金属学报  2006, Vol. 42 Issue (8): 857-860

论文 本期目录 | 过刊浏览 |

环氧涂层金属体系的串联双槽电化学阻抗谱分析

张金涛;胡吉明;张鉴清

常州工学院理学院

The analysis of EIS for serial double-cell of epoxy coated mild steels

JinTao Zhang

常州工学院理学院

张金涛; 胡吉明; 张鉴清 . 环氧涂层金属体系的串联双槽电化学阻抗谱分析[J]. 金属学报, 2006, 42(8): 857-860 .
, , . The analysis of EIS for serial double-cell of epoxy coated mild steels[J]. Acta Metall Sin, 2006, 42(8): 857-860 .

摘要 参考文献 相关文章 Metrics 全文: PDF(610 KB)   摘要: 应用电化学阻抗谱(EIS)技术以单槽和串联双槽两种方式测量了同一环氧涂层金属样品5个测试点在浸泡过程中阻抗行为的变化. 通过两种测试方式中涂层金属体系各测量点的极化电阻Rp(Rp=Rc+Rct+Rdiff)间的关联性, 说明了涂层金属的EIS双槽检测技术的可靠性. 实验结果表明: 同一样品两个测试点的阻抗差别较大时, 采用串联双槽测量的总阻抗值与其中的高阻抗测试点的阻抗值更为接近, 两个测试点单槽测量的Rp(Rc+Rct+Rdiff)之和(∑Rpi)与双槽测量的Rp间存在较大偏差;阻抗相近的两个测试点进行串联测量时, Rp近似等于两点分别以单槽方法所得Rp之和(∑Rpi); 两个测试点的阻抗均较小时, 串联后测得的Rp与两点单独测量的Rp之和间存在较大偏差. 关键词 ： 电化学阻抗谱,  环氧涂层,  串联双槽     Abstract：The single-cell and serial double-cell impedance measurements of five points on the same epoxy coating covered mild steel were performed by electrochemical impedance spectroscopy (EIS) technique. The reliability of double-cell method was demonstrated by the relationship between polarization resistance values (Rp, where Rp=Rc+Rct+Rdiff) of organic coated-metal systems with single-cell and double-cell measuring methods, respectively. The experimental results suggested that when the impedance difference of two epoxy coated-mild steel electrodes selected in the double-cell was large, the value of impedance of epoxy covered metal system with double-cell was close to that of the electrode with higher impedance, and the relative error between the sum of Rp of single-cells and Rp of double-cell was larger; for two electrodes with similar impedance values were in series, the Rp of double-cell was equal to the sum of Rp of two single-cells, and the relative error of these results was smaller; both impedance values of two electrodes were small and they were in series, one could find that Rp of double-cell was not the same as the sum of Rp of two single systems and there was larger relative error between these results. Key words： EIS    Organic coatings    Serial double-cell    Equivalent electrical circuit 收稿日期: 2005-11-30      ZTFLH:  TG174.3   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 张金涛 胡吉明 张鉴清 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2006/V42/I8/857 [1]Wel G K V D.Prog Organic Coat,1999;37:1 [2]Bellucci F,Nicodemo L,Monetta T.Corros Sci,1992;33:1203 [3]Scantlebury J D,Galic K.Prog Organic Coat,1997;31:201 [4]Amirudin A,Thierry D.Prog Organic Coat,1995;26:1 [5]Oliveira C G,Ferreira M G S.Corros Sci,2003;45:123 [6]Hu J M,Zhang J Q,Cao C N.Prog Organic Coat,2003;46:273 [7]Zhang J T,Hu J M,Zhang J Q,Cao C N.Prog Organic Coat,2004;49:293 [8]Zhang J T,Hu J M,Zhang J Q,Cao C N.Prog Organic Coat,2004;51:145 [9]Zhang J T,Hu J M,Zhang J Q,Cao C N.Corrosion,2005;61:872 [10]Murray J N.Prog Organic Coat,1997;30:225 [11]Wen G M,Cai C S,Liu B H,Guo J D,Su F T,Liu R X,Tian W D.J Chin Soc Corros Prot,1992;12:63(温国谋，蔡长寿，刘碧环，郭景东，苏方腾，刘仁新，田伟东．中国腐蚀与防护学报，1992；12：63) [12]Xie D M,Hu J M,Wang J M,Zhang J Q.Acta Metall Sin (Engl Lett),2002;15:299 [13]Lin Y H,Du R G,Hu R G,Lin C J.Acta Phys-Chim Sin,2005;21:740(林玉华，杜荣归，胡融刚，林昌健．物理化学学报，2005；21：740) [14]Cao C N,Zhang J Q.An Introduction to Electrochemical Impedance Spectroscopy.Beijing:Science Press,2002:156(曹楚南，张鉴清．电化学阻抗谱导论．北京：科学出版社，2002：156) [15]Xie D M.PhD Thesis,Zhejiang University,Hangzhou,2002(谢德明．浙江大学博士学位论文，杭州，2002) [16]Osborne J H,Blohowiak K Y,Taylor S R,Hunter C.Prog Organic Coat,2001;41:217 [17]Dehri I,Erbil M.Corros Sci,2000;42:969 [18]Grundmeier G,Thiemann P,Carpentier J,Barranco V.Surf Coat Technol,2003;174-175:996. [1] 夏大海, 计元元, 毛英畅, 邓成满, 祝钰, 胡文彬. 2024铝合金在模拟动态海水/大气界面环境中的局部腐蚀机制[J]. 金属学报, 2023, 59(2): 297-308. [2] 潘成成, 张翔, 杨帆, 夏大海, 何春年, 胡文彬. 三维石墨烯/Cu复合材料在模拟海水环境中的腐蚀和空蚀行为[J]. 金属学报, 2022, 58(5): 599-609. [3] 魏洁, 魏英华, 李京, 赵洪涛, 吕晨曦, 董俊华, 柯伟, 何小燕. 带损伤环氧涂层钢筋在Cl-和碳化耦合作用下的腐蚀行为[J]. 金属学报, 2020, 56(6): 885-897. [4] 操发春, 吴航, 杨延格, 曹京宜, 张涛, 王福会. γ-APS接枝环氧树脂分子对环氧涂层/金属界面化学键合的研究[J]. 金属学报, 2019, 55(2): 238-248. [5] 白杨, 王振华, 李相波, 李焰. 低压冷喷涂制备Al(Y)-30%Al2O3涂层及其海水腐蚀行为[J]. 金属学报, 2019, 55(10): 1338-1348. [6] 魏仁超, 许凤玲, 蔺存国, 唐晓, 李焰. 远青弧菌、硫酸盐还原菌及其混合菌种作用下 B10合金的海水腐蚀行为[J]. 金属学报, 2014, 50(12): 1461-1470. [7] 傅欣欣, 董俊华, 韩恩厚, 柯伟. 低碳钢Q235在模拟酸雨大气腐蚀条件下的电化学阻抗谱监测*[J]. 金属学报, 2014, 50(1): 57-63. [8] 周小卫,沈以赴. Ni－CeO2纳米镀层在酸性NaCl溶液中的腐蚀行为及电化学阻抗谱特征[J]. 金属学报, 2013, 49(9): 1121-1130. [9] 厉英,丁玉石,崔绍刚,王常珍. 掺杂Sc的CaZrO3的制备及电学性能[J]. 金属学报, 2012, 48(5): 575-578. [10] 张杰 宋秀霞 栾鑫 孙彩霞 段继周 侯保荣. 海藻希瓦氏菌对Zn-Al-Cd牺牲阳极的腐蚀性能影响[J]. 金属学报, 2012, 48(12): 1495-1502. [11] 郭少强 许立宁 常炜 密雅荣 路民旭. 3Cr管线钢CO2腐蚀实验研究[J]. 金属学报, 2011, 47(8): 1067-1074. [12] 黄发 王俭秋 韩恩厚 柯伟. 硼酸缓冲溶液中Cl-浓度和温度对690合金腐蚀行为的影响[J]. 金属学报, 2011, 47(7): 809-815. [13] 王长罡 董俊华 柯伟 陈楠. 硼酸缓冲溶液中pH值和Cl-浓度对Cu腐蚀行为的影响[J]. 金属学报, 2011, 47(3): 354-360. [14] 朱庆振 薛文斌 鲁亮 杜建成 刘贯军 李文芳. (Al2O3-SiO2)sf/AZ91D镁基复合材料微弧氧化膜的制备及电化学阻抗谱分析 制备及电化学阻抗谱分析[J]. 金属学报, 2011, 47(1): 74-80. [15] 宋利晓 张昭 张鉴清 曹楚南. 纳米结构黑镍薄膜的电沉积机理[J]. 金属学报, 2011, 47(1): 123-128. Viewed Full text Abstract Cited   Shared      Discussed