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金属学报    DOI: 10.11900/0412.1961.2025.00285
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700 ℃时效10000 h对Al、Si复合添加14Cr-ODS钢力学性能和组织稳定性的影响
李新乐1,2  王旗涛1,2  李尧志1,2  尹梦婕1,2  代华龙1,2  李艳芬2
Effects of Long-Term Thermal Aging at 700 °C up to 10000 h on Mechanical Properties and Microstructure of 14Cr-ODS Steel With the Addition of Al and Si
LI Xinle 1,2  WANG Qitao1,2  LI Yaozhi1,2  YIN Mengjie1,2  DAI Hualong1,2  LI Yanfen2
引用本文:

李新乐, 王旗涛, 李尧志, 尹梦婕, 代华龙, 李艳芬. 700 ℃时效10000 h对Al、Si复合添加14Cr-ODS钢力学性能和组织稳定性的影响[J]. 金属学报, DOI: 10.11900/0412.1961.2025.00285.

全文: PDF(2549 KB)  
摘要: 

在14Cr-氧化物弥散强化(ODS)铁素体钢基础上复合添加Al和Si可进一步提高耐腐蚀性能,然而其长期高温稳定性尚不明确,影响核反应堆服役安全。本工作通过向14Cr-ODS钢中分别复合添加4%Al + 0.6%Si和4%Al + 1.5%Si (质量分数),制备了0.6Si-ODS和1.5Si-ODS钢,通过EBSD和TEM表征及拉伸性能测试等,研究了700 ℃、10000 h长期时效对其组织演化和力学性能的影响及作用机理。结果表明,Si含量从0.6%增加至1.5%对ODS钢时效前后的微观组织及力学性能没有明显影响。热处理态ODS钢中,纳米氧化物均弥散析出,0.6Si-ODS钢中析出YAlO3 (YAP)、Y4Zr3O12、Y2(Zr0.6Ti0.4)2O7和Y2Si2O7等多种类型,除此之外,1.5Si-ODS钢中还生成少量200 nm富Si氧化物。其中1.5Si-ODS钢中纳米氧化物的平均尺寸约为(6.3 ± 0.8) nm,数量密度达到2.3 × 1023 m-3。700 ℃时效10000 h后,两种钢的显微硬度、室温和高温(700 ℃)拉伸性能与时效前相比均基本未发生变化,其中1.5Si-ODS钢在700 ℃时的抗拉强度仅从214 MPa变为210 MPa、延伸率从37.5%变为36.8%,表现出优异的稳定性,其高的延伸率优于绝大多数同类ODS钢。时效后两种ODS钢中的纳米氧化物结构、数量密度及尺寸等均未发生明显变化,并强烈钉扎晶界和阻碍位错运动,有效延缓组织回复,从而确保了力学性能的稳定性。

关键词 ODS钢组织演变纳米氧化物组织稳定性长时时效    
Abstract
Structural materials for generation-IV nuclear reactors must withstand extremely harsh environments involving high temperatures, corrosive coolants, and severe radiation, which render conventional nuclear structural materials ineffective. Owing to its excellent high-temperature stability, remarkable mechanical properties, and outstanding resistance to irradiation damage, oxide dispersion-strengthened (ODS) steel is considered a promising candidate for advanced nuclear power systems. The addition of Al and Si to 14Cr-ODS steel can improve its corrosion resistance. However, research on the long-term high-temperature stability of 14Cr-ODS steel with the addition of Al and Si, which is critical for ensuring reactor operational reliability, remains inadequate. In this study, the microstructural evolution, hardness and tensile - properties of two 14Cr-ODS steels containing 4%Al + 0.6%Si and 4%Al + 1.5%Si (designated as 0.6Si-ODS and 1.5Si-ODS, respectively) were investigated after long-term aging at 700 °C for 10000 h. The results showed that the addition of 0.6%–1.5% Si exerted no notable influence on the microstructure and mechanical properties of the steels before and after aging. Nanoparticles uniformly dispersed were identified as YAlO3, Y4Zr3O12, Y2(Zr0.6Ti0.4)2O7, and Y2Si2O7 by TEM. In addition, a small amount of 200 nm Si-rich oxide particles were found in 1.5Si-ODS steel. The nanoparticles with an average size of (6.3 ± 0.8) nm were observed in 1.5Si-ODS, whose number density reached 2.3 × 1023 m−3. After aging at 700 °C for 10000 h, the hardness and tensile properties of both the steels at room temperature and 700 °C remained essentially unchanged. The ultimate tensile strength of 1.5Si-ODS decreased only slightly from 214 MPa to 210 MPa, and the elongation decreased from 37.5% to 36.8% at 700 °C, which is markedly higher than that of most reported Si-containing ODS steels. Microstructural observations confirmed that the grain size, nanoparticle size, and number density of nanoparticles exhibited excellent stability. These stable nanoparticles continuously pinned grain boundaries, effectively hindering the movement of dislocations and recovery of grain or subgrain structures, ensuring the stability of mechanical properties.
Key wordsOxide dispersion strengthened (ODS)    Microstructural evolution    Nanoparticles    Thermal stability    Aging
收稿日期: 2025-09-25     
基金资助:国家自然科学基金(No. 52371126); 中国科学院战略性先导科技专项(No. XDA0410000); 中核集团领创项目(无)
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