HIGH TEMPERATURE CORROSION OF NANO-CRYSTALLINE METALLIC MATERIALS

doi:10.3724/SP.J.1037.2013.00604

Acta Metall Sin

2014, Vol. 50

Issue (2): 202-211 DOI: 10.3724/SP.J.1037.2013.00604

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HIGH TEMPERATURE CORROSION OF NANO-CRYSTALLINE METALLIC MATERIALS

PENG Xiao(

), WANG Fuhui

State Key Laboratory for Corrosion and Protection, Chinese Academy of Sciences, Shenyang 110016

Cite this article:

PENG Xiao, WANG Fuhui. HIGH TEMPERATURE CORROSION OF NANO-CRYSTALLINE METALLIC MATERIALS. Acta Metall Sin, 2014, 50(2): 202-211.

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Abstract

Some structural metallic materials, with only necessary to?be?“nanocrystallized” rather than to be increased with the contents of Cr and Al, have the ability to thermally grow a protective scale of Cr₂O₃ and Al₂O₃ at high temperature environments. Nanocrystallizationof alloys containing Cr or/and Al is an alternative to conventionally coating them with a high-Cr or/and high-Al material. High temperature corrosion behaviors of nanocrystalline metallic materials have been extensively reported in the past 20 years. In this paper, characteristics of high temperature corrosion of nanocrystalline metals, together with the fundamental reasons and questions desired to be clarified for the improvement of the corrosion resistance of alloys by nanocrystallization, were briefly reviewed.

Key words: nanocrystalline alloy high temperature corrosion selective oxidation adhesion

Received: 22 September 2013

ZTFLH:

TG172.5

Fund: Support by National Natural Science Foundation of China (No.51271189)

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	Xiao PENG
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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2013.00604 OR https://www.ams.org.cn/EN/Y2014/V50/I2/202

Fig.1

发生选择性氧化所需的Cr或Al临界含量随晶粒度的变化关系

Fig.2

Ni-Cr双相金属材料的选择性氧化过程示意图^[19]

Fig.3

Ni-10Cr双相金属材料在空气中900 ℃氧化15 min后的截面TEM形貌及相应的元素分布图

Fig.4

K52粗晶合金和纳米晶合金空气中1000 ℃氧化100 h后的截面形貌^[35]

Fig.5

Ni-25Cr-5Al-1S粗晶和纳米晶合金在空气中1000 ℃和304不锈钢及其纳米晶化后在900 ℃的氧化动力学曲线

Fig.6

304不锈钢及其纳米晶化后在含40%水蒸气的空气中在不同温度的氧化动力学曲线^[39]

Fig.7

Ni-25Cr-5Al-1S粗晶合金及其纳米晶化后在空气中1000 ℃氧化20 h后的截面TEM形貌及相应的元素分布图^[47]

Fig.8

Ni-25Cr-5Al-1S粗晶合金及其纳米晶化后在真空中1000 ℃退火1 h后的表面S的XPS分析结果^[47]

Fig.9

粗晶Ni₃Al空气中900 ℃循环氧化5次后的表面和截面形貌^[38]

Fig.10

粗晶Ni₃Al空气中900 ℃循环氧化5次后的截面形貌^[38]

Fig.11

超细晶Ni₃Al空气中900 ℃循环氧化100次后的截面形貌^[38]

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