表面喷丸处理对<strong>NiCrAlYSi</strong>涂层恒温氧化行为的影响

doi:10.11900/0412.1961.2020.00353

金属学报

2021, Vol. 57

Issue (5): 684-692 DOI: 10.11900/0412.1961.2020.00353

研究论文

本期目录 | 过刊浏览

表面喷丸处理对NiCrAlYSi涂层恒温氧化行为的影响

刘冠熙, 黄光宏, 罗学昆, 申造宇, 何利民(

), 李建平, 牟仁德

中国航发北京航空材料研究院航空材料先进腐蚀与防护重点实验室北京 100095

The Influence of Surface Shot Peening on the Isothermal Oxidation Behavior of NiCrAlYSi Coating

LIU Guanxi, HUANG Guanghong, LUO Xuekun, SHEN Zaoyu, HE Limin(

), LI Jianping, MU Rende

Aviation Key Laboratory of Science and Technology on Advanced Corrosion and Protection for Aviation Material, AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China

引用本文:

刘冠熙, 黄光宏, 罗学昆, 申造宇, 何利民, 李建平, 牟仁德. 表面喷丸处理对NiCrAlYSi涂层恒温氧化行为的影响[J]. 金属学报, 2021, 57(5): 684-692.
Guanxi LIU, Guanghong HUANG, Xuekun LUO, Zaoyu SHEN, Limin HE, Jianping LI, Rende MU. The Influence of Surface Shot Peening on the Isothermal Oxidation Behavior of NiCrAlYSi Coating[J]. Acta Metall Sin, 2021, 57(5): 684-692.

全文: PDF(14699 KB) HTML

摘要:

采用真空电弧离子镀工艺制备了NiCrAlYSi涂层，研究了NiCrAlYSi涂层表面喷丸处理对其恒温氧化行为的影响。结果表明，喷丸处理工艺可降低涂层表面粗糙度，提高涂层表面致密性和平整性。在恒温氧化过程中，经过喷丸处理后的涂层能减少O原子向内扩散从而避免异常氧化区的出现，同时形成的热生长氧化(TGO)层厚度更加均匀，通过0.4 MPa、5 min喷丸处理后，NiCrAlYSi涂层TGO层厚度生长速率较未喷丸处理涂层降低60%，抗氧化性能得到提高。

关键词 ： NiCrAlYSi涂层, 真空电弧离子镀, 喷丸, 恒温氧化, 热生长氧化层

Abstract：

Thermal barrier coatings (TBCs), which mainly comprise top and bond coats, have been applied to the hot components of gas turbine engines owing to their low thermal conductivity, high-temperature oxidation resistance, gas corrosion resistance, and so on. However, a thermally grown oxide (TGO) layer, which germinates between top and bond coats, has a considerable effect on the service life of TBCs. Moreover, the microstructure optimization and growth inhibition of a TGO layer are crucial. The surface modification of bond coat in TBCs has been introduced to reduce and optimize the growth rate of a TGO layer. Among these methods, the surface shot peening of bond coat has yet to be extensively elucidated at high service temperatures. Furthermore, the influence of surface shot peening on isothermal oxidation behavior has rarely been reported in literature. In the present research, NiCrAlYSi coating was prepared using vacuum arc ion plating. The influence of the surface shot peening process on the isothermal oxidation behavior of NiCrAlYSi coating was investigated in detail, which indicated that the surface roughness of NiCrAlYSi coating reduced after the shot peeing. In this process, the compactness and smoothness of NiCrAlYSi coating improved, which could avoid the formation of an abnormal oxidation area in the coating due to the penetration and diffusion of oxygen atoms inside the coating. A uniform and low thickness deviation TGO layer could be generated at the surface. The TGO layer growth rate of NiCrAlYSi coating with 0.4 MPa and 5 min shot peening reduced by 60% compared to no shot peening, and the oxidation resistance of NiCrAlYSi coating improved.

Key words： NiCrAlYSi coating vacuum arc ion plating shot peening isothermal oxidation thermally grown oxide (TGO) layer

收稿日期: 2020-09-08

ZTFLH:

TG174.44

基金资助:中国科协第五届青年人才托举工程项目(2019-2021QNRC001)

作者简介: 刘冠熙，男，1993年生，硕士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	刘冠熙
	黄光宏
	罗学昆
	申造宇
	何利民
	李建平
	牟仁德
44.8K

链接本文:

https://www.ams.org.cn/CN/10.11900/0412.1961.2020.00353 或 https://www.ams.org.cn/CN/Y2021/V57/I5/684

表1 IC10合金和NiCrAlYSi涂层名义成分 (mass fraction / %)

表2 NiCrAlYSi涂层表面喷丸工艺参数

图1 NiCrAlYSi涂层不同喷丸工艺处理前后表面形貌的SEM像(a, b) P-0, without shot peening process (c, d) P-1 (e, f) P-2

图2 不同喷丸工艺处理前后NiCrAlYSi涂层截面形貌的SEM像(a) P-0 (b) P-1 (c) P-2

表3 不同喷丸工艺处理前后NiCrAlYSi涂层试样的质量变化 (g)

图3 不同喷丸工艺处理前后NiCrAlYSi涂层1050℃恒温氧化增重曲线

图4 NiCrAlYSi涂层1050℃恒温氧化200和600 h后截面形貌的SEM像(a, b) P-0 (c, d) P-1 (e, f) P-2

图5 P-1试样1050℃恒温氧化200 h后涂层截面SEM像和EDS分析

图6 NiCrAlYSi涂层1050℃恒温氧化1000 h后截面形貌的SEM像(a, b) P-0 (c) P-1 (d) P-2

图7 热生长氧化(TGO)层平均厚度随氧化时间的变化及TGO层预测生长曲线

图8 NiCrAlYSi涂层1050℃恒温氧化和TGO层生长基本原理图(a) initial stage (b) middle stage (c) critical stage

1	Padture N P, Gell M, Jordan E H. Thermal barrier coatings for gas-turbine engine applications [J]. Science, 2002, 296: 280
2	Clarke D R, Oechsner M, Padture N P. Thermal-barrier coatings for more efficient gas-turbine engines [J]. MRS Bull., 2012, 37: 891
3	Cao X Q. New Materials and Structures of Thermal Barrier Coatings [M]. Beijing: Science Press, 2016: 20
3	曹学强. 热障涂层新材料和新结构 [M]. 北京: 科学出版社, 2016: 20
4	Xu H B, Gong S K, Liu F S. Recent development in materials design of thermal barrier coatings for gas turbine [J]. Acta Aeronaut. Astronaut. Sin., 2000, 21: 7
4	徐惠彬, 宫声凯, 刘福顺. 航空发动机热障涂层材料体系的研究 [J]. 航空学报, 2000, 21: 7
5	Vaßen R, Jarligo M O, Steinke T, et al. Overview on advanced thermal barrier coatings [J]. Surf. Coat. Technol., 2010, 205: 938
6	Brandl W, Grabke H J, Toma D, et al. The oxidation behavior of sprayed MCrAlY coatings [J]. Surf. Coat. Technol., 1996, 86: 41
7	Yu D Q, Lu X Y, Ma J, et al. Study of oxidation behavior of the gradient NiCrAlY coating at 1000 and 1100^oC [J]. Acta Metall. Sin., 2012, 48: 759
7	于大千, 卢旭阳, 马军等. 梯度NiCrAlY涂层的1000和1100℃氧化行为研究 [J]. 金属学报, 2012, 48: 759
8	Feng Y, Dong T S, Li G L, et al. High temperature oxidation resistance and TGO growth mechanism of laser remelted thermal barrier coatings [J]. J. Alloys Compd., 2020, 828: 154266
9	Guan H R, Li M H, Sun X F, et al. Investigation on oxidation and failure of the thermal barrier coating deposited on superalloy [J]. Acta Metall. Sin., 2002, 38: 1133
9	管恒荣, 李美姮, 孙晓峰等. 高温合金热障涂层的氧化和失效研究 [J]. 金属学报, 2002, 38: 1133
10	Li M H, Zhang Z Y, Sun X F, et al. High temperature oxidation behavior of a EBPVD thermal barrier coating [J]. Acta Metall. Sin., 2002, 38: 989
10	李美姮, 张重远, 孙晓峰等. 电子束物理气相沉积热障涂层的高温氧化行为 [J]. 金属学报, 2002, 38: 989
11	Torkashvand K, Poursaeidi E, Mohammadi M. Effect of TGO thickness on the thermal barrier coatings life under thermal shock and thermal cycle loading [J]. Ceram. Int., 2018, 44: 9283
12	Tolpygo V K, Clarke D R, Murphy K S. Oxidation-induced failure of EB-PVD thermal barrier coatings [J]. Surf. Coat. Technol., 2001, 146-147: 124
13	Tolpygo V K, Clarke D R. Surface rumpling of a (Ni, Pt)Al bond coat induced by cyclic oxidation [J]. Acta Mater., 2000, 48: 3283
14	Balint D S, Kim S S, Liu Y F, et al. Anisotropic TGO rumpling in EB-PVD thermal barrier coatings under in-phase thermomechanical loading [J]. Acta Mater., 2011, 59: 2544
15	Davis A W, Evans A G. Effects of bond coat misfit strains on the rumpling of thermally grown oxides [J]. Metall. Mater. Trans., 2006, 37A: 2085
16	Shen Z Y, Huang G H, He L M, et al. Effect of surface treatments on lifetime and failure mechanism of thermal barrier coatings [J]. Rare Met. Mater. Eng., 2016, 45: 776
16	申造宇, 黄光宏, 何利民等. 表面处理对热障涂层寿命及失效机理的影响 [J]. 稀有金属材料与工程, 2016, 45: 776
17	Zhang D B, Gong S K, Xu H B, et al. Effect of bond coat surface roughness on the thermal cyclic behavior of thermal barrier coatings [J]. Surf. Coat. Technol., 2006, 201: 649
18	Tolpygo V K, Clarke D R, Murphy K S. The effect of grit blasting on the oxidation behavior of a platinum-modified nickel-aluminide coating [J]. Metall. Mater. Trans., 2001, 32A: 1467
19	Zhang H W, Zhang Y D, Wu Q. Numerical simulations of shot-peening process and impact effect [J]. Acta Metall. Sin., 2010, 46: 111
19	张洪伟, 张以都, 吴琼. 喷丸强化过程及冲击效应的数值模拟 [J]. 金属学报, 2010, 46: 111
20	Zhang J W, Lu L T, Zhang W H. Analysis on fatigue property of microshot peened medium carbon steel [J]. Acta Metall. Sin., 2009, 45: 1378
20	张继旺, 鲁连涛, 张卫华. 微粒子喷丸中碳钢疲劳性能分析 [J]. 金属学报, 2009, 45: 1378
21	Karaoglanli A C, Doleker K M, Demirel B, et al. Effect of shot peening on the oxidation behavior of thermal barrier coatings [J]. Appl. Surf. Sci., 2015, 354: 314
22	Guinard C, Montay G, Guipont V, et al. Residual stress analysis of laser-drilled thermal barrier coatings involving various bond coats [J]. J. Therm. Spray Technol., 2015, 24: 252
23	Ma K K, Schoenung J M. Isothermal oxidation behavior of cryomilled NiCrAlY bond coat: Homogeneity and growth rate of TGO [J]. Surf. Coat. Technol., 2011, 205: 5178
24	Tomimatsu T, Zhu S, Kagawa Y. Effect of thermal exposure on stress distribution in TGO layer of EB-PVD TBC [J]. Acta Mater., 2003, 51: 2397
25	Naumenko D, Shemet V, Singheiser L, et al. Failure mechanisms of thermal barrier coatings on MCrAlY-type bondcoats associated with the formation of the thermally grown oxide [J]. J. Mater. Sci., 2009, 44: 1687
26	Shen Z Y, Zhong B T, He L M, et al. LaZrCeO/YSZ TBCs by EB-PVD: Microstructural evolution, residual stress and degradation behavior [J]. Mater. Chem. Front., 2019, 3: 892
27	Shen Z Y, He L M, Xu Z H, et al. Morphological evolution and failure of LZC/YSZ DCL TBCs by electron beam-physical vapor deposition [J]. Materialia, 2018, 4: 340
28	Shen Z Y, He L M, Mu R D, et al. Effects of gradient transitional layer on thermal cycling life and failure of LaZrCeO/YSZ thermal barrier coatings [J]. Corros. Sci., 2020, 163: 108224
29	Sauer T, translated by Pei Y R, Ma G Y. Numerical Analysis [M]. Beijing: China Machine Press, 2014: 124
29	Sauer T著, 裴玉茹, 马赓宇译. 数值分析 [M]. 北京: 机械工业出版社, 2014: 124

[1]	黄鼎, 乔岩欣, 杨兰兰, 王金龙, 陈明辉, 朱圣龙, 王福会. 基体表面喷丸处理对纳米晶涂层循环氧化行为的影响[J]. 金属学报, 2023, 59(5): 668-678.
[2]	张聪惠, 荣花, 宋国栋, 胡坤. 喷丸表面粗糙度对纯Ti焊接接头在HCl溶液中应力腐蚀开裂行为的影响[J]. 金属学报, 2019, 55(10): 1282-1290.
[3]	高玉魁. 不同表面改性强化处理对TC4钛合金表面完整性及疲劳性能的影响^*[J]. 金属学报, 2016, 52(8): 915-923.
[4]	吴多利, 姜肃猛, 范其香, 宫骏, 孙超. 镍基高温合金Al-Cr涂层的恒温氧化行为^*[J]. 金属学报, 2014, 50(10): 1170-1178.
[5]	王维新姜肃猛卫广智马军宫骏孙超. NiCoCrAlYSiB+AlSiY梯度涂层恒温氧化行为[J]. 金属学报, 2011, 47(5): 578-586.
[6]	张洪伟张以都吴琼. 喷丸强化过程及冲击效应的数值模拟[J]. 金属学报, 2010, 46(1): 111-117.
[7]	张继旺鲁连涛张卫华. 微粒子喷丸中碳钢疲劳性能分析[J]. 金属学报, 2009, 45(11): 1378-1383.
[8]	栾卫志; 姜传海; 王浩伟 . TiB2/6351Al复合材料喷丸层再结晶过程X射线衍射分析[J]. 金属学报, 2008, 44(6): 671-674 .
[9]	王东林; 李家宝; 金涛; 杨胜群; 魏政; 胡壮麒; 付立群 . DZ4镍基高温合金的再结晶[J]. 金属学报, 2006, 42(2): 167-171 .
[10]	马素媛; 陈瑞; 贺笑春; 李家宝; 郝学卓 . 0Cr13Ni4Mo马氏体不锈钢表层的喷丸强化[J]. 金属学报, 2005, 41(1): 28-.
[11]	李东; 陈怀宁; 刘刚; 卢柯 . SS400钢焊接接头表层组织纳米均一化及硬度均一化处理[J]. 金属学报, 2001, 37(9): 980-984 .
[12]	刘道新; 何家文 . 喷丸强化因素对Ti合金微动疲劳抗力的作用[J]. 金属学报, 2001, 37(2): 156-160 .
[13]	盖秀颖;李家宝;康增桥;王中光;朱永平;李超. 60Mn钢喷丸表面的力学性能[J]. 金属学报, 1996, 32(6): 605-610.
[14]	徐可为;胡奈赛;何家文. 纯铜和黄铜喷丸强化的组织效应[J]. 金属学报, 1994, 30(1): 29-34.
[15]	姚枚;王声平;李金魁;王仁智;李向斌. 表面强化件的疲劳强度分析及金属的内部疲劳极限[J]. 金属学报, 1993, 29(11): 33-41.

Viewed

Full text

Abstract

Cited

Shared

Discussed