Please wait a minute...
金属学报  2006, Vol. 42 Issue (12): 1267-1273     
  论文 本期目录 | 过刊浏览 |
Mg-6Al-(Sr, Ca)合金的显微组织和蠕变性能
白 晶;孙扬善;薛 烽;薛 山;强 婧;陶卫健;刘海峰
东南大学材料科学与工程学院
Microstructures and creep properties of Mg-6Al based magnesium alloys with strontium and calcium addition
东南大学材料科学与工程系
引用本文:

白晶; 孙扬善; 薛烽; 薛山; 强婧; 陶卫健; 刘海峰 . Mg-6Al-(Sr, Ca)合金的显微组织和蠕变性能[J]. 金属学报, 2006, 42(12): 1267-1273 .

全文: PDF(1945 KB)  
摘要: 陶卫健, 刘海峰//金属学报.—2006;42(12).12671273 系统研究了Mg-6Al-2Sr和Mg-6Al-(1-2)Sr-1Ca合金在水冷模铸造和压铸态下的显微组织、力学及蠕变性能. Mg-6Al-2Sr合金的铸态组织由-Mg和沿枝晶界分布呈片状的-Mg+Al4Sr共晶相组成. 在Mg-6Al-2Sr基础上加入少量的Ca, 合金中的Al4Sr被Mg2Ca取代, 且出现了Mg-Al-Sr三元中间相, 合金的抗蠕变性能显著提高. 对蠕变后试样进行的扫描电镜观察表明, Mg-6Al合金中添加Sr和Ca后形成的中间相均具有很高的热稳定性. Mg-6Al-2Sr合金蠕变后的试样中出现了-Mg17Al12相的非连续析出; 而采用Sr和Ca复合合金化的试样显微组织在蠕变后无明显变化, 也未析出相, 因而显著地提高了合金的抗蠕变性能. 与水冷模铸造试样相比, 压铸试样具有更细的显微组织和更高的室温与高温力学性能, 但抗蠕变性能略低.
关键词 Mg-Al-(SrCa)合金压铸水冷模铸造    
Abstract:The microstructure, tensile and creep properties of Mg-6Al-2Sr and two Mg-6Al-(1-2)Sr-1Ca based alloys have been investigated. The results indicate that the as cast microstructure of Mg-6Al-2Sr alloy consists of the dendritic -Mg and lamellar Al4Sr intermetallics at grain boundaries. Calcium addition to Mg-6Al-2Sr alloy results in the formation of Mg2Ca compound and a Mg-Al-Sr ternary intermediate phase, and the significant improvement of creep properties. The SEM microstructure observations performed on the samples after creep tests reveal that the intermediate phases in the Mg-6Al based alloy alloys with Sr and Ca additions have high thermodynamic stability. Discontinuous precipitation of β-Mg17Al12 occurs in Mg-6Al-2Sr alloy during creep deformation, however, no obvious changes have been observed in the microstructure of the alloys with combined addition of Sr and Ca after creep tests. The die cast sample shows finer microstructure and higher room temperature and high temperature tensile properties while relatively lower creep resistance in comparison with the samples which were cast by water cooled mould.
Key wordsheat-resistant magnesium    strontium    calcium    die cast    water cooler mould    creep resistance
收稿日期: 2006-03-14     
ZTFLH:  TG146.22  
[1] Pekguleryuz M O. Mater Sci Forum, 2000; 350: 131
[2] Zeng R W, Ke W, Xu Y B, Han E H, Zhu Z Y. Acta Metall Sin, 2001; 37: 673 (曾荣伟,柯伟,徐永波,韩恩厚,朱自勇.金属学报,2001; 37:673)
[3] Pekguleryuz M O, Baril E. Mater Trans, 2001; 42: 1258
[4] Pekguleryuz M, Labelle P, Argo D, Baril E. In: Kaplan H I ed, 2003 Magnesium Technology, Warrendale, PA: Minerals, Metals and Materials Society, 2003: 201
[5] Luo A A. Int Mater Rev, 2004; 49: 13
[6] Luo A A, Powell B R. In: Hryn J ed., Magnesium Technology 2001, Warrendale, PA: Minerals, Metals and Materials Society, 2001: 137
[7] Pekguleryuz M O, Kaya A A. Adv Eng Mater, 2003; 5: 866
[8] Blum W, Watzinger B, Zhang P. Adv Eng Mater, 2000; 2: 349
[9] Zhang P, Watzinger B, Blum W. Phys Status Solidi, 1999; 175A: 481
[10] Pekguleryuz M O, Baril E. In: Hryn J ed., Magnesium Technology 2001, Warrendale, PA: Minerals, Metals and Materials Society, 2001: 119
[11] Yuan G Y, Sun Y S, Zhang W M, Bao Y H. Ada Metall Sin (Engl Lett), 2000; 13: 867
[12] Min X G, Sun Y S, Du W W, Xue F. J Southeast Univ (Nat Sci), 2002; 32: 409 (闵学刚,孙扬善,杜温文,薛烽.东南大学学报(自然科学版),2002;32:409)
[13] Regev M, Aghion E, Rosen A. Mater Sci Eng, 1997; A234- 236: 123
[14] Pekguleryuz M O, Baril E, Labelle P, Argo D. J Adv Mater, 2003; 35: 32
[15] Bradai D, Kadi H M. J Mater Sci, 1999; 34: 5331
[16] Xiao X L, Luo C P, Nie J F, Muddle B C. Acta Metall Sin, 2001; 37: 7 (肖晓玲,罗承萍,聂建锋,Muddle B C.金属学报,2001; 37:7)
[17] Bai J, Sun Y S, Xun S, Xue F, Zhu T B. Mater Sci Eng, 2006; A419: 181
[18] Mordike B L, Lukac P. In: Lorimer G W ed., Proc 3rd Int Magnesium Conf, London: Institute of Materials, 1996: 419
[1] 孙宝德, 王俊, 康茂东, 汪东红, 董安平, 王飞, 高海燕, 王国祥, 杜大帆. 高温合金超限构件精密铸造技术及发展趋势[J]. 金属学报, 2022, 58(4): 412-427.
[2] 刘日平, 马明臻, 张新宇. 块体非晶合金铸造成形的研究新进展[J]. 金属学报, 2021, 57(4): 515-528.
[3] 曹永友, 熊守美, 郭志鹏. 压铸压室内部界面传热反算模型的建立和应用*[J]. 金属学报, 2015, 51(6): 745-752.
[4] 祁明凡, 康永林, 周冰, 朱国明, 张欢欢. 强制对流搅拌流变压铸AZ91D镁合金的组织与性能*[J]. 金属学报, 2015, 51(6): 668-676.
[5] 王志胜, 陈祥, 李言祥, 张华伟, 刘源. B对铜合金压铸热作模具钢高温力学及热疲劳性能的影响*[J]. 金属学报, 2015, 51(5): 519-526.
[6] 万谦,赵海东,邹纯. 铝合金压铸件微观孔洞三维特征及分布的研究[J]. 金属学报, 2013, 49(3): 284-290.
[7] 王向杰 游国强 张均成 龙思远. 压铸AZ91D镁合金母材气孔在重熔过程的遗传性研究[J]. 金属学报, 2012, 48(12): 1437-1445.
[8] 吴孟武 熊守美. 考虑压室预结晶的镁合金压铸组织实验及模拟研究[J]. 金属学报, 2011, 47(5): 528-534.
[9] 韩志强 李金玺 杨文 赵海东 柳百成. 铝合金挤压铸造过程微观孔洞形成的建模与仿真[J]. 金属学报, 2011, 47(1): 7-16.
[10] 李帅君 熊守美 Mei Li John Allison. 压铸充型过程中卷气现象的数值模拟研究[J]. 金属学报, 2010, 46(5): 554-560.
[11] 吴孟武 熊守美. 基于改进CA方法的压铸镁合金微观组织模拟[J]. 金属学报, 2010, 46(12): 1534-1542.
[12] 单际国 张婧 郑世卿 陈武柱 任家烈. 压铸镁合金激光焊气孔形成原因的实验研究[J]. 金属学报, 2009, 45(8): 1006-1012.
[13] 韩志强 朱维 柳百成. 挤压铸造凝固过程热--力耦合模拟 I.数学模型及求解方法[J]. 金属学报, 2009, 45(3): 356-362.
[14] 朱维 韩志强 柳百成. 挤压铸造凝固过程热--力耦合模拟 II. 模拟计算及实验验证[J]. 金属学报, 2009, 45(3): 363-368.
[15] 李帅君 熊守美 Mei Li John Allison. 应用两相流模型模拟压铸充型过程的卷气现象[J]. 金属学报, 2009, 45(10): 1153-1158.