Driving Force for the Nucleation from Supercooled Liquid and Thermodynamic Analysis of Glass Forming Ability for Binary Alloys

Acta Metall Sin

2008, Vol. 44

Issue (9): 1111-1115 DOI:

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Driving Force for the Nucleation from Supercooled Liquid and Thermodynamic Analysis of Glass Forming Ability for Binary Alloys

Na Wang;;Zhenmin Du

北京科技大学

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Na Wang; Zhenmin Du. Driving Force for the Nucleation from Supercooled Liquid and Thermodynamic Analysis of Glass Forming Ability for Binary Alloys. Acta Metall Sin, 2008, 44(9): 1111-1115 .

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Abstract Using CALPHAD technique and the reported thermodynamic parameters, the driving forces for the formations of all crystalline phases from supercooled liquid states were analyzed, and the composition ranges with low crystalline abilities but high glass forming abilities(GFA) are estimated thermodynamically for glass forming systems. The typical glass forming binary systems, Cu-Zr, Nb-Ni and Pd-Si, were selected and investigated, in which the eutectic depths of the equilibrium phase diagrams are visibly different. The compositional dependency of GFA was predicted in each alloy system, the best glass formers are obtained and are compared with the eutectic points and the experimental results. The present estimation can explain the experimental best formers for the bulk amorphous systems satisfactorily.

Key words: Supercooled liquid alloys Driving Force for the Nucleation Glass Forming Ability Thermodynamic Analy

Received: 14 January 2008

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https://www.ams.org.cn/EN/ OR https://www.ams.org.cn/EN/Y2008/V44/I9/1111

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