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Acta Metall Sin  1988, Vol. 24 Issue (2): 100-105    DOI:
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BEHAVIOR OF CERIUM IN GRAIN BOUNDARY SEGREGATION AND ITS INFLUENCE ON EQUILIBRIUM SEGREGATION OF PHOSPHORUS AT GRAIN BOUNDARIES IN α-IRON
ZHANG Dongbin Beijing University of Iron and Steel Technology WU Chengjian Department of Materials Science;Beijing University of Iron and Steel Technology
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ZHANG Dongbin Beijing University of Iron and Steel Technology WU Chengjian Department of Materials Science;Beijing University of Iron and Steel Technology. BEHAVIOR OF CERIUM IN GRAIN BOUNDARY SEGREGATION AND ITS INFLUENCE ON EQUILIBRIUM SEGREGATION OF PHOSPHORUS AT GRAIN BOUNDARIES IN α-IRON. Acta Metall Sin, 1988, 24(2): 100-105.

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Abstract  The equilibrium intergranular segregation of Ce and P in α-Fehas been analyzed by employing the combination of TEM+EDAX and AES. Theeffect of Ce on the equilibrium segregation of P and the embrittlement of the alloyshas also been studied in detail. The results show that there is cosegregation of Ceand P at the grain boundaries in Fe-0.3%P-0.16%Ce alloy. The addition of Ce doesnot decrease the equilibrium segregation of P, but significantly lowers the ductile-brittle transition temperature. The interaction between Ce and P at grain bounda-ries was discussed from the point of the interfacial two-dimensional phase.
Key words:  grain boundary segregation      cerium      phosphorus      embrittlement      TEM+ EDAX microanalysis      AES analysis     
Received:  18 February 1988     
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