Review on Research Progress of Steel and Iron Wear-Resistant Materials

doi:10.11900/0412.1961.2019.00370

Acta Metall Sin

2020, Vol. 56

Issue (4): 523-538 DOI: 10.11900/0412.1961.2019.00370

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Review on Research Progress of Steel and Iron Wear-Resistant Materials

WEI Shizhong¹(

),XU Liujie²(

)

^1.National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials, Henan University of Science and Technology, Luoyang 471003, China
^2.Engineering Research Center of Tribology & Materials Protection, Ministry of Education，Henan University of Science and Technology, Luoyang 471003, China

Cite this article:

WEI Shizhong, XU Liujie. Review on Research Progress of Steel and Iron Wear-Resistant Materials. Acta Metall Sin, 2020, 56(4): 523-538.

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Abstract

In this paper, the development history of iron and steel wear-resistant materials is introduced, and the composition, microstructure, wear property, antiwear mechanism and modification technology of three typical wear resistant materials, namely high manganese steel, high chromium cast iron and high vanadium high-speed steel, are mainly reviewed. The wear-resistant steel represented by high manganese steel relies on the matrix with high strength and toughness to resist wear, while the wear-resistant alloy represented by high chromium cast iron and high vanadium high-speed steel mainly relies on the wear-resistant phase with high hardness to resist wear. High vanadium high speed steel has better wear resistance than high chromium cast iron, which is related to VC characteristics with high hardness and good shape. It is proposed that high performance wear-resistant materials should have three elements: high strength and toughness matrix, multi-scale synergistic action of high quality wear-resistant phase with high hardness and good morphology, as well as good bonding interface between wear-resistant phase and matrix.

Key words: steel and iron wear-resistant material research progress prospect

Received: 04 November 2019

ZTFLH:

TG141

Fund: National Natural Science Foundation of China(51171060);Program for Changjiang Scholars and Innovative Research Team in University(IRT1234)

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https://www.ams.org.cn/EN/10.11900/0412.1961.2019.00370 OR https://www.ams.org.cn/EN/Y2020/V56/I4/523

Fig.1 Typical microstructures of high manganese steel of as-cast (a) and after solid solution treatment (b)^[11]

Fig.2 The orientation image map of 18Mn steel after compressed 70% at 900 ℃, holding time for 3 min and forced-air hardening (ND—normal direction)^[12]Color online(a) orientation image map of Kikuchi lines contrast(b) orientation image map of phase distribution (grey: austanite, red: ε-M; blue: α'-M)(c) orientation of austenite

Fig.3 Bright (a, d) and dark (b, e) field TEM images and electron diffraction patterns (c, f) of high manganese steel under the compression deformations of 30% (a~c) and 50% (d~f)^[19]

Fig.4 Typical microstructure of high chromium cast iron^[51](a) OM image of the microstructure (b) the morphology of the extractive primary carbides

Table 1 Test result under different abrasive wear conditions^[52]

Table 2 Effect of size effect of carbide on wear resistance of high Cr cast iron^[61]

Table 3 chemical compositions of high vanadium high speed steel^{[103,104,105,106,107,108]}

Fig.5 Liquids surface diagram of Fe-5Cr-V-C, Fe-15Cr-V-C and Fe-5Cr-5W-5Mo-V-C systems^[109]

Fig.6 A pseudo-binary phase diagram of (Fe-5Cr-5Mo-5W-2C)-V alloy system (T—temperature)^[111]

Fig.7 Pseudo-binary phase diagram of (Fe-5Cr-2Mo-9V)-C alloy system^[112]

Fig.8 The curves of iso-austenite (A_r—volume fraction of retained austenite, %)^[108]

Fig.9 Relationship of retained austenite content (a) and hardness(b) vs quenching and tempering temperatures using back-propagation (BP) neural network^[117]

Fig.10 SEM images of the worn cross-section under rolling sliding wear condition^[113](a) high chromium cast iron (Cr20) (b) high-vanadium high-speed steel (V10)

Fig.11 Microstructures of V10^[113](a) TEM image of VC (b) HRTEM of coherent interface of the VC/austenite matrix (d—interplanar spacing)

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