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Acta Metall Sin  1992, Vol. 28 Issue (11): 65-69    DOI:
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ISOTHERMAL CRYSTALLIZATION KINETICS OF AMORPHOUS (Fe (0.99)Cu_(0.01))_(78)Si_9B_(13) ALLOY
LIU Xuedong; WANG Jingtang (State Key Laboratory of RSA; Institute of Metal Research; Academia Sinica; Shenyang)
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LIU Xuedong; WANG Jingtang (State Key Laboratory of RSA; Institute of Metal Research; Academia Sinica; Shenyang). ISOTHERMAL CRYSTALLIZATION KINETICS OF AMORPHOUS (Fe (0.99)Cu_(0.01))_(78)Si_9B_(13) ALLOY. Acta Metall Sin, 1992, 28(11): 65-69.

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Abstract  Two stages of isothermal crystallization of the amorphous(Fe_(0.99)Cu_(0.01))_(78)Si_9B_(13) alloy were observed under examination by DSC together with XRD and TEM, i.e., precipitation of α-Fe(Si) solution and Fe_2B intermetallic compound. The nucleation and growth of both phases were analyzed based on the concept of local Avrami index and the crystallization "C" curve of the alloy was obtained. Comparison of activation energies of crystallization of both phases indicates that the precipitation of α-Fe(Si) is easier than that of Fe_2B. Meanwhile, an addition of Cu to the FeSiB glass may improve the morphology of α-Fe(Si) particles.
Key words:  Amorphous alloy      activation energy of crystallization      local Avrami index      (Fe_(0.99)Cu_(0.01))_(78)Si_9B_(13) alloy     
Received:  18 November 1992     
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