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Na_2SO_4 INDUCED HOT CORROSION OF Ni_3Al-Fe INTERMETALLIC COMPOUND AT INTERMEDIATE TEMPERATURES |
ZENG Chaoliu;ZHANG Jianqing;WU Weitao(Corrosion Science Laboratory; Institute of Corrosion and Protection of Metals; Chinese Academy of Sciences ;Shenyang)GUO Jianting (Institute of Metal Research; Chinese Academy of Sciences; Shenyang) |
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Cite this article:
ZENG Chaoliu;ZHANG Jianqing;WU Weitao(Corrosion Science Laboratory; Institute of Corrosion and Protection of Metals; Chinese Academy of Sciences ;Shenyang)GUO Jianting (Institute of Metal Research; Chinese Academy of Sciences; Shenyang). Na_2SO_4 INDUCED HOT CORROSION OF Ni_3Al-Fe INTERMETALLIC COMPOUND AT INTERMEDIATE TEMPERATURES. Acta Metall Sin, 1994, 30(21): 398-402.
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Abstract Ni_3Al-Fe suffers from catastrophic hot corrosion in the presence of Na_2SO_4 salt film at 700- 820 ℃,which may be ascribed to the formation of eutectic Na_2O-Na_2SO_4 melt produced by the reaction between Fe and Na_2SO_4 . Then, MoO_3, the oxidation product of Mo in the alloy, may also contribute to the electrochemical cathodic reduction, and induce rapid corrosion of Ni_3Al-Fe. The acidic conditions of molten salts established by the SO_3 produced by the reaction between Na_2SO_4 and MoO_3,and the internal sulphidation along substrate alloy may also accelerate the corrosion of Ni_3Al-Fe.
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1李辉,郭建亭,谭明晖,孙超,赖万慧,王淑荷,金属学报,1992;28:A3372沈华清,曾潮流,楼翰一,王福会,郭建亭,吴维.腐蚀科学与防护技术,1993;29:B4503曾潮流,张鉴清,吴维.材料工程,1993;119:14张允书,李连方,石声泰.中国腐蚀与防护学报,1990;10:2755沈华清,曾潮流,吴维,郭建亭.金属学报,1993;29:B4506SternKH,DeanhardtML,PanayappanRm.JPhysChem,1979;83:2848 |
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