 郭永安 郭建亭 周兰章. 3种铸造镍基高温合金热疲劳行为研究[J]. 金属学报, 2011, 47(9): 1129-1134.
[13] 邱军 赵文金 Thomas Guilbert Jean-Luc Bechade. 3种锆合金的高温氧化行为[J]. 金属学报, 2011, 47(9): 1216-1220.
[14] 宋鹏 陆建生 张德丰 吕建国 李德江. La和Hf对CoNiCrAl合金涂层高温氧化行为的影响[J]. 金属学报, 2011, 47(6): 655-662.
[15] 徐朝政 姜肃猛 马军 宫骏 孙超. 两种电弧离子镀Ni-Co-Cr-Al-Si-Y涂层的高温氧化行为[J]. 金属学报, 2009, 45(8): 964-970.