Please wait a minute...
Acta Metall Sin  2023, Vol. 59 Issue (3): 413-423    DOI: 10.11900/0412.1961.2021.00243
Research paper Current Issue | Archive | Adv Search |
Effect of Austenitizing Temperature on Microstructures and Mechanical Properties of Si-Mn Hot-Rolled Plate After Quenching and Partitioning Treatment
CHENG Yuanyao1,2, ZHAO Gang1,2, XU Deming1,2(), MAO Xinping3, LI Guangqiang1,2
1 Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China
2 State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
3 Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China
Cite this article: 

CHENG Yuanyao, ZHAO Gang, XU Deming, MAO Xinping, LI Guangqiang. Effect of Austenitizing Temperature on Microstructures and Mechanical Properties of Si-Mn Hot-Rolled Plate After Quenching and Partitioning Treatment. Acta Metall Sin, 2023, 59(3): 413-423.

Download:  HTML  PDF(3608KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The production of quenching and partitioning (Q&P) steel using hot-rolled steel instead of cold-rolled steel can significantly reduce the manufacturing process time and cost. However, the initial microstructures of hot-rolled and cold-rolled steels are different, which affect the microstructures and mechanical properties of Q&P steel. Because most studies used Q&P steel prepared from cold-rolled steel, the microstructures and mechanical properties of Q&P steel prepared from hot-rolled steel are unclear. This study examines the microstructures and mechanical properties of Q&P Si-Mn steel prepared from hot-rolled steel as a function of the austenitizing temperature. The results showed that the ferrite in the Q&P Si-Mn steel produced from the hot-rolled steel had lath-type and blocky-type morphologies. The observed ferrite morphology could influence the morphology of the adjacent retained austenite. The lath-type and blocky-type ferrite surrounding the retained austenite was mainly observed as the thin lath and blocky types, respectively. The ferrite and retained austenite contents decreased with increasing austenitizing temperature. In addition, the corresponding yield and tensile strengths increased gradually with a concomitant decrease in elongation and the product of strength and elongation. When the austenitizing temperature was 810oC, the product of strength and elongation of the Q&P Si-Mn steels produced from hot-rolled steel reached 28.36 GPa·%, which was approximately 36% higher than that of Q&P980 produced industrially from cold-rolled steel. The higher product of strength and elongation of Q&P Si-Mn steel produced from hot-rolled steel may be related to the different morphologies of ferrite, which might control the morphology and stability of the adjacent retained austenite. These experimental results could provide a theoretical basis for preparing Q&P steel from hot-rolled steel instead of cold-rolled steel.

Key words:  hot-rolled plate of Si-Mn steel      ferrite      austenitizing temperature      quenching and partitioning (Q&P) treatment      product of strength and elongation     
Received:  10 June 2021     
ZTFLH:  TG142.1  
Fund: Chinese Postdoctoral Science Foundation(2020M682494);Technical Innovation Special Major Project of Hubei Province(2017AAA113)
About author:  XU Deming, Tel: (027)68862652, E-mail: xudeming@wust.edu.cn

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2021.00243     OR     https://www.ams.org.cn/EN/Y2023/V59/I3/413

Fig.1  Schematic of quenching and partitioning (Q&P) Si-Mn steel heat treatments (Ac1—start temperature of pearlite transformed to austenite, Ms—initial temperature of martensite transformation, Mf—finish temperature of martensite transformation)
Fig.2  OM (a) and SEM (b) images of the Si-Mn hot-rolled plate (B, F, M, BF, and LF refer to bainite, ferrite, martensite, blocky ferrite, and lath-like ferrite, respectively)
Fig.3  SEM images of the Q&P Si-Mn steels under austenitizing temperatures of 810oC (a), 840oC (b), 870oC (c), 910oC (d), and 950oC (e) (RA, M1, and M2/RA refer to retained austenite, primary martensite, and secondary martensite/retained austenite island, respectively)
Fig.4  XRD spectra (a) and volume fraction and carbon content of retained austenite (b) of Q&P Si-Mn steels under different austenitizing temperatures
Fig.5  EBSD images of the Q&P Si-Mn steels under austenitizing temperatures of 810oC (a), 870oC (b), and 950oC (c) (The green, gray, and black structures represent RA, F or M1, and M2, respectively)
Fig.6  TEM images of the Q&P Si-Mn steels under austenitizing temperatures of 810oC (a, b), 870oC (c, d), and 950oC (e, f) (Insets in Figs.6b and d show the selected area electron diffraction patterns of blocky RA and film-like RA, respectively)
Fig.7  Engineering stress-strain curves of Q&P Si-Mn steels under different austenitizing temperatures
Fig.8  Yield strength (a), tensile strength (b), elongation (c), and product of strength and elongation (d) of Q&P Si-Mn steels under different austenitizing temperatures
Fig.9  True stress-true strain (a) and strain hardening rate (b) curves of the Q&P Si-Mn steels under austenitizing temperatures of 810, 870, and 950oC
TA / oCStage IStage IIStage III
810ε < 0.0150.015 < ε < 0.1660.166 < ε < 0.207
870ε < 0.0180.018 < ε < 0.1120.112 < ε < 0.135
950ε < 0.0200.020 < ε < 0.0880.088 < ε < 0.109
Table 1  Range of the true strain of every stage in the strain hardening rate curve of the Q&P Si-Mn steels under austenitizing temperatures of 810, 870, and 950oC
1 Speer J G, Matlock D K, De Cooman B C, et al. Carbon partitioning into austenite after martensite transformation [J]. Acta Mater., 2003, 51: 2611
doi: 10.1016/S1359-6454(03)00059-4
2 Speer J G, Matlock D K, Cooman B C D, et al. Comments on “On the definitions of paraequilibrium and orthoequilibrium” by M. Hillert and J. Ågren, Scripta Materialia, 50, 697-9 (2004) [J]. Scr. Mater., 2005, 52: 83
doi: 10.1016/j.scriptamat.2004.08.029
3 Wang L, Feng W J. Development and application of Q&P sheet steels [A]. Advanced Steels: The Recent Scenario in Steel Science and Technology [M]. Berlin, Heidelberg: Springer, 2011: 255
4 Yin R Y. Achievement on the thin slab casting process in China [J]. Iron steel, 2008, 43(3): 1
doi: 10.1179/1743281215Y.0000000036
殷瑞钰. 中国薄板坯连铸连轧的进展 [J]. 钢铁, 2008, 43(3): 1
5 Gan Y, Li G Y, Ma M T, et al. Development of advanced compact steel process and deep working technology for high-strength-ductility auto-parts [A]. The 10th CSM Steel Congress & The 6th Baosteel Biennial Academic Conference [C]. Beijing: Metallurgical Industry Press, 2015: 1802
干 勇, 李光瀛, 马鸣图 等. 先进短流程-深加工新技术与高强塑性汽车构件的开发 [A]. 第十届中国钢铁年会暨第六届宝钢学术年会论文集II [C]. 北京: 冶金工业出版社, 2015: 1802
6 Gouné M, Aoued S, Danoix F, et al. Alloying-element interactions with austenite/martensite interface during quenching and partitioning of a model Fe-C-Mn-Si alloy [J]. Scr. Mater., 2019, 162: 181
doi: 10.1016/j.scriptamat.2018.11.012
7 Huyghe P, Caruso M, Collet J L, et al. In situ quantitative assessment of the role of silicon during the quenching and partitioning of a 0.2C steel [J]. Metall. Mater. Trans., 2019, 50A: 3486
8 Kang T, Zhao Z Z, Liang J H, et al. Effect of the austenitizing temperature on the microstructure evolution and mechanical properties of Q&P steel [J]. Mater. Sci. Eng., 2020, A771: 138584
9 Zhao Z Z, Liang J H, Zhao A M, et al. Effects of the austenitizing temperature on the mechanical properties of cold-rolled medium-Mn steel system [J]. J. Alloys Compd., 2017, 691: 51
doi: 10.1016/j.jallcom.2016.08.093
10 Mandal G, Ghosh S K, Bera S, et al. Effect of partial and full austenitisation on microstructure and mechanical properties of quenching and partitioning steel [J]. Mater. Sci. Eng., 2016, A676: 56
11 Chen S, Hu J, Shan L Y, et al. Characteristics of bainitic transformation and its effects on the mechanical properties in quenching and partitioning steels [J]. Mater. Sci. Eng., 2021, A803: 140706
12 Ariza-Echeverri E A, Masoumi M, Nishikawa A S, et al. Development of a new generation of quench and partitioning steels: Influence of processing parameters on texture, nanoindentation, and mechanical properties [J]. Mater. Des., 2020, 186: 108329
doi: 10.1016/j.matdes.2019.108329
13 Li Y J, Kang J, Zhang W N, et al. A novel phase transition behavior during dynamic partitioning and analysis of retained austenite in quenched and partitioned steels [J]. Mater. Sci. Eng., 2018, A710: 181
14 Zinsaz-Borujerdi A, Zarei-Hanzaki A, Abedi H R, et al. Room temperature mechanical properties and microstructure of a low alloyed TRIP-assisted steel subjected to one-step and two-step quenching and partitioning process [J]. Mater. Sci. Eng., 2018, A725: 341
15 Zhang J, Ding H, Misra R D K, et al. Enhanced stability of retained austenite and consequent work hardening rate through pre-quenching prior to quenching and partitioning in a Q-P microalloyed steel [J]. Mater. Sci. Eng., 2014, A611: 252
16 Ding R, Tang D, Zhao A M, et al. Effect of ultragrain refinement on quenching and partitioning steels manufactured by a novel method [J]. Mater. Des., 2015, 87: 640
doi: 10.1016/j.matdes.2015.08.073
17 Ren Y Q, Xie Z J, Zhang H W, et al. Effect of precursor microstructure on morphology feature and mechanical property of C-Mn-Si steel [J]. Acta Metall. Sin., 2013, 49: 1558
doi: 10.3724/SP.J.1037.2013.00301
任勇强, 谢振家, 张宏伟 等. 前躯体组织对C-Mn-Si钢组织特征及力学行为的影响 [J]. 金属学报, 2013, 49: 1558
doi: 10.3724/SP.J.1037.2013.00301
18 Huang J, Poole W J, Militzer M. Austenite formation during intercritical annealing [J]. Metall. Mater. Trans., 2004, 35A: 3363
19 Su Y Y, Chiu L H, Chuang T L, et al. Retained austenite amount determination comparison in JIS SKD11 steel using quantitative metallography and X-ray diffraction methods [J]. Adv. Mater. Res., 2012, 482-484: 1165
20 van Dijk N H, Butt A, Zhao L M, et al. Thermal stability of retained austenite in TRIP steels studied by synchrotron X-ray diffraction during cooling [J]. Acta Mater., 2005, 53: 5439
doi: 10.1016/j.actamat.2005.08.017
21 Kang Y L, Fu J, Liu D L, et al. Microstructure and Properties Control of Thin Slab Continuous Casting and Rolling Steel [M]. Beijing: Metallurgical Industry Press, 2006: 178
康永林, 傅 杰, 柳得橹 等. 薄板坯连铸连轧钢的组织性能控制 [M]. 北京: 冶金工业出版社, 2006: 178
22 Santofimia M J, Zhao L, Sietsma J. Microstructural evolution of a low-carbon steel during application of quenching and partitioning heat treatments after partial austenitization [J]. Metall. Mater. Trans., 2009, 40A: 46
23 Zhang J, Ding H, Misra R D K. Enhanced strain hardening and microstructural characterization in a low carbon quenching and partitioning steel with partial austenization [J]. Mater. Sci. Eng., 2015, A636: 53
24 Wang C Y, Zhang Y J, Cao W Q, et al. Austenite/martensite structure and corresponding ultrahigh strength and high ductility of steels processed by Q&P techniques [J]. Sci. China Technol. Sci., 2012, 55: 1844
doi: 10.1007/s11431-012-4875-9
25 Arlazarov A, Gouné M, Bouaziz O, et al. Evolution of microstructure and mechanical properties of medium Mn steels during double annealing [J]. Mater. Sci. Eng., 2012, A542: 31
26 Shi J, Sun X J, Wang M Q, et al. Enhanced work-hardening behavior and mechanical properties in ultrafine-grained steels with large-fractioned metastable austenite [J]. Scr. Mater., 2010, 63: 815
doi: 10.1016/j.scriptamat.2010.06.023
27 Xiong X C, Chen B, Huang M X, et al. The effect of morphology on the stability of retained austenite in a quenched and partitioned steel [J]. Scr. Mater., 2013, 68: 321
doi: 10.1016/j.scriptamat.2012.11.003
28 Cai Z H, Ding H, Misra R D K, et al. Austenite stability and deformation behavior in a cold-rolled transformation-induced plasticity steel with medium manganese content [J]. Acta Mater., 2015, 84: 229
doi: 10.1016/j.actamat.2014.10.052
29 Wang M M, Hell J C, Tasan C C. Martensite size effects on damage in quenching and partitioning steels [J]. Scr. Mater., 2017, 138: 1
doi: 10.1016/j.scriptamat.2017.05.021
30 Yan S, Liu X H, Liu W J, et al. Comparative study on microstructure and mechanical properties of a C-Mn-Si steel treated by quenching and partitioning (Q&P) processes after a full and intercritical austenitization [J]. Mater. Sci. Eng., 2017, A684: 261
31 Sun J, Yu H, Wang S Y, et al. Study of microstructural evolution, microstructure-mechanical properties correlation and collaborative deformation-transformation behavior of quenching and partitioning (Q&P) steel [J]. Mater. Sci. Eng., 2014, A596: 89
32 Ding R, Tang D, Zhao A M, et al. A new type of quenching and partitioning processing developed from martensitic pre-microstructure [J]. Mater. Manuf. Processes, 2014, 29: 704
doi: 10.1080/10426914.2014.912304
33 Sun S H, Zhao A M. Effect of microstructure morphology on mechanical properties of quenching and partitioning steel [J]. Mater. Sci. Technol, 2018, 34: 347
doi: 10.1080/02670836.2017.1390901
34 Li Y J, Liu D, Chen D, et al. Response of retained austenite to quenching temperature in a novel low density Fe-Mn-Al-C steel processed by hot rolling-air cooling followed by non-isothermal partitioning [J]. Mater. Sci. Eng., 2019, A753: 197
35 Yi H L, Chen P, Bhadeshia H K D H. Optimizing the morphology and stability of retained austenite in a δ-TRIP steel [J]. Metall. Mater. Trans., 2014, 45A: 3512
36 Zhou Q, Qian L H, Tan J, et al. Inconsistent effects of mechanical stability of retained austenite on ductility and toughness of transformation-induced plasticity steels [J]. Mater. Sci. Eng., 2013, A578: 370
37 Xie Z J, Ren Y Q, Zhou W H, et al. Stability of retained austenite in multi-phase microstructure during austempering and its effect on the ductility of a low carbon steel [J]. Mater. Sci. Eng., 2014, A603: 69
[1] ZHAO Yafeng, LIU Sujie, CHEN Yun, MA Hui, MA Guangcai, GUO Yi. Critical Inclusion Size and Void Growth in Dual-Phase Ferrite-Bainite Steel During Ductile Fracture[J]. 金属学报, 2023, 59(5): 611-622.
[2] HOU Xuru, ZHAO Lin, REN Shubin, PENG Yun, MA Chengyong, TIAN Zhiling. Effect of Heat Input on Microstructure and Mechanical Properties of Marine High Strength Steel Fabricated by Wire Arc Additive Manufacturing[J]. 金属学报, 2023, 59(10): 1311-1323.
[3] SUN Yi, ZHENG Qinyuan, HU Baojia, WANG Ping, ZHENG Chengwu, LI Dianzhong. Mechanism of Dynamic Strain-Induced Ferrite Transformation in a 3Mn-0.2C Medium Mn Steel[J]. 金属学报, 2022, 58(5): 649-659.
[4] PENG Jun, JIN Xinyan, ZHONG Yong, WANG Li. Influence of Substrate Surface Structure on the Galvanizability of Fe-16Mn-0.7C-1.5Al TWIP Steel Sheet[J]. 金属学报, 2022, 58(12): 1600-1610.
[5] Xingpin CHEN,Wenjia LI,Ping REN,Wenquan CAO,Qing LIU. Effects of C Content on Microstructure and Properties ofFe-Mn-Al-C Low-Density Steels[J]. 金属学报, 2019, 55(8): 951-957.
[6] Hao CHEN, Congyu ZHANG, Jianing ZHU, Zenan YANG, Ran DING, Chi ZHANG, Zhigang YANG. Austenite/Ferrite Interface Migration and Alloying Elements Partitioning: An Overview[J]. 金属学报, 2018, 54(2): 217-227.
[7] Ke ZHANG, Zhaodong LI, Fengli SUI, Zhenghai ZHU, Xiaofeng ZHANG, Xinjun SUN, Zhenyi HUANG, Qilong YONG. Effect of Cooling Rate on Microstructure Evolution and Mechanical Properties of Ti-V-Mo Complex Microalloyed Steel[J]. 金属学报, 2018, 54(1): 31-38.
[8] Liming DONG,Li YANG,Jun DAI,Yu ZHANG,Xuelin WANG,Chengjia SHANG. Effect of Mn, Ni, Mo Contents on Microstructure Transition and Low Temperature Toughness of Weld Metal for K65 Hot Bending Pipe[J]. 金属学报, 2017, 53(6): 657-668.
[9] Jun ZHANG,Wenxiong CHEN,Chengwu ZHENG,Dianzhong LI. Phase-Field Modeling of Austenite-to-Ferrite Transformation in Fe-C-Mn Ternary Alloys[J]. 金属学报, 2017, 53(6): 760-768.
[10] Fengyu SONG,Yanmei LI,Ping WANG,Fuxian ZHU. EFFECTS OF HEAT INPUT ON THE MICROSTRUC-TURE AND IMPACT TOUGHNESS OF WELD METAL PROCESSED BY A NEW FLUXNOVEL FLUX CORED WIRE WELD[J]. 金属学报, 2016, 52(7): 890-896.
[11] Xuelin WANG,Liming DONG,Weiwei YANG,Yu ZHANG,Xuemin WANG,Chengjia SHANG. EFFECT OF Mn, Ni, Mo PROPORTION ON MICRO-STRUCTURE AND MECHANICAL PROPERTIESOF WELD METAL OF K65 PIPELINE STEEL[J]. 金属学报, 2016, 52(6): 649-660.
[12] Jun ZHANG,Chengwu ZHENG,Dianzhong LI. MODELING OF ISOTHERMAL AUSTENITE TO FERRITE TRANSFORMATION IN A Fe-CALLOY BY PHASE-FIELD METHOD[J]. 金属学报, 2016, 52(11): 1449-1458.
[13] Huidong WU,Chi ZHANG,Wenbo LIU,Zhigang YANG. SIMULATION OF GROWTH KINETICS OF PRO-EUTECTOID FERRITE USING MIXED CONTROL MODEL WITH CONSIDERATION OF DISLOCATION INTERACTION[J]. 金属学报, 2015, 51(9): 1136-1144.
[14] Liansheng CHEN, Jianyang ZHANG, Yaqiang TIAN, Jinying SONG, Yong XU, Shihong ZHANG. EFFECT OF Mn PRE-PARTITIONING ON C PARTITIONING AND RETAINED AUSTENITE OF Q&P STEELS[J]. 金属学报, 2015, 51(5): 527-536.
[15] Lei WANG,Di TANG,Yong SONG. AUSTENITE TRANSFORMING IN CONTINUOUS COOLING PROCESS UNDER DIFFUSION CONTROL MODEL[J]. 金属学报, 2015, 51(11): 1341-1348.
No Suggested Reading articles found!