UPCONVERSION WHITE PHOTOLUMINESCENCE AND FERROELECTRIC PROPERTY FOR Er3+-Tm3+- Yb3+ TRI-CODOPED Bi4Ti3O12 THIN FILM

doi:10.3724/SP.J.1037.2013.00503

Acta Metall Sin

2014, Vol. 50

Issue (1): 88-94 DOI: 10.3724/SP.J.1037.2013.00503

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UPCONVERSION WHITE PHOTOLUMINESCENCE AND FERROELECTRIC PROPERTY FOR Er³⁺-Tm³⁺- Yb³⁺ TRI-CODOPED Bi₄Ti₃O₁₂ THIN FILM

SUN Lina¹(

), TAN Jun^2,³, BA Dechun¹, YUAN Peixin¹

1 School of Mechanical Engineering and Automation, Northeastern University, Shenyang 110819
2 College of Sciences, Northeastern University, Shenyang 110819
3 Research Institute, Northeastern University, Shenyang 110819

Cite this article:

SUN Lina, TAN Jun, BA Dechun, YUAN Peixin. UPCONVERSION WHITE PHOTOLUMINESCENCE AND FERROELECTRIC PROPERTY FOR Er³⁺-Tm³⁺- Yb³⁺ TRI-CODOPED Bi₄Ti₃O₁₂ THIN FILM. Acta Metall Sin, 2014, 50(1): 88-94.

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Abstract

The Er³⁺-Tm³⁺-Yb³⁺ tri-codoped Bi₄Ti₃O₁₂ thin films were prepared by chemical solution deposition method and its upconversion (UC) photoluminescence and ferroelectric properties were studied. There are four emission bands in the visible UC luminescence spectra excited by 980 nm infrared light at room temperature. The 478 nm blue emission band corresponds to ¹G₄ → ³H₆ transition of Tm³⁺, and the 527, 548 nm green emission bands correspond to ²H_11/2→ ⁴I_15/2 and ⁴S_3/2 → ⁴I_15/2 transitions of Er³⁺, and the 657 nm red emission band corresponds to ⁴F_9/2 → ⁴I_15/2 transition of Er³⁺ and ¹G₄ → ³F₄ transition of Tm³⁺. The fluorescent color can be tuned by adjusting Er³⁺, Tm³⁺ and Yb³⁺ concentrations. For Bi_3.59-_xEr_xTm_0.01Yb_0.4Ti₃O₁₂ (BEr_xTYT) thin films with fixed Tm³⁺ and Yb³⁺ concentrations, the intensity ratio of green and red emissions to blue one gradually increased with the increase of Er³⁺ concentrations, and the quenching concentration of Er³⁺ is only about 1.75‰ (mole fraction). For Bi_3.593-_yEr_0.007Tm_yYb_0.4Ti₃O₁₂ (BETm_yYT) thin films with fixed Er³⁺ and Yb³⁺ concentrations, the intensity ratio of green and red emissions to blue one decreased with the increase of Tm³⁺ concentrations, and Tm³⁺ quenching concentration is about 2.5‰. For Bi_3.98-_zEr_0.01Tm_0.01Yb_zTi₃O₁₂ (BETYb_zT) thin films with fixed Er³⁺ and Tm³⁺ concentrations, the intensity ratio of blue or red emission to green one increase with increase of Yb³⁺ concentrations, and Yb³⁺ quenching concentration is less than 5 mol% for the luminescence from Er³⁺ and lager than 18 mol% for the luminescence from Tm³⁺. The optimal color coordinate in these films is (0.31, 0.34), close to standard white-light coordinate of (0.33, 0.33), which appears in Bi_3.5815Er_0.0085Tm_0.01Yb_0.4Ti₃O₁₂ thin film. The color coordinate has only a little change with increasing pumping power, which suggests that luminescence from the thin films has good color stability. There exist significant energy transfers from Er³⁺ to Tm³⁺, which will affect the relative intensities of blue, green and red emissions and their quenching concentrations by analyzing the UC emission mechanism of the thin films. The remnant polarization value of the film prepared on Pt/Ti/SiO₂/Si substrate reaches the maximum and is equal to 27.8 μC/cm² when the total codoping concentration of Er³⁺, Tm³⁺ and Yb³⁺ is about 10% (Bi_3.5815Er_0.0085Tm_0.01Yb_0.4Ti₃O₁₂ film).

Key words: white photoluminescence ferroelectric property upconversion thin film

Received: 20 August 2013

ZTFLH:

O484.4

Fund: Supported by Programs for Science and Technology Development of Liaoning Province(No.2012216033), Fundamental Research Funds for the Central Universities (No.N120403013), Programs for Science and Technology Development of Shenyang(No.F11-174-9-00) and Science and Technology Plan Project of Shenyang (No.F12-277-1-60)

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	Lina SUN
	Jun TAN
	Dechun BA
	Peixin YUAN

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https://www.ams.org.cn/EN/10.3724/SP.J.1037.2013.00503 OR https://www.ams.org.cn/EN/Y2014/V50/I1/88

Fig.1

在石英玻璃和Pt(111)/Ti/SiO₂/Si衬底上制备的Bi_3.5815Er_0.0085Tm_0.01Yb_0.4Ti₃O₁₂薄膜的XRD谱

Fig.2

980 nm红外光激发下 Bi_3.59-_xEr_xTm_0.01Yb_0.4Ti₃O₁₂(BEr_xTYT)薄膜的上转换荧光光谱

Fig.3

980 nm红外光激发下 Bi_3.593-_yEr_0.007Tm_yYb_0.4Ti₃O₁₂ (BETm_yYT) 薄膜的上转换荧光光谱

Fig.4

980 nm红外光激发下 Bi_3.98-_zEr_0.01Tm_0.01Yb_zTi₃O₁₂(BETYb_zT) 薄膜的上转换荧光光谱

Fig.5

980 nm的红外激光器在不同功率红外光激发下 Bi_3.585Er_0.005Tm_0.01Yb_0.4Ti₃O₁₂薄膜的上转换荧光光谱

Fig.6

980 nm红外光激发下BETYT薄膜的能级及上转换机制示意图

Fig. 7

在Pt(111)/Ti/SiO₂/Si衬底上制备Bi_3.5815Er_0.0085-Tm_0.01Yb_0.4Ti₃O₁₂薄膜的场强-极化磁滞回线

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