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A METHOD FOR MEASURING ACTIVITIES IN SLAG CONTAINING VOLATILE COMPONENT B_2O_3 |
DAI Changhong; ZHANG Hianpeng(Northeastern University; Shenyang) |
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Cite this article:
DAI Changhong; ZHANG Hianpeng(Northeastern University; Shenyang). A METHOD FOR MEASURING ACTIVITIES IN SLAG CONTAINING VOLATILE COMPONENT B_2O_3. Acta Metall Sin, 1994, 30(18): 243-246.
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Abstract The activity of CaO in the CaO-B2O3 slag containing volatile component B2O3 has been measured in a partially sealed graphite container in equilibrium between the slag and melt, and the activity of B2O3 has been calculated by integrating Gibbs-Duhem equation. The experimental results are in good agreement with the previous data derived from the phase diagram and free energies of formation.
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1张子青,周继程,田彦文,吕向明,张晔,丁涌海.全国第五届冶金过程物理化学年会论文集,1984:2542张成涛,MgO-B2O3,SiO2B2O3及MgO-SiO2-B2O3体系的热力学研究,东北大学硕士论文,19883邹元赵彭年,曹兆民.金属学报,1963;6:1214RichardsonFD.PhysicalChemistryofMellsinMetallurgy,NewYork:Academic,1974:1375InghramMG,PorterRF,ChupkaWA.JChemPhys,1956;25:4986RaoBKDP,GaskellDR.MetallTrans,1981;12B:469 |
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