|
|
CORROSION BEHAVIOR OF Mg-Zn-Y-Zr ALLOYS IN NaCl SOLUTION |
ZHANG Yacong, WANG Jincheng, LU Wenquan |
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072 |
|
Cite this article:
ZHANG Yacong WANG Jincheng LU Wenquan. CORROSION BEHAVIOR OF Mg-Zn-Y-Zr ALLOYS IN NaCl SOLUTION. Acta Metall Sin, 2011, 47(9): 1174-1180.
|
Abstract In recent years, Mg-Zn-Y-Zr alloys have attracted significant interest due to the high strength at room and elevated temperature. Current researches mainly focus on the microstructures and mechanical properties of Mg-Zn-Y-Zr alloys, however, the corrosion behaviors of Mg-Zn-Y-Zr alloys have been seldom studied. In the present paper, the mass loss corrosion and electrochemical corrosion behavior of three Mg-Zn-Y-Zr alloys with Zn contents of 4.3% (mass fraction), 6% and 8.6% in 5% (mass fraction) NaCl solution were studied, respectively. The morphology, microstructure and phase composition of these alloys after different immersion time were observed. The results showed that the type of second phase and the content of Zn in these alloys significantly affect their corrosion resistance performance and the Mg-Zn-Y-Zr alloy with 4.3% Zn exhibited better corrosion resistance. With the increase of Zn content, the W phase with stronger effect of galvanic corrosion formed at grain boundaries and the content of Zn in α-Mg matrix also increased, which resulted in the worse corrosion performance. Experimental results also showed that the corrosion process of Mg-4.3Zn-0.7Y-0.6Zr alloy can be divided into three stages: galvanic corrosion, Zr-rich zone-Zr--poor zone corrosion and pitting corrosion.
|
Received: 17 January 2011
|
|
Fund: Supported by Program for New Century Excellent Talents in University (No.NCET-09-0683) and Fund of the State Key Laboratory of Solidification Processing in NWPU (No.24-TZ-2009) |
[1] Li W X. Non–ferrous Metal Material Engineering Introduction. Beijing: Metallurgical Industry Press, 2007: 39(黎文献. 有色金属材料工程概论. 北京: 冶金工业出版社, 2007: 39)[2] Xu D K, Liu L, Xu Y B, Han E H. Acta Mater, 2008; 56: 985[3] Jia S C. PhD Thesis, Jilin University, 2006(贾素秋. 吉林大学博士学位论文, 2006)[4] Bae D H, Kim S H, Kim D H, Kim W T. Acta Mater, 2002; 50: 2343[5] Singh A, Nakamura A M, Watanabe M, Kato A, Tsai A P. Scr Mater, 2003; 49: 417[6] Popov I, Starosvetsky D, Shechtman D. J Mater Sci, 2000; 251: 1[7] Zhang E L, He W W, Du H, Yang K. Mater Sci Eng, 2008; A488: 102[8] Li Z J, Gu X N, Lou S Q, Zheng Y F. Biomaterials, 2008; 29: 1329[9] Song Y W, Shan D Y, Chen R S, Han E H. Corros Sci, 2010; 52: 1830[10] Zhang Y C, Wang J C, Zhang Q, L¨u W Q. Foundry Technol, 2010; 31: 1299(张亚丛, 王锦程, 张琪, 吕文泉. 铸造技术, 2010; 31: 1299)[11] Xu Y D, Hu S S, Zhu L P, Cheng F J, Zhu X R. Ordnance Mater Sci Eng, 2009; 32: 42(徐永东, 胡绳荪, 朱利萍, 程方杰, 朱秀荣. 兵器材料科学与工程, 2009; 32: 42)[12] Chang J W, Guo X W, Fu P H, Peng L M, Ding W J. Electrochim Acta, 2007; 52: 3160[13] Si L. Master Dissertation, Xi’an: Northwestern Polytechnical University, 2010(司林. 西安: 西北工业大学硕士学位论文, 2010)[14] Song G L, Atrens A, Dargusch M. Corros Sci, 1999; 41: 249[15] Xia L T, Gao S, Luo X P, Zang D M. Foundry, 2005; 15: 794(夏兰廷, 高珊, 罗小萍, 臧东勉. 铸造, 2005; 15: 794)[16] Chen X Y. Master Dissertation, Xi’an: Northwestern Polytechnical University, 2009(陈先毅. 西安: 西北工业大学硕士学位论文, 2009)[17] Lunder O, Lein J E, Aune T K, Nisancioglu K. Corrosion, 1989; 45: 74l |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|