CALCULATING MODELS OF MASS ACTION CONCENTRATIONS FOR SEVERAL MOLTEN BINARY SALTS

Acta Metall Sin

1997, Vol. 33

Issue (5): 515-523 DOI:

Current Issue | Archive | Adv Search

CALCULATING MODELS OF MASS ACTION CONCENTRATIONS FOR SEVERAL MOLTEN BINARY SALTS

ZHANG Jian (University of Science and Technology Beijing; Beijing 100083)

Cite this article:

ZHANG Jian (University of Science and Technology Beijing; Beijing 100083). CALCULATING MODELS OF MASS ACTION CONCENTRATIONS FOR SEVERAL MOLTEN BINARY SALTS. Acta Metall Sin, 1997, 33(5): 515-523.

Download:

PDF(654KB)
Export: BibTeX | EndNote (RIS)

Abstract Calculating models of mass action concentrations have been formulated for molten binary salt systems involving solid solution, eutectic and compound formation respectively according to the condition that cations and anions combine together during reaction. The agreement between calculated and measured values is very well, while opposite results would get when the cations and the anions separate from each other. This shows that the cations and the anions combine together during reaction indeed, because of the deficiency of dielectric material for most molten salts.

Key words: activity molten salt cation and anion mass action concentration

Received: 18 May 1997

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

URL:

https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y1997/V33/I5/515

1张鉴.炉外精炼的理论与实践.北京:冶金工业出版社,1994:103
2张鉴.中国有色金属学报,待发表
3张鉴.1994年全国冶金物理化学学术会议论文集,广州,1994:122
4Zhang Jian.J Uni Sci Technol Beijing,1994;1:22
5 Mitsuru Ito,Tadasni Sasamoto,Toshiyuki Sta.Bull Chem Soc Jpn,1981;54:3391
6 Pelton A D,Gebriel A J.Chem Soc Faraday Trans,1985;18:1167
7 Wang Zhichang,Tian Yanwen,YU Hualong,Zhou Jiankang.Metall Trans,1992;23B:666
8 Levin E M,Robbins C R,Mcmurdie H F.Phase Diagrams for Ceramists.Columbus:The AmericanCeramic Society, 1964: 378
9 Thonstad J.Advances in Molten Salt Chemistry.Amsterdam:Mamantov G,Mamantov C B,Braunstein J 1987:77
10邱竹贤,冯乃祥.全国第五届冶金过程物理化学年会论文集(上册),1984:96
11 Knacke O,Kubaschewski O,Hesselmann K.Thermochemical Properties of Inorganic Substances II.Berlin:Springer-Verlag,1991:1359
12张鉴.北京钢铁学院论文集,北京:北京钢铁学院科学研究部,1962:71
13张鉴.北京钢铁学院学报,1984;6(1):2

[1]	JU Tianhua, SHU Nian, HE Wei, DING Xueyong. A Predicted Model for Activity Interaction Coefficient Between Solutes in Alloy Solutions[J]. 金属学报, 2023, 59(11): 1533-1540.
[2]	Rongyao MA, Lin ZHAO, Changgang WANG, Xin MU, Xin WEI, Junhua DONG, Wei KE. Influence of Hydrostatic Pressure on the Thermodynamics and Kinetics of Metal Corrosion[J]. 金属学报, 2019, 55(2): 281-290.
[3]	Xiaofeng LU, Ming XIAO, Yangmei CHEN, Bangcheng YANG. Bioactivity of Titanium Metal Hybridized with Inactivated Bacterial Biofilm[J]. 金属学报, 2017, 53(10): 1402-1412.
[4]	Muqin LI, Haitao YAO, Fanghong WEI, Mingda LIU, Zan WANG, Shuhao PENG. *The Microstructure and in Vivo* and in Vitro Property of Multi-Component Composite Films on the Biomedical Pure Magnesium Surface**[J]. 金属学报, 2017, 53(10): 1337-1346.
[5]	Tao LIU,Jiasheng DONG,Guang XIE,Yisheng WANG,Hui LI,Zhijun LI,Xingtai ZHOU,Langhong LOU. CORROSION BEHAVIOR OF GH3535 SUPERALLOY IN FLiNaK MOLTEN SALT[J]. 金属学报, 2015, 51(9): 1059-1066.
[6]	Xiaoyan CHEN,Zhe JIN,Xuefeng BAI,Yizhou ZHOU,Tao JIN,Xiaofeng SUN. EFFECT OF C ON THE INTERFACIAL REACTION AND WETTABILITY BETWEEN A Ni-BASED SUPERALLOY AND CERAMIC MOULD[J]. 金属学报, 2015, 51(7): 853-858.
[7]	Dongsong RONG,Yong JIANG,Jianming GONG. EXPERIMENTAL RESEARCH AND THERMODYNAMIC SIMULATION OF LOW TEMPERATURE COLOSSAL CARBURIZATION OF AUSTENITIC STAINLESS STEEL[J]. 金属学报, 2015, 51(12): 1516-1522.
[8]	YAN Yongde, YANG Xiaonan, ZHANG Milin, WANG Li, XUE Yun, ZHANG Zhijian. STUDY ON PREPARATION OF Al-Li-Gd ALLOYS BY ELECTROCHEMICAL CODEPOSITION FROM CHLORIDE MELTS[J]. 金属学报, 2014, 50(8): 989-994.
[9]	GONG Wenbiao, LI Renwei, LI Yupeng,SUN Daqian, WANG Wenquan. STABILIZATION AND CORROSION RESISTANCE UNDER HIGH-TEMPERATURE OF NANOSTRUCTURED CeO₂/ZrO₂-Y₂O₃ THERMAL BARRIER COATING[J]. 金属学报, 2013, 49(5): 593-598.
[10]	WANG Shulan CHEN Xiaoyun. STUDY ON THE ELECTRO–REFINING SILICON IN MOLTEN SALT CaCl2–NaCl–CaO[J]. 金属学报, 2012, 48(2): 183-186.
[11]	PENG Haijian JIN Jun LI Defu HU Jie. CORROSION BEHAVIORS OF Ni-Cr-Mo CORROSION RESISTENCE ALLOYS IN CaCl₂-CaF₂ MOLTEN SALT[J]. 金属学报, 2011, 47(9): 1195-1199.
[12]	LV Jiaxin; ZHENG Lei; ZHANG Maicang; DONG Jianxin. CORROSION BEHAVIOR OF NICKEL BASE ALLOY FGH95 IN MOLTEN NaCl–Na₂SO₄[J]. 金属学报, 2009, 45(2): 204-210.
[13]	WU Ling. The improvement of regular solution model based on GA-NN and its application in binary slag system[J]. 金属学报, 2008, 44(7): 799-802 .
[14]	;. Investigation on Preparation of Tb2Fe17 by Direct Electrochemical Reduction of Tb4O7-Fe2O3 Pellet in Molten Calcium Chloride[J]. 金属学报, 2008, 44(7): 859-862 .
[15]	;. EXPERIMENTAL RESEARCH OF PREPARATION OF CaB6 BY MOLTEN SALT ELECTROLYSIS METHOD[J]. 金属学报, 2008, 44(10): 1243-1246 .

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed