EFFECT OF TEMPERING TEMPERATURE ON CARBIDE AND MECHANICAL PROPERTIES IN A Fe-Cr-Ni-Mo HIGH-STRENGTH STEEL

doi:10.3724/SP.J.1037.2013.00672

Acta Metall Sin

2014, Vol. 50

Issue (4): 447-453 DOI: 10.3724/SP.J.1037.2013.00672

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EFFECT OF TEMPERING TEMPERATURE ON CARBIDE AND MECHANICAL PROPERTIES IN A Fe-Cr-Ni-Mo HIGH-STRENGTH STEEL

WEN Tao, HU Xiaofeng, SONG Yuanyuan, YAN Desheng, RONG Lijian(

)

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016

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WEN Tao, HU Xiaofeng, SONG Yuanyuan, YAN Desheng, RONG Lijian. EFFECT OF TEMPERING TEMPERATURE ON CARBIDE AND MECHANICAL PROPERTIES IN A Fe-Cr-Ni-Mo HIGH-STRENGTH STEEL. Acta Metall Sin, 2014, 50(4): 447-453.

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Abstract

The variation of carbides with tempering temperature in a Fe-Cr-Ni-Mo high-strength steel and their effect on mechanical properties are investigated by means of TEM and three-dimensional atom probe (3DAP). The results show that there mainly appear M₃C and M₇C₃ when tempering temperature is rather low (400 ℃), the former is thick with a length of about 1 μm and the latter is fine and the length is less than 200 nm, and M is composed of Fe, Cr and Mn. Tempering at 500 and 600 ℃, the amount of carbide increases gradually, and there appear M₂C and M₆C types of carbide which are both less than 200 nm in length, simultaneously M₃C becoming fine or disappear. When tempering temperature further increases to 650 ℃, besides M₂C there also appears MC type of carbide. The size of both M₂C and MC are less than 100 nm, meanwhile the amount of carbide decreases. The M of M₂C, M₆C and MC is a combination mainly of Cr, Mo and V. The strength of the Fe-Cr-Ni-Mo high-strength steel gradually reduces with increasing tempering temperature, but the downtrend of strength is rather small when tempering temperature is in the range of 500~600 ℃, owing to secondary hardening induced by the appearance of V-carbide. In short, the high-strength steel could obtain better combination of strength and impact toughness after tempering at about 530~600 ℃.

Key words: Fe-Cr-Ni-Mo high-strength steel carbide tempering temperature impact toughness at low- temperature

Received: 23 October 2013

ZTFLH:

TG161

Fund: Supported by National Natural Science Foundation of China (No.91226204)

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2013.00672 OR https://www.ams.org.cn/EN/Y2014/V50/I4/447

Fig.1

回火温度对Fe-Cr-Ni-Mo高强钢强度和延伸率的影响

Fig.2

回火温度对Fe-Cr-Ni-Mo高强钢低温(-50 ℃)冲击吸收功的影响

Fig.3

不同温度回火后Fe-Cr-Ni-Mo高强钢中碳化物的TEM像和SAED谱

表1 不同回火温度所对应的碳化物的类型、尺寸及成分

Fig.4

600 ℃回火2 h后碳化物形成元素的3D空间分布及浓度分布

[1]	Misra R D K, Jia Z, Malley R O, Jansto S J. Mater Sci Eng, 2011; A528: 8772
[2]	Lee K H, Park S G, Kim Min C, Lee B S, Wee D M. Mater Sci Eng, 2011; A529: 156
[3]	Lee B S,Kim M C,Yoon J H,Hong J H. Int J Press Ves Pip, 2010; 87: 74
[4]	Han S Y, Shin S Y, Seo C H, Lee H, Bae J H, Kim K, Lee S, Kim N J. Metall Mater Trans, 2009; 40A: 1851
[5]	Wang W, Shan Y Y, Yang K. Acta Metall Sin, 2007; 43: 578
	(王伟, 单以银, 杨柯. 金属学报, 2007; 43: 578)
[6]	Michael D M, David N S. Acta Mater, 2011; 59: 1881
[7]	Takashi O, Takashi W, Masanori A, Kazumi A. Nucl Eng Des, 2008; 238: 408
[8]	Liu Q D, Liu W Q, Wang Z M, Zhou B X. Acta Metall Sin, 2008; 44: 786
	(刘庆东, 刘文庆, 王泽民, 周邦新. 金属学报, 2008; 44: 786)
[9]	Liu Q D, Chu Y L, Wang Z M, Liu W Q, Zhou B X. Acta Metall Sin, 2008; 44: 1281
	(刘庆东, 楮于良, 王泽民, 刘文庆, 周邦新. 金属学报, 2008; 44: 1281)
[10]	Zhang Y. PhD Dissertation, Dalian Maritime University, 2007
	(张洋. 大连海事大学博士学位论文, 2007)
[11]	Zhang S H. Alloy-Steel. Beijing: Metallurgical Industry Press, 1981: 10, 37
	(章守华. 合金钢. 北京: 冶金工业出版社, 1981: 10, 37)
[12]	Qi Z F. Diffusion and Phase Transition in Solid Metals. Beijing: China Machine Press, 1998: 201
	(戚正风. 固态金属中的扩散与相变. 北京: 机械工业出版社, 1998: 201)
[13]	Janovec J, Vyrostkova A, Svoboda M. Metall Mater Trans, 1994; 25A: 267
[14]	Tao P, Zhang C, Yang Z G, Takeda H. Acta Metall Sin, 2009; 45: 51
	(陶鹏, 张弛, 杨志刚, 武田裕之. 金属学报, 2009; 45: 51)
[15]	Bjarbo A, Hattestrand M. Metall Mater Trans, 2001; 32A: 19
[16]	Pigrova G D. Metall Mater Trans, 1996; 27A: 498
[17]	Sun S W, Mao J F, Lei T Q, He L L. Acta Metall Sin, 2000; 36: 1009
	(孙树文, 茅建富, 雷廷权, 贺连龙. 金属学报, 2000; 36: 1009)
[18]	Liu Q D, Peng J C, Liu W Q, Zhou B X. Acta Metall Sin, 2009; 45: 1288
	(刘庆东, 彭建超, 刘文庆, 周邦新. 金属学报, 2009; 45: 1288)
[19]	Sun S W, Lei T Q, Tang Z X, You G, Wang X, Chen J L. Iron Steel, 1998; 33: 38
	(孙树文, 雷廷权, 唐之秀, 犹公, 王欣, 陈家伦. 钢铁, 1998; 33: 38)

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