Please wait a minute...
Acta Metall Sin  2006, Vol. 42 Issue (6): 647-652     DOI:
Research Articles Current Issue | Archive | Adv Search |
Microstructure and Fracture of Pb-free Solder Interconnects in Ceramic Ball Grid Array Packages under Thermal Cycling
WANG Wei; WANG Zhongguang; XIAN Aiping; SHANG Jianku
中国科学院金属所
Cite this article: 

WANG Wei; WANG Zhongguang; XIAN Aiping; SHANG Jianku. Microstructure and Fracture of Pb-free Solder Interconnects in Ceramic Ball Grid Array Packages under Thermal Cycling. Acta Metall Sin, 2006, 42(6): 647-652 .

Download:  PDF(551KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  Microstructure and thermal fatigue behavior of Pb-free solder interconnects in ceramic ball grid array (BGA) packages were examined by cross-sectional microscopy, thermal cycling experiments and finite element modeling. The BGA assemblies were made by reflow soldering Sn-Ag-Cu solder balls between Ag-metallized multilayer ceramic chip and Cu-metallized printed circuit board using the eutectic Sn-Ag-Cu solder paste. In the as-reflowed condition, Cu6Sn5 and Ag3Sn intermetallic compounds (IMCs) were formed at the solder interfaces with Cu and Ag metallizations respectively. Following thermal cycling, the Cu6Sn5 layer grew thicker and Cu3Sn IMC was found at the interface with Cu metallization. On the ceramic side, visible thickening of the Ag3Sn layer was also observed. The Ag3Sn in the solder near the interface went through a morphological change from the needle shape to spherical. As a result of repeated thermal cycling, fatigue cracks developed in the solder interconnects. The fatigue crack appeared first at the corner of the solder ball with the chip, where the maximum shear stress was found by the finite element analysis. Subsequent growth of the fatigue cracks led to final fracture of the solder interconnects. The cracks preferred to propagate along the Cu6Sn5/solder interface on the side of the print circuit board and in the solder joint near the interfacial Ag3Sn layer on the ceramic side.
Key words:  Pb-free solder      interconnect      ceramic ball grid array (CBGA)      
Received:  01 November 2005     
ZTFLH:  TB302.3  
  TB303  

URL: 

https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2006/V42/I6/647

[1] Xie D J, Wang Z P. Finite Elem Anal Design, 1998; 30: 31
[2] IPC (Association Connecting Electronics Industries). Moisture/Reflow Sensitivity Classification for Nonher-metic Solid State Surface Mount Devices. Joint Industry Standard, IPC/JEDEC J-STD-020C, 2004
[3] Sharif A, Islam M N, Chan Y C. Mater Sci Eng, 2004; B13: 84
[4] Allen S L, Notis M R, Chromik R R, Vinci R P. J Mater Res, 2004; 19: 1417
[5] Tu P L, Chan C, Hung C, Lai J K L. Microelectron Reliab, 2001; 41: 87
[6] Tu P L, Chan C, Hung C, Lai J K L. Microelectron Reliab, 2001; 41: 1993
[7] Xu X H. Master Thesis, National Cheng Kung University, Taibei, 2002 (许修豪.国立成功大学硕士学位论文,台北, 2002)
[8] Ding Y, Wang C Q, Li M Y, Wang W Q. Mater Sci Eng, 2006; B127: 62
[9] Lin Y C, Chen X, Liu X S, Lu G Q. Microelectron Reliab, 2005; 45: 143
[10] Jen Y-M, Wu Y-L, Fang C-K. Microelectron Reliab, 2006; 46: 386
[11] Zhu X H, Yu Z X. Well-Chosen Example of ANSYS Senior Engineering Finite Element Analysis. Beijing: Publishing House of Electronics Industry, 2004: 313 (祝效华,余志祥. ANSYS高级工程有限元分析范例精选. 北京:电子工业出版社, 2004:313)
[12] Wang G Z, Cheng Z N. Chin J Appl Mech, 2000; 17: 133 (王国忠,程兆年.应用力学学报, 2000;17:133)
[13] Li Y, Wang R C, Gu Z G, Rong R F. J Fudan Univ (Nat Sci), 2003; 42: 60 (李 勇,汪荣昌,顾之光,戎瑞芬.复旦学报(自然科学版), 2003;42:60)
[14] Qian Y Y, Ma X, Yoshida F. Weld J, 2002; 81: 85-s
[1] GUO Fu, DU Yihui, JI Xiaoliang, WANG Yishu. Recent Progress on Thermo-Mechanical Reliability of Sn-Based Alloys and Composite Solder for Microelectronic Interconnection[J]. 金属学报, 2023, 59(6): 744-756.
[2] ZHANG Zhijie, HUANG Mingliang. In Situ Study on Liquid-Solid Electromigration Behavior in Cu/Sn-37Pb/Cu Micro-Interconnect[J]. 金属学报, 2020, 56(10): 1386-1392.
[3] Guangping ZHANG, Honglei CHEN, Xuemei LUO, Bin ZHANG. Progress in Thermal Fatigue of Micro/Nano-ScaleMetal Conductors[J]. 金属学报, 2018, 54(3): 357-366.
[4] Zhijie ZHANG,Mingliang HUANG. Liquid-Solid Electromigration Behavior of Cu/Sn-52In/Cu Micro-Interconnect[J]. 金属学报, 2017, 53(5): 592-600.
[5] Wenying ZHANG, Jun LI, Bo ZHOU. OXIDATION KINETICS BEHAVIOR AND ELECTRICAL PROPERTY OF MnCO2O4 SPINEL AS A COATING MATERIAL FOR METALLIC INTERCONNECTS[J]. 金属学报, 2016, 52(3): 355-360.
[6] Yong ZUO, Limin MA, Sihan LIU, Yutian SHU, Fu GUO. WHISKER MITIGATION FOR Sn-BASED Pb-FREE SOLDERS BY POSS ADDITION[J]. 金属学报, 2015, 51(6): 685-692.
[7] XU Jiayu CHEN Hongtao LI Mingyu. STUDY ON LEAD-FREE SOLDER JOINT RELIABILITY BASED ON GRAIN ORIENTATION[J]. 金属学报, 2012, 48(9): 1042-1048.
[8] WANG Songlin, FENG Yi, WANG Dongsheng, WANG Jingwen. THREE-LAYER CO-FIRING FABRICATION OF LaCrO3-BASED CERAMIC INTERCONNECT, COMPOSITE ANODE SUPPORT AND YSZ ELECTROLYTE[J]. 金属学报, 2012, 48(5): 587-592.
[9] TIAN Yanhong WANG Chunqing ZHAO Shaowei. ULTRASONIC BONDABILITY AND ANTIOXIDATION PROPERTY OF TiN/Ag METALLIZATION ON Cu PAD[J]. 金属学报, 2010, 46(5): 618-622.
[10] ZHANG Zhefeng ZHANG Peng TIAN Yanzhong ZHANG Qingke QU Shen ZOU Hefei DUAN Qiqiang LI Shouxin WANG Zhongguang. INTERFACIAL EFFECTS OF FATIGUE CRACKING IN METALLIC MATERIALS[J]. 金属学报, 2009, 45(7): 788-800.
[11] HUA Bin ZHANG Jianfu LU Fengshuang KONG Yonghong PU Jian LI Jian. EFFECT OF LaCoO3 COATING ON THE INTERMEDIATE TEMPERATURE OXIDATION BEHAVIOR OF SUS 430 METALLIC INTERCONNECT[J]. 金属学报, 2009, 45(5): 605-609.
[12] YIN Limeng YANG Yan LIU Liangqi ZHANG Xinping. SIZE EFFECT OF MECHANICAL BEHAVIOR OF MINIATURE SOLDER JOINT INTERCONNECTIONS IN ELECTRONIC PACKAGING[J]. 金属学报, 2009, 45(4): 422-427.
[13] LIU Bo; TANG Wenjin; SONG Zhongxiao; XU Kewei. Microstructure and Thermal Stability of CuSiN Self--Aligned Layerin Advanced Copper Interconnect Multilayer Films[J]. 金属学报, 2007, 43(11): 1145-1147 .
[14] . EFFECT OF INTERMETALLIC COMPOUNDS ON THE TENSILE PROPERTIES OF Sn-3.8Ag-0.7Cu SOLDER ALLOY[J]. 金属学报, 2007, 42(1): 41-46 .
No Suggested Reading articles found!