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Acta Metall Sin  1997, Vol. 33 Issue (5): 533-538    DOI:
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NANO-REACTION PROCESS TO SYNTHESIZE ULTRAFINE Bi-Pb-Sr-Ca-Cu-O SUPERCONDUCTOR PRECURSOR POWDER WITH LOW CARBON CONTENT
MAO Chuanbin;ZHOU Lian;WU Xiaozu;DU Zehua(Northwestern Institute for Nonferrous Metal Research; Baoji 721014)(Northeastern University; Shenyang;110006)
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MAO Chuanbin;ZHOU Lian;WU Xiaozu;DU Zehua(Northwestern Institute for Nonferrous Metal Research; Baoji 721014)(Northeastern University; Shenyang;110006). NANO-REACTION PROCESS TO SYNTHESIZE ULTRAFINE Bi-Pb-Sr-Ca-Cu-O SUPERCONDUCTOR PRECURSOR POWDER WITH LOW CARBON CONTENT. Acta Metall Sin, 1997, 33(5): 533-538.

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Abstract  New process has been developed to synthesize ultrafine Bi-Pb-Sr-Ca-Cu-O superconductor precursor powder with high homogeneity. First, nanoparticle suspension is prepared from mixed cation solution, and thus the inhomogeneity is limitted in nanosize level.Second, nanoparticles are transformed into ultrafine oxide particles with suitable phase assemblages with agglomerate possibility minimized as possible as it can be, and thereby the ultrafine state of bismuth-based superconductor precursor powder with low carbon content (≈200 μg/g) is prepared in short time by this new process, which can sintered into high Tc superconductor at lower temperature.
Key words:  Bi-Pb-Sr-Ca-Cu-O superconductor      nano-reaction process      powder     
Received:  18 May 1997     
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