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NANO-REACTION PROCESS TO SYNTHESIZE ULTRAFINE Bi-Pb-Sr-Ca-Cu-O SUPERCONDUCTOR PRECURSOR POWDER WITH LOW CARBON CONTENT |
MAO Chuanbin;ZHOU Lian;WU Xiaozu;DU Zehua(Northwestern Institute for Nonferrous Metal Research; Baoji 721014)(Northeastern University; Shenyang;110006) |
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Cite this article:
MAO Chuanbin;ZHOU Lian;WU Xiaozu;DU Zehua(Northwestern Institute for Nonferrous Metal Research; Baoji 721014)(Northeastern University; Shenyang;110006). NANO-REACTION PROCESS TO SYNTHESIZE ULTRAFINE Bi-Pb-Sr-Ca-Cu-O SUPERCONDUCTOR PRECURSOR POWDER WITH LOW CARBON CONTENT. Acta Metall Sin, 1997, 33(5): 533-538.
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Abstract New process has been developed to synthesize ultrafine Bi-Pb-Sr-Ca-Cu-O superconductor precursor powder with high homogeneity. First, nanoparticle suspension is prepared from mixed cation solution, and thus the inhomogeneity is limitted in nanosize level.Second, nanoparticles are transformed into ultrafine oxide particles with suitable phase assemblages with agglomerate possibility minimized as possible as it can be, and thereby the ultrafine state of bismuth-based superconductor precursor powder with low carbon content (≈200 μg/g) is prepared in short time by this new process, which can sintered into high Tc superconductor at lower temperature.
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Received: 18 May 1997
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1 Flukiger R,Jeremie A,Hensel B,Seibt E,Xu J Q,Yamada Y.Adv Cryog Eng,1922;38:1073 2 Bhargave A, Yamashita T,Mackinnon I D.Physica C,1995;247:385 3 Wang L N,Zakharchenko I V,Muhammed M,Xu J H,Grisnin A M,Rao K V,Balachandran U.Supercond Sci Technol, 1995;8:94 4 Mao C B,Du Z H,Zhou L.Sci Chin,(Series E),1996;39:182 5梁敬魁,车广灿,陈小龙.高Tc氧化物超导体系的相关系和晶体结构.北京:科学出版社,1994:215 6 Teremie A,Almami-Yadri K,Grivel J C,Flukiger K F.Supercond Sci Technol,1994;6:73 |
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