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Acta Metall Sin  1994, Vol. 30 Issue (15): 121-125    DOI:
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INTERFACIAL EXCESS VOLUME IN NANOCRYSTALLINE Ni-P ALLOYS WITH DIFFERENT GRAIN SIZES
SUI Manling (Northeastern University; International Centre for Materials Physics;Chinese Academy of Sciences; Shenyang);LU Ke (Institute of Meial Research; Chinese Academy of Sciences; Shenyang)
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SUI Manling (Northeastern University; International Centre for Materials Physics;Chinese Academy of Sciences; Shenyang);LU Ke (Institute of Meial Research; Chinese Academy of Sciences; Shenyang). INTERFACIAL EXCESS VOLUME IN NANOCRYSTALLINE Ni-P ALLOYS WITH DIFFERENT GRAIN SIZES. Acta Metall Sin, 1994, 30(15): 121-125.

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Abstract  Nanocrystalline Ni-P alloy samples with grain sizes ranging from 13 nm to 107 nm have been prepared by the crystallization method. A positron annihilation spectroscopy technique was used to investigate the interfacial defects in these nanocrystalline samples.It was found that with a decrease of grain size,the excess volume in a unit volume of interfaces is reduced. By means of accurate density measurement and structural characteristic analyses of the nanocrystalline samples, the interfacial excess volume in the sample is found to be decreasing with reduction of grain size,i.e. a densification of interfaces.This result is in a good agreement with those from the positron annihilation experiments and from other property measurements.
Key words:  nanocrystalline materials      crystallization method. interfacial excess volume      Ni-P alloy      positron annihilation spectroscopy     
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