金属学报  2012, Vol. 48 Issue (4): 441-449    DOI: 10.3724/SP.J.1037.2011.00633

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冷却方式对Nb-Ti微合金钢组织和性能及沉淀行为的影响

陈俊, 唐帅,刘振宇,王国栋

东北大学轧制技术及连轧自动化国家重点实验室, 沈阳 110819

EFFECTS OF COOLING PROCESS ON MICROSTRUCTURE, MECHANICAL PROPERTIES AND PRECIPITATION BEHAVIORS OF NIOBIUM-TITANIUM MICRO-ALLOYED STEEL

CHEN Jun, TANG Shuai, LIU Zhenyu, WANG Guodong

State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819

陈俊, 唐帅,刘振宇,王国栋. 冷却方式对Nb-Ti微合金钢组织和性能及沉淀行为的影响[J]. 金属学报, 2012, 48(4): 441-449.
, , , . EFFECTS OF COOLING PROCESS ON MICROSTRUCTURE, MECHANICAL PROPERTIES AND PRECIPITATION BEHAVIORS OF NIOBIUM-TITANIUM MICRO-ALLOYED STEEL[J]. Acta Metall Sin, 2012, 48(4): 441-449.

摘要 参考文献 相关文章 Metrics 全文: PDF(1115 KB)   摘要: 两阶段控制轧制后, 采用不同的冷却路径进行冷却, 研究冷却路径对 Nb-Ti微合金钢组织和性能及沉淀行为的影响. 结果表明, 超快冷+空冷冷却路径可获得细晶组织, 晶粒平均尺寸约为7.76 μm, 屈服强度高达425 MPa, 抗拉强度高达500 MPa. 超快冷+炉冷试样中存在细小的沉淀粒子, 沉淀粒子尺寸主要集中在2-7 nm, 而超快冷+空冷试样中只存在少量球形沉淀粒子, 轧后直接空冷可获得相间沉淀粒子. 不同冷却路径获得的热轧板在700 ℃下退火300 s后, 沉淀粒子发生明显的粗化; 退火处理后, 超快冷+炉冷试样的晶粒平均尺寸减小为6.47 μm, 相对于退火前, 其屈服强度和抗拉强度分别增加50和 30 MPa, 强度的增加主要源于细晶强化. 对于含0.03%Nb(质量分数)的 Nb-Ti微合金钢, 由于沉淀粒子的体积分数有限, 因此细晶强化效果远高于沉淀强化效果, 强度的变化与晶粒尺寸的变化具有很好的对应性. 另外, 加工硬化指数与晶粒尺寸密切相关, 随着晶粒平均尺寸的增加使加工硬化指数增加. 关键词 ： Nb-Ti微合金钢,  超快冷,  冷却路径,  组织和性能,  沉淀强化,  细晶强化,  加工硬化指数     Abstract：The tested steels were cooled to room temperature using different cooling paths after two-stage rolling, and effects of cooling paths on microstructure, mechanical properties and precipitation behaviors of Nb-Ti micro-alloyed steels were investigated. The results show the hot rolled plates with fine grain were produced at the cooling path of ultra fast cooling + air cooling, and the average grain size, lower yield strength and ultimate tensile strength are about 7.76 μm, 425 MPa and 500 MPa, respectively. The fine precipitation particles ranging from 2 nm to 7 nm were observed in the samples cooling with ultra fast cooling + furnace cooling, but are only a few globular precipitates in the samples cooling with ultra fast cooling + air cooling. The inter-phase precipitation was observed in samples cooling with air cooling after finish rolling. These plates with different cooling paths were annealed at 700 ℃ for 300 s. The precipitation particles were obviously coarsened during annealing. It can be found that the average grain size of the samples with cooling path of ultra fast cooling + furnace cooling is 6.47 μm and the increments of lower yield strength and ultimate tensile strength are about 50 and 30 MPa, respectively. The strength increment mainly depends on fine grain strengthening.For niobium-titanium micro-alloyed steels containing 0.03%Nb (mass fraction), because the volume fraction of precipitates is limited, grain boundaries strengthening is higher than precipitation hardening, making changes of strength be in good agreement with that of grain size. In addition, the strain hardening exponent is mainly related to average grain size, and strain hardening exponent increases with average grain size increasing. Key words： niobium-titanium micro-alloyed steel    ultra fast cooling    cooling path    microstructure and mechanical property    precipitation hardening    fine grain strengthening    strain hardening exponent 收稿日期: 2011-10-09      ZTFLH:  TG142.33   基金资助: 中央高校基本科研业务费专项资金项目N110607003和N100507002资助 作者简介: 陈俊, 男, 1982年生, 博士生 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 陈俊 唐帅 刘振宇 王国栋 44.8K 链接本文: https://www.ams.org.cn/CN/10.3724/SP.J.1037.2011.00633      或      https://www.ams.org.cn/CN/Y2012/V48/I4/441 [1] Yong Q L.  Secondary Phase in Steel. Beijing: Metallurgical Industry Press, 2006: 15     (雍启龙. 钢铁材料中的第二相. 北京: 冶金工业出版社, 2006: 15) [2] Duan X G, Cai Q W, Wu H B.  Acta Metall Sin, 2011; 47: 251     (段修刚, 蔡庆伍, 武会斌. 金属学报, 2011; 47: 251) [3] Fang S F, Zhang J.  Acta Metall Sin, 1990; 26: A228     (方淑芳, 张健. 金属学报, 1990; 26: A228) [4] Tang G Y, Zheng Y Z, Cai Q G, Zhu J.  Acta Metall Sin,1989; 25: A414     (唐国翌, 郑炀曾, 蔡其巩, 朱静. 金属学报, 1989; 25: A414) [5] Zrnika J, Kvackaj T, Pongpaybul A, Sricharoenchai P, Vilk J,Vrchovinsky V.  Mater Sci Eng, 2001; A319: 321 [6] Xue X H, Shan Y Y, Zheng L, Lou S N.  Mater Sci Eng,2006; A438: 285 [7] Mesplont C.  Proc 1th International Conf on Super-High Strength Steels, Rome, Italy: AIM, 2005 (CD-ROM) [8] Jiao D T, Cai Q W, Wu H B.  Acta Metall Sin, 2009; 45: 1111     (焦多田, 蔡庆伍, 武会斌. 金属学报, 2009; 45: 1111) [9] Arribas M, Lopez B, Rodriguez-Ibabe J M.  Mater Sci Eng,2008; A485: 383 [10] Dutta B, Sellars C M.  Mater Sci Technol, 1987; 3: 197 [11] Liu W J, Jonas J J.  Metall Trans, 1989; 20A: 689 [12] Abad R, Fernandez A I, Lopez B, Podriguez-Ibabe J M.  ISIJ Int,2001; 41: 1373 [13] Yu Q B, Wang Z D, Liu X H, Wang G D.  Mater Sci Eng, 2004; A379: 384 [14] Wu J B, Liu G Q, Wang H.  Acta Metall Sin, 2010; 46: 838      (吴晋彬, 刘国权, 王浩. 金属学报, 2010, 46: 838) [15] Fu L M, Shan A D, Wang W.  Acta Metall Sin, 2010; 46: 832      (付立铭, 单爱党, 王巍. 金属学报, 2010, 46: 832) [16] Bai D Q, Yue S, Sun W P, Jonas J J.  Metall Trans, 1993; 24A: 2151 [17] Maruyama N, Uemori R, Sugiyama M.  Mater Sci Eng, 1998; A250: 2 [18] Koch C C, Morris D G, Lu K, Inoue A.  MRS Bull, 1999; 24: 54 [19] Tsuji N, Ito Y, Saito Y, Minamino Y.  Scr Mater, 2002; 47: 893 [20] Song R, Ponge D, Raabe D.  Acta Mater, 2003; 53: 4881 [21] Cao J C.  PhD Thesis, Kunming University of Science and Technology, 2006      (曹建春. 昆明理工大学博士学位论文, 2006) [22] Wang Z D, Qu J B, Liu X H, Wang G D.  Acta Metall Sin, 2000; 36: 618      (王昭东, 曲锦波, 刘相华, 王国栋. 金属学报, 2000, 36: 618) [23] Akben M G, Bacroix B, Jonas J J.  Acta Metall, 1983; 31: 161 [24] Altuna M A, Lza-Mendia A, Gutierrez I.  3rd International Conf on Thermomechanical Proc Steels, Padova, Italy: Milano: AIM, 2008 (CD-ROM) [25] Davenport A, Honeycombe R.  Proc Roy Soc London, 1971; 322: 191 [26] Lagneborg R, Zajac S.  Metall Mater Trans, 2001; 32A: 39 [27] Andrews K W.  Iron Steel Inst, 1965; 203: 721 [1] 王磊, 刘梦雅, 刘杨, 宋秀, 孟凡强. 镍基高温合金表面冲击强化机制及应用研究进展[J]. 金属学报, 2023, 59(9): 1173-1189. 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