Study of Microsegregation In Al--Cu—Zn Ternary Alloys by Experiment and Scheil Model

Acta Metall Sin

2004, Vol. 40

Issue (6): 664- DOI:

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Study of Microsegregation In Al--Cu—Zn Ternary Alloys by Experiment and Scheil Model

CHEN Fuyi; JIE Wanqi

State Key Laboratory for Solidification Process; Northwestern Polytechnic University;Xi'an 710072

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CHEN Fuyi; JIE Wanqi. Study of Microsegregation In Al--Cu—Zn Ternary Alloys by Experiment and Scheil Model. Acta Metall Sin, 2004, 40(6): 664-.

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Abstract The solidification path and microsegregation during primary solidification of Al--Cu--Zn alloy were investigated comparably by CALPHAD coupled with Scheil model, simple Scheil equation and experiment. It was indicated by the CALPHAD that the solute content at the end point of primary solidification changes synchronistically with the start point, solute content in dendritic arm and the partition coefficient increase with the solid fraction. Simple Scheil equation was shown to be able to calculate the eutectic amount on the base of partition coefficient calculated by thermodynamics, its prediction for the different solutes is self--consistent and agreeable with the CALPHAD. The eutectic amount and SDAS was measured in DC experiment and compared to model value, it was shown that the experimental data are in agreement with the model prediction.

Key words: Al--Cu--Zn alloy Scheil equation microsegregation CALPHAD

Received: 30 June 2003

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