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Acta Metall Sin  1991, Vol. 27 Issue (1): 145-147    DOI:
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KINETICS OF INTERACTION BETWEEN PbS AND PbO·SiO_2
LI Cheng Beijing Central Engineering and Reseorch Institute for Non-Ferrous Metallurgical Industry; LIU Chunpeng Kunming Institute of Technology
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LI Cheng Beijing Central Engineering and Reseorch Institute for Non-Ferrous Metallurgical Industry; LIU Chunpeng Kunming Institute of Technology. KINETICS OF INTERACTION BETWEEN PbS AND PbO·SiO_2. Acta Metall Sin, 1991, 27(1): 145-147.

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Abstract  The kinetics of interaction between PbS and PbO.SiO_2 at 900--1100℃has been studied. A function F(α)=(0.5-α)/(1-α)~(5/3), α being the ratio of SO_2 evolvedin time τ to the total SO_2 to be escaped, is revealed as straight line on a plotagainst τ. The reaction seems to be under chemical or diffusion control during theprior or later stage, of which the activation energy calculated is △E=140 or △E_D=105.8 kJ/mol, respectively.
Key words:  kinetics      PbS      PbO.SiO_2      chemical control      diffusion control      activation energy     
Received:  18 January 1991     
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1 陆跃华,刘纯鹏.金属学报,1988;24:B50
2 Gaskell D R.见:中国金属学会编译组译,化学冶金进展评论.北京:冶金工业出版社,1985:97x
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