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金属学报  2008, Vol. 44 Issue (12): 1431-1438    
  论文 本期目录 | 过刊浏览 |
阴极极化条件下X70钢的缝隙腐蚀行为
陈旭;李晓刚;杜翠薇;梁平
北京科技大学腐蚀与防护中心
CREVICE CORROSION BEHAVIOR OF THE STEEL X70 UNDER CATHODIC POLARIZATION
CHEN Xu;LI Xiaogang;DU Cuiwei;LIANG Ping
School of Materials Science and Engineering; University of Science and Technology Beijing
引用本文:

陈旭 李晓刚 杜翠薇 梁平. 阴极极化条件下X70钢的缝隙腐蚀行为[J]. 金属学报, 2008, 44(12): 1431-1438.
, , , . CREVICE CORROSION BEHAVIOR OF THE STEEL X70 UNDER CATHODIC POLARIZATION[J]. Acta Metall Sin, 2008, 44(12): 1431-1438.

全文: PDF(972 KB)  
摘要: 

采用矩形缝隙装置, 测量了模拟剥离涂层下不同位置X70钢的电位、溶液pH值及氧含量随时间的变化曲线. 研究了外加阴极极化电位、涂层破损尺寸和缝隙厚度对X70钢在Na2SO4溶液中的缝隙腐蚀行为的影响. 结果表明, 缝隙内氧气迅速耗尽并使溶液pH值升高, 氧耗尽与外加阴极极化电位无关. 随着缝口阴极极化程度加大, 缝隙内各点电位负移, 有效保护距离增加. 溶液介质电位(IR)降集中在缝口. 极化程度过高会导致氢气的析出. 减小缝隙厚度和破损点尺寸使缝隙内极化程度降低.

关键词 X70管线钢阴极保护缝隙腐蚀电位分布氧含量pH值    
Abstract

A rectangle crevice assembly was used to measure the change of potential of steel X70, pH value and oxygen content in the crevice with time under the simulated disbonded coating. The effects of cathodic polarization potential, crevice thickness, holiday size on the crevice corrosion behavior of steel X70 in Na2SO4 solution were investigated. It is found that the dissolved oxygen was depleted within the crevice and thus shifted the solution to a more alkaline state. The oxygen depletion has no relation with the applied potential. The potential of the steel reaches the protected potential range, pH value of the solution increases and the protection distance becomes longer when the applied cathodic potential is more negative. Overprotection would result in the hydrogen evolution. The potential drop (IR) of the solution mainly occurs in the vicinity of the opening. The polarization degree decreases the thinner or smaller holiday crevice.

Key wordspipeline steel X70    cathodic protection    crevice corrosion    potential distribution    oxygen content    pH value
收稿日期: 2008-02-29     
ZTFLH: 

TG174.41

 
基金资助:

国家科技部基础条件平台建设项目No. 2005DKA10400

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