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Acta Metall Sin  2014, Vol. 50 Issue (11): 1294-1304    DOI: 10.11900/0412.1961.2014.00110
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THE EFFECT OF SACRIFICIAL ANODE ON CORRO- SION PROTECTION OF Q235B STEEL IN SIMULATED TIDAL ZONE
MU Xin, WEI Jie, DONG Junhua(), KE Wei
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
Cite this article: 

MU Xin, WEI Jie, DONG Junhua, KE Wei. THE EFFECT OF SACRIFICIAL ANODE ON CORRO- SION PROTECTION OF Q235B STEEL IN SIMULATED TIDAL ZONE. Acta Metall Sin, 2014, 50(11): 1294-1304.

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Abstract  

The environment of the tidal zone is very complex. The interactions of dry-wet alternation and sea erosion lead to serious corrosion of steel structures, which makes it difficult to adopt protective methods. Therefore, it is of great significance to study the corrosion and protection methods of steel in tidal zone. At present, the widely used protection method in tidal zone is coating which is effective in short term. However, it is easy to cause blister failure during the long-term service process, and it will increase the maintenance cost. Sacrificing anode protection is the most common method used in the seawater environment due to its advantages such as low cost, simple operation, no external current, no interference with adjacent metal facilities, good current dispersion ability, easy management and maintenance and high efficiency, etc.. However, in the tidal zone, sacrificial anode protective is effective only when the protected metal is in seawater immersion state. After the tide receded, the protected metal exposes in air. At this time, the current loop is destroyed, and the sacrificial anode protection effect is weakened. Therefore, it is commonly known that the sacrificial anode protection method can not protect the whole tidal zone against corrosion. At present, the corrosion process and mechanism of steel structures under sacrificial anode protection in the tidal zone are not clear. In order to study the corrosion mechanism of sacrificial anode protection, a corrosion experimental trough was designed to simulate the tidal zone and immersion zone. The electrode potential of Q235B mild steel under different protecting area of sacrificial anode in it was monitored in situ by the electrochemical workstation. The results show that under the sacrificial anode protection, the long scale specimen of Q235B steel is protected well, the corrosion degree in the tidal zone gradually reduces with the decrease of tide level, and the protected height increases with the increase of sacrificial anode area. Protective effect of sacrificial anode is mainly decided by the IR drop of specimen surface when the steel structures are exposed in the air, the smaller value of IR drop, the better protection effect. However, although the protection effect of steel structures can be improved by increasing the metal area of sacrificial anode, sometimes a part of steel structure may be in the state of excessive protection. The effective way to solve the corrosion problem of tidal zone needs to cooperate the sacrificial anode with other protective methods.

Key words:  laboratory simulation      tidal corrosion      mild steel      sacrificial anode      electrode potential     
Received:  08 August 2014     
ZTFLH:  TG172.5  
Fund: Supported by National Natural Science Foundation of China (No.51131007), National Basic Research Program of China (No.2014CB643300) and National Material Environmental Corrosion Platform

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2014.00110     OR     https://www.ams.org.cn/EN/Y2014/V50/I11/1294

Fig.1  Macro corrosion morphologies of Q235B steel without (a) and with sacrificial anode protection for specimens No.1 (b), No.2 (c) and No.3 (d) after corrosion for 60 d in the simulation tide system (Positions a, b, c and d indicate four test positions, HWL means high water level, LWL means low water level)
Fig.2  Micro corrosion morphologies of specimens No.1 (a1~a4), No.2 (b1~b4) and No.3 (c1~c4) on positions a (a1~c1), b (a2~c2), c (a3~c3) and d (a4~c4) with sacrificial anode protection on Q235B steel after corrosion for 60 d in the simulation tide system
Fig.3  XRD spectra of positions a (a), b (b), c (c) and d (d) on Q235B steel without and with sacrificial anode protection after corrosion for 60 d
Fig.4  Changes of tide height with time (The height of 0 means low water level, 400 means high water level)
Fig.5  Changes of open potential with corrosion time of Q235B steel without and with sacrificial anode protection, on positions a (a1~a3), b (b1~b3), c (c1~c3) and d (d1~d3) in 0~2 d (a1~d1), 28~30 d (a2~d2) and 58~60 d (a3~d3)
Specimen Stage Position a Position b Position c Position d
No.0 Initial stage -0.82~-0.68 -0.82~-0.62 -0.84~-0.75 -0.85~-0.80
Later stage -0.77~-0.63 -0.82~-0.72 -0.84~-0.77 -0.84~-0.79
Variation trend Up 0.05 Down 0.1 Down 0.02 Up 0.01
No.1 Initial stage -1.05~-0.77 -1.07~-0.72 -1.07~-0.70 -1.07~-1.05
Later stage -1.02~-0.67 -1.09~-0.72 -1.09~-0.95 -1.10~-0.98
Variation trend Up 0.1 Down 0.02 Down 0.25 Down 0.07
No.2 Initial stage -1.07~-0.75 -1.08~-0.72 -1.08~-0.70 -1.08~-1.06
Later stage -1.05~-0.70 -1.10~-0.75 -1.11~-0.95 -1.11~-1.03
Variation trend Up 0.05 Down 0.03 Down 0.25 Down 0.03
No.3 Initial stage -1.10~-0.73 -1.12~-0.70 -1.12~-0.80 -1.12~-1.11
Later stage -1.10~-0.72 -1.12~-0.85 -1.12~-0.95 -1.12~-1.11
Variation trend Up 0.01 Down 0.15 Down 0.15 Unchanged
Table 1  Variation range and overall trend of potential in four test positions in the simulation tide system
Fig.6  Changes of tide height of specimens No.0 (a1) and No.3 (a2), and changes of potential without sacrificial anode protection (No.0, b1~e1) and with sacrificial anode protection (No.3, b2~e2) with corrosion time, on positions a (b1, b2), b (c1, c2), c (d1, d2) and d (e1, e2) in the 20th day
Fig.7  Corrosion rate of Q235B steel under protected sacrificial anode (Nos.1~3) and real bare steel (No.0)[9]
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