PHASE FIELD SIMULATION OF THE EFFECT OF APPLIED EXTERNAL STRESS ON GROWTH KINETICS OF COHERENT Ni4Ti3 PRECIPITATE IN NiTi ALLOY
KE Changbo, MA Xiao, ZHANG Xinping
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640
Cite this article:
KE Changbo MA Xiao ZHANG Xinping. PHASE FIELD SIMULATION OF THE EFFECT OF APPLIED EXTERNAL STRESS ON GROWTH KINETICS OF COHERENT Ni4Ti3 PRECIPITATE IN NiTi ALLOY. Acta Metall Sin, 2010, 46(8): 921-929.
The presence and distribution of Ni4Ti3 particles in NiTi alloys have a significant influence on martensitic phase transformation path by favoring the formation of R–phase rather than B19’ phase since the latter produces larger lattice deformation. To deeply understand the above, some experimental studies have been done by using differential scanning calorimetry (DSC) and in situ transmission electron microscopy (TEM). Meanwhile, some preliminary simulations have also been performed focusing on the morphology evolution of single and multiple Ni4Ti3 variants in single NiTi alloy system as well as considering the effect of external loads on selective precipitate growth. Whereas, in engineering application, the NiTi alloys often undergo the external load which may affect the growth kinetics of Ni4Ti3 precipitates. Therefore, it is necessary to investigate the effect of applied load on growth kinetics of Ni4Ti3 precipitates. In this paper, the phase field method has been extended to study the microstructure evolution and growth kinetics of Ni4Ti3 precipitates in NiTi alloys during zero–stress and stress–assisted aging. The simulation results show that during stress–free aging, four groups of the variants precipitate along the corresponding (111)B2 habit plane; when the NiTi matrix is under <111>B2 comprssive stress–assisted aging, there is only one group of the variants with the normal lines parallel to <111>B2 to be precipitated. Although the uniaxial compressive stress apparently promotes the nucleation and slightly accelerates the growth of Ni4Ti3 variants in each group, the trends of aging time dependences of the area fraction, variant length, variant width and length–width ratio seem unchanged. The larger stresses can cause length and width of the variant slightly larger, but the area fraction of the Ni4Ti3 particles increases with increasing stress level. The simulation results are in good coincidence with the experimental results available.
Supported by National Natural Science Foundation of China (Nos. 50871039 and 50801029) and Chinese Government Graduate Student Overseas Study Program (No.2008615024)
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