(Ti, Zr, Hf)--(Cu, Ni, Ag)--Al}多组元合金体系的机械驱动非晶化

金属学报

2004, Vol. 40

Issue (4): 421-428

论文

本期目录 | 过刊浏览

(Ti, Zr, Hf)--(Cu, Ni, Ag)--Al}多组元合金体系的机械驱动非晶化

张来昌沈智奇徐坚

中国科学院金属研究所沈阳材料科学国家(联合)实验室; 沈阳 110016

MECHANICALLY--DRIVEN AMORPHIZATION IN A (Ti, Zr, Hf)--(Cu, Ni, Ag)--Al MULTICOMPONENT ALLOY SYSTEM

HANG Laichang; SHEN Zhiqi; XU Jian

Shenyang National Laboratory for Materials Science; Institute of Metal Research; The Chinese Academy of Sciences; Shenyang 110016

引用本文:

张来昌; 沈智奇; 徐坚 . (Ti, Zr, Hf)--(Cu, Ni, Ag)--Al}多组元合金体系的机械驱动非晶化[J]. 金属学报, 2004, 40(4): 421-428 .
, , . MECHANICALLY--DRIVEN AMORPHIZATION IN A (Ti, Zr, Hf)--(Cu, Ni, Ag)--Al MULTICOMPONENT ALLOY SYSTEM[J]. Acta Metall Sin, 2004, 40(4): 421-428 .

全文: PDF(440 KB)

摘要: 研究了由前过渡族金属和后过渡族金属按照等原子比替代的(Ti0.33Zr0.33Hf0.33)50(Ni0.33Cu0.33Ag0.33)40Al10多组元合金在机械研磨作用下的非晶化转变, 并与由熔体急冷制备的同一成分玻璃态合金进行了对比. 两种途径获得的玻璃态相似. 在机械研磨的稳态产物中, 仍残留有少量尺寸小于30 nm的晶体相颗粒, 即非晶化转变未能完全实现. 机械研磨形成的非晶相表现有明确的玻璃转变和约80 K宽的过冷液态温度区间, 晶化过程分两步进行, 第一步晶化转变完成后, 剩余的非晶相亦具有玻璃态行为, 呈现另一玻璃转变及约100 K宽的过冷液态温度区间.

关键词 ：机械合金化, 非晶态合金, 过冷液体

Abstract：The glass formation under high--energy ball milling was investigated for a (Ti0.33Zr0.33Hf0.33)50(Ni0.33Cu0.33Ag0.33)40Al10 high--order alloy system. For comparison, the glassy ribbon with the same composition was prepared using melt--spinning (MS) method as well. Structural features of the samples were characterized using X--ray diffraction, ransmission electron microscopy and differential scanning calorimetry. Mechanical alloying (MA) results in a formation of glassy alloy similar to that obtained by MS. But, the glass formation is incomplete and a small amount of unreated crystallites smaller than 30 nm in size still remains in the final product. Like the melt--spun glass, the ball--milled glassy alloy also exhibits a distinct glass transition and a wide supercooled liquid region of about 80 K. Crystallization of the glassy alloy is a two--step p rocess, regardless of the synthesis routes. After the primary crystallization is completed, the remaining amorphous phase shows a detectable glass transition and a large supercooled liquid region of about 100 K.

Key words： mechanical alloying amorphous alloy supercooled liquid region

收稿日期: 2003-05-13

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