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Acta Metall Sin  1989, Vol. 25 Issue (4): 41-47    DOI:
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MECHANISM OF NON-EQUILIBRIUM SEGREGATION OF SOLUTE TO GRAIN BOUNDARIES
CHU Youyi;ZHANG Sanhong;HE Xinlai;KE Jun T. Ko Beijing University of Science and Technology
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CHU Youyi;ZHANG Sanhong;HE Xinlai;KE Jun T. Ko Beijing University of Science and Technology. MECHANISM OF NON-EQUILIBRIUM SEGREGATION OF SOLUTE TO GRAIN BOUNDARIES. Acta Metall Sin, 1989, 25(4): 41-47.

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Abstract  In consideration of the local equilibrium among vacancies, solute atomsand vacancy-solute atom complexes, and the influence of equilibrium grain bound-ary segregation, theoretical dynamic formulas for non-equilibrium grain boundarysegregation of solute have been derived on the basis of the vacancy-draggingmechanism. Theoretical calculation by computer has been carried out for the non-equilibrium segregation of B to austenitic grain boundaries during isothermal hold-ing and continuous cooling after heating at high temperatures. The results agree wellwith those obtained from experiments.
Key words:  solute atoms      non-equilibrium segregation      boron      grain boundary     
Received:  18 April 1989     
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