Please wait a minute...
Acta Metall Sin  2020, Vol. 56 Issue (9): 1247-1254    DOI: 10.11900/0412.1961.2020.00013
Current Issue | Archive | Adv Search |
Initial Corrosion Behavior of Carbon Steel and Weathering Steel in Nansha Marine Atmosphere
LIU Yuwei1,2, ZHAO Hongtao1, WANG Zhenyao1()
1 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2 School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
Cite this article: 

LIU Yuwei, ZHAO Hongtao, WANG Zhenyao. Initial Corrosion Behavior of Carbon Steel and Weathering Steel in Nansha Marine Atmosphere. Acta Metall Sin, 2020, 56(9): 1247-1254.

Download:  HTML  PDF(2389KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Along with the increasing pace of marine resource development and strategic deployment of China, the infrastructure materials and deployed aircraft were facing severe salt fog corrosion during the construction process of the South China Sea. Materials damage in this environment is much more serious than that in other marine atmospheric environment. Owing to its location near the equator and the direct impact of solar radiation, Nansha marine atmosphere is a representative and typical climate with high temperature, high humidity, high salinity and high radiation. However, there has been lack of material corrosion data and relevant fundamental research until now. Carbon steel is usually one of the most widely used infrastructure materials and reference materials, and its corrosion data exposed to Nansha Islands marine atmosphere is much more important. These corrosion data can not only provide important basis for environmental corrosivity category, but also provide reference for indoor accelerated corrosion test. Therefore, in order to obtain useful information on selected construction materials, adopting the appropriate corrosion protection methods, and predicting the life of metallic structures under service, the exposure test was conducted on carbon steel Q235 and weathering steel Q450NQR1 in Nansha Islands for 2 and 5 months. Thickness loss analysis, macroscopic observation, SEM, XRD, optical profiler and tensile tests were conducted to study the initial corrosion behavior on both sides of Q235 and Q450NQR1 in Nansha marine atmosphere. The results showed that the initial corrosion behavior of both steels at this site was more serious than those at most areas, such as Wanning and Xisha Islands, and the corrosion of skyward of both steels was more serious than that of field-ward. The rust layer formed on field-ward was easier to fall off. After exposure for 2 months, the thickness loss of Q235 was the same as that of Q450NQR1, and corrosion products on both sides were mainly composed of γ-FeOOH, α-FeOOH and Fe3O4; while after 5 months' exposure, the thickness loss of Q235 was much larger than that of Q450NQR1, and corrosion products were mainly composed of γ-FeOOH, α-FeOOH, Fe3O4 and β-FeOOH. The relative composition of β-FeOOH and γ-FeOOH was fewer on the field-ward, and the relative composition of Fe3O4 was fewer on the skyward.

Key words:  Nansha marine atmosphere      carbon steel      atmospheric corrosion mechanism      corrosion product     
Received:  10 January 2020     
ZTFLH:  TG172.3  
Fund: National Natural Science Foundation of China(51671197);Strategic Priority Research Program of Chinese Academy of Sciences(XDA13040502)

URL: 

https://www.ams.org.cn/EN/10.11900/0412.1961.2020.00013     OR     https://www.ams.org.cn/EN/Y2020/V56/I9/1247

SteelCSiMnPSCrNiCuFe
Q2350.220.080.100.0150.003---Bal.
Q450NQR10.080.310.410.0730.0060.470.150.29Bal.
Table 1  Chemical compositions of Q235 and Q450NQR1
Fig.1  Schematic of tensile test specimen (unit: mm)
Fig.2  Exposure site
Fig.3  Variation in the thickness loss of Q235 and Q450NQR1 as a function of exposure time
Fig.4  Composition of corrosion products formed on Q235 (a, b) and Q450NQR1 (c, d)
Fig.5  Macro-morphologies of the corrosion products on skyward (a~d) and field-ward (e~h) sides of Q235 and Q450NQR1
Fig.6  Cross-section micro-morphologies of the corrosion products on skyward (a~d) and field-ward (e~h) sides of Q235 and Q450NQR1
Fig.7  Three-dimensional morphologies on skyward surface (a~d) and field-ward surface (e~f) of Q235 and Q450NQR1 after removal of the corrosion products
SurfaceQ235Q450NQR1
2 months5 months2 months5 months
Skyward971512396870916805
Field-ward766310013751612462
Table 2  Surface roughnesses of Q235 and Q450NQR1
Fig.8  Stress (σ)-strain (ε) curves of Q235 (a) and Q450NQR1 (b) exposed for different months
[1] Hou W, Liang C. Eight-year atmospheric corrosion exposure of steels in China [J]. Corrosion, 1999, 55: 65
[2] Oh S J, Cook D C, Townsend H E. Atmospheric corrosion of different steels in marine, rural and industrial environments [J]. Corros. Sci., 1999, 41: 1687
[3] Townsend H E. Effects of alloying elements on the corrosion of steel in industrial atmospheres [J]. Corrosion, 2001, 57: 497
[4] Zhang Q C, Wu J S, Wang J J, et al. Corrosion behavior of weathering steel in marine atmosphere [J]. Mater. Chem. Phys., 2002, 77: 603
[5] Surnam B Y R, Oleti C V. Atmospheric corrosion in Mauritius [J]. Corros. Eng. Sci. Technol., 2012, 47: 446
[6] Morcillo M, Chico B, Mariaca L, et al. Salinity in marine atmospheric corrosion: Its dependence on the wind regime existing in the site [J]. Corros. Sci., 2000, 42: 91
[7] de la Fuente D, Díaz I, Simancas J, et al. Long-term atmospheric corrosion of mild steel [J]. Corros. Sci., 2011, 53: 604
[8] de Meybaum B R, Ayllon E S. Characterization of atmospheric corrosion products on weathering steels [J]. Corrosion, 1980, 36: 345
[9] Almeida E, Morcillo M, Rosales B, et al. Atmospheric corrosion of mild steel. Part I - Rural and urban atmospheres [J]. Mater. Corros., 2000, 51: 859
[10] Han W, Pan C, Wang Z Y, et al. Initial atmospheric corrosion of carbon steel in industrial environment [J]. J. Mater. Eng. Perform., 2015, 24: 864
[11] Morcillo M, Chico B, de la Fuente D, et al. Looking back on contributions in the field of atmospheric corrosion offered by the MICAT ibero-american testing network [J]. Int. J. Corros., 2012, 2012: 824365
[12] Ericsson R. The influence of sodium chloride on the atmospheric corrosion of steel [J]. Mater. Corros., 1978, 29: 400
[13] Perez F C. Atmospheric corrosion of steel in a humid tropical climate—Influence of pollution, humidity, temperature, solar radiation and rainfall [J]. Corrosion, 1984, 40: 170
[14] Morcillo M, Alcántara J, Díaz I, et al. Marine atmospheric corrosion of carbon steels [J]. Rev. Metal., 2015, 51: e045.
[15] Feliu S, Morcillo M, Chico B. Effect of distance from sea on atmospheric corrosion rate [J]. Corrosion, 1999, 55: 883
[16] Guerra J C, Castañeda A, Corvo F, et al. Atmospheric corrosion of low carbon steel in a coastal zone of Ecuador: Anomalous behavior of chloride deposition versus distance from the sea [J]. Mater. Corros., 2019, 70: 444
[17] Alcántara J, Chico B, Díaz I, et al. Airborne chloride deposit and its effect on marine atmospheric corrosion of mild steel [J]. Corros. Sci., 2015, 97: 74
[18] Yamashita M, Miyuki H, Matsuda Y, et al. The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century [J]. Corros. Sci., 1994, 36: 283
[19] Li X G, Dong C F, Xiao K, et al. Corrosion/Aging Behavior and Mechanism of Typical Materials in Xisha Marine Atmosphere [M]. Beijing: Science Press, 2014: 37
(李晓刚, 董超芳, 肖 葵等. 西沙海洋大气环境下典型材料腐蚀/老化行为与机理 [M]. 北京: 科学出版社, 2014: 37)
[20] Liu Y W, Zhang J, Wei Y H, et al. Effect of different UV intensity on corrosion behavior of carbon steel exposed to simulated Nansha atmospheric environment [J]. Mater. Chem. Phys., 2019, 237: 121855
[21] Zhang X, Yang S W, Zhang W H, et al. Influence of outer rust layers on corrosion of carbon steel and weathering steel during wet-dry cycles [J]. Corros. Sci., 2014, 82: 165
[22] Misawa T, Asami K, Hashimoto K, et al. The mechanism of atmospheric rusting and the protective amorphous rust on low alloy steel [J]. Corros. Sci., 1974, 14: 279
[23] Chen Y Y, Tzeng H J, Wei L I, et al. Corrosion resistance and mechanical properties of low-alloy steels under atmospheric conditions [J]. Corros. Sci., 2005, 47: 1001
[24] Misawa T, Hashimoto K, Shimodaira S. The mechanism of formation of iron oxide and oxyhydroxides in aqueous solutions at room temperature [J]. Corros. Sci., 1974, 14: 131
doi: 10.1016/S0010-938X(74)80051-X
[25] Hao L, Zhang S X, Dong J H, et al. Atmospheric corrosion resistance of MnCuP weathering steel in simulated environments [J]. Corros. Sci., 2011, 53: 4187
[26] Ke W, Dong J H. Study on the rusting evolution and the performance of resisting to atmospheric corrosion for Mn-Cu steel [J]. Acta Metall. Sin., 2010, 46: 1365
doi: 10.3724/SP.J.1037.2010.01365
(柯 伟, 董俊华. Mn-Cu钢大气腐蚀锈层演化规律及其耐候性的研究 [J]. 金属学报, 2010, 46: 1365)
doi: DOI: 10.3724/SP.J.1037.2010.00489
[1] LI Xiaohan, CAO Gongwang, GUO Mingxiao, PENG Yunchao, MA Kaijun, WANG Zhenyao. Initial Corrosion Behavior of Carbon Steel Q235, Pipeline Steel L415, and Pressure Vessel Steel 16MnNi Under High Humidity and High Irradiation Coastal-Industrial Atmosphere in Zhanjiang[J]. 金属学报, 2023, 59(7): 884-892.
[2] LI Qian, LIU Kai, ZHAO Tianliang. Rust Formation Behavior and Mechanism of Q235 Carbon Steel in 5%NaCl Salt Spray Under Elastic Tensile Stress[J]. 金属学报, 2023, 59(6): 829-840.
[3] WANG Zhoutou, YUAN Qing, ZHANG Qingxiao, LIU Sheng, XU Guang. Microstructure and Mechanical Properties of a Cold Rolled Gradient Medium-Carbon Martensitic Steel[J]. 金属学报, 2023, 59(6): 821-828.
[4] PENG Zhiqiang, LIU Qian, GUO Dongwei, ZENG Zihang, CAO Jianghai, HOU Zibing. Independent Change Law of Mold Heat Transfer in Continuous Casting Based on Big Data Mining[J]. 金属学报, 2023, 59(10): 1389-1400.
[5] LIU Yuwei, GU Tianzhen, WANG Zhenyao, WANG Chuan, CAO Gongwang. Corrosion Behavior of Q235 and Q450NQR1 Exposed to Marine Atmospheric Environment in Nansha, China for 34 Months[J]. 金属学报, 2022, 58(12): 1623-1632.
[6] GUO Zhongao, PENG Zhiqiang, LIU Qian, HOU Zibing. Nonuniformity of Carbon Element Distribution of Large Area in High Carbon Steel Continuous Casting Billet[J]. 金属学报, 2021, 57(12): 1595-1606.
[7] SONG Xuexin, HUANG Songpeng, WANG Chuan, WANG Zhenyao. The Initial Corrosion Behavior of Carbon Steel Exposed to the Coastal-Industrial Atmosphere in Hongyanhe[J]. 金属学报, 2020, 56(10): 1355-1365.
[8] Qingdong ZHANG,Shuo LI,Boyang ZHANG,Lu XIE,Rui LI. Molecular Dynamics Modeling and Studying of Micro-Deformation Behavior in Metal Roll-Bonding Process[J]. 金属学报, 2019, 55(7): 919-927.
[9] Canshuai LIU,Zhaohui TIAN,Zhiming ZHANG,Jianqiu WANG,En-Hou HAN. Corrosion Behaivour of X65 Low Carbon Steel During Redox State Transition Process of High LevelNuclear Waste Disposal[J]. 金属学报, 2019, 55(7): 849-858.
[10] Xingchen CHEN, Jie WANG, Deren CHEN, Shuncong ZHONG, Xiangfeng WANG. Effect of Na on Early Atmospheric Corrosion of Al[J]. 金属学报, 2019, 55(4): 529-536.
[11] Zibing HOU, Rui XU, Yi CHANG, Jianghai CAO, Guanghua WEN, Ping TANG. Time-Series Fluctuation Characteristics of Segregation Carbon Element Distribution Along Casting Direction in High Carbon Continuous Casting Billet[J]. 金属学报, 2018, 54(6): 851-858.
[12] Huidong WU, Goro MIYAMOTO, Zhigang YANG, Chi ZHANG, Hao CHEN, Tadashi FURUHARA. Incomplete Bainite Transformation Accompanied with Cementite Precipitation in Fe-1.5(3.0)%Si-0.4%C Alloys[J]. 金属学报, 2018, 54(3): 367-376.
[13] Mingxiao GUO, Chen PAN, Zhenyao WANG, Wei HAN. A Study on the Initial Corrosion Behavior of Carbon Steel Exposed to a Simulated Coastal-Industrial Atmosphere[J]. 金属学报, 2018, 54(1): 65-75.
[14] Hui ZHANG, Yanxia DU, Wei LI, Minxu LU. Investigation on AC-Induced Corrosion Behavior and Product Film of X70 Steel in Aqueous Environment with Various Ions[J]. 金属学报, 2017, 53(8): 975-982.
[15] XU Qiufa, PANG Xiaolu, LIU Quanlin, GAO Kewei. CREVICE CORROSION OF LOW ALLOY STEEL AND CARBON STEEL IN THE SIMULATED GROUNDWATER AT 90 ℃[J]. 金属学报, 2014, 50(6): 659-666.
No Suggested Reading articles found!