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Acta Metall Sin  2017, Vol. 53 Issue (8): 975-982    DOI: 10.11900/0412.1961.2016.00566
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Investigation on AC-Induced Corrosion Behavior and Product Film of X70 Steel in Aqueous Environment with Various Ions
Hui ZHANG, Yanxia DU(), Wei LI, Minxu LU
Corrosion and Protection Center, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
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Hui ZHANG, Yanxia DU, Wei LI, Minxu LU. Investigation on AC-Induced Corrosion Behavior and Product Film of X70 Steel in Aqueous Environment with Various Ions. Acta Metall Sin, 2017, 53(8): 975-982.

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Abstract  

During the past decades, more buried oil or gas pipeline failures have been attributed to alternating current (AC) interference, and finally, those corrosion failures were investigated and the AC current density was identified as the critical influence parameter. There is general agreement on AC current density as a chief factor in determining metal wastage condition or assessing the AC corrosion risk for any type of soil in the presence of AC corrosion. Different degrees of AC corrosion may occurr if long distance pipelines pass through different kinds of soil environments, however, the effect of soil ions on pipeline steel without cathodic protection is still not well understood. Therefore, it is imperative to study the AC corrosion behaviors of pipeline steel in different soil environments. In the AC corrosion simulation experiment, by investigating the AC corrosion behaviors of X70 steel in 4 kinds of environmental media, the corrosion rates (Kd) were obtained, whose order was Kd (NaCl)>Kd Na2SO4)>Kd (CaCl2)>Kd (MgCl2). SEM, EDS and XRD were used to characterize and analyse the microscope morphologies, elements and phase compositions of the corrosion product films surfaces/cross-sections. Under the same AC current density, the reasons of differences of X70 steel's corrosion rate in different media were discussed. The presence of corrosive ions SO42- and Cl- would accelerate the corrosion rate, Na+ would not affect the formation of corrosion product film in NaCl and Na2SO4 solution media, however, the presence of Ca2+ and Mg2+ were helpful to form protective corrosion product films in MgCl2 and CaCl2 solution media.

Key words:  X70 steel      AC corrosion      environmental media      corrosion rate      corrosion product film     
Received:  19 December 2016     
ZTFLH:  TE988  
Fund: Supported by National Natural Science Foundation of China (No.51401017) and National Key Research and Development Program of China (Nos.2016YFC0802101 and 2016YFC0802103)

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https://www.ams.org.cn/EN/10.11900/0412.1961.2016.00566     OR     https://www.ams.org.cn/EN/Y2017/V53/I8/975

Fig.1  Diagram of experiment setup equivalent circuit (RE—reference electrode, WE—working electrode, CE—counter electrode)
Corrosion medium Mass concentration of solution Resistivity of corrosion medium
gL-1 Ωm
Na2SO4 solution with quartz sand 4 8.80
MgCl2 solution with quartz sand 4 6.08
CaCl2 solution with quartz sand 3 7.40
NaCl solution with quartz sand 3.28 5.90
Table 1  Parameters of simulation corrosion media
Fig.2  Corrosion rates of X70 steel under alternating current (AC) interference density of 300 A/m2 in 4 kinds of simulated media exposed for 168 h
Fig.3  XRD spectra of the corrosion product films on X70 under AC interference density of 300 A/m2 in simulated media of Na2SO4 (a), MgCl2 (b), CaCl2 (c) and NaCl (d)
Fig.4  Low (a, c, e, g) and high (b, d, f, h) magnified surface SEM images of corrosion product films on X70 steel in simulated media of Na2SO4 (a, b), MgCl2 (c, d), CaCl2 (e, f) and NaCl (g, h)
Fig.5  Low (a, c, e, g) and high (b, d, f, h) magnified cross-sectional SEM images of corrosion product films on X70 steel in simulated media of Na2SO4 (a, b), MgCl2 (c, d), CaCl2 (e, f) and NaCl (g, h)
Fig.6  EDS analyses of inner corrosion product films (a, c, e, g) and outer corrosion produt films (b, d, f, h) on X70 steel in simulated media of Na2SO4 (a, b), MgCl2 (c, d), CaCl2 (e, f) and NaCl (g, h)
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