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MICROSEGREGATION OF SOLUTE ELEMENTS IN SOLIDIFYING MUSHY ZONE OF STEEL AND ITS EFFECT ON LONGITUDINAL SURFACE CRACKS OF CONTINUOUS CASTING STRAND |
CAI Zhaozhen; ZHU Miaoyong |
School of Materials and Metallurgy; Northeastern University; Shenyang 110004 |
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Cite this article:
CAI Zhaozhen ZHU Miaoyong. MICROSEGREGATION OF SOLUTE ELEMENTS IN SOLIDIFYING MUSHY ZONE OF STEEL AND ITS EFFECT ON LONGITUDINAL SURFACE CRACKS OF CONTINUOUS CASTING STRAND. Acta Metall Sin, 2009, 45(8): 949-955.
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Abstract The solidification of molten steel in continuous casting mold is a complicated nonequilibrium process with high cooling rate of 10—100 ℃/s. At such a cooling rate, the segregation of the solute elements such as C, Si, Mn, P and S in brittle temperature range (ΔθB) will vary with their initial contents and influence on the thermal strain significantly which could greatly increase the incidence of surface defects of strand. In this paper, a microsegregation model of solute elements in mushy zone with δ/γ transformation during solidification was established based on the regular hexagon transverse cross section of dendrite shape proposed by Ueshima by finite difference method under the non-equilibrium solidification condition at 10 ℃/s of cooling rate and the brittle temperaturerange ΔθB was determined. The distribution characteristics of solute elements and the effect of their segregations on ΔθB and thermal strin were nvestigatedTe results show that both P and S are the most serious segregation elements in final stage of solidification and affect on ΔθB sinificantly together with carbon content in molten steel. The mechanism that increasing contents of P and S may incrasthe probability of longitudinal surface crack for continuous casting strand was presented by calculatng the change law of thermal strain with carbn content under different of P and S contents.
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Received: 15 January 2009
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Fund: Supported by Program for New century Excellent Talents in University (No. NCET–04–0285) |
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