Please wait a minute...
金属学报  1985, Vol. 21 Issue (3): 115-122    
  论文 本期目录 | 过刊浏览 |
高饱和铁基非晶态合金的磁性和热稳定性
陈金昌;司红;沈保根;詹文山;赵见高
冶金工业部钢铁研究总院;冶金工业部钢铁研究总院;中国科学院物理研究所;中国科学院物理研究所;中国科学院物理研究所
MAGNETIC PROPERTY AND THERMOSTABILITY OF Fe-BASE AMORPHOUS ALLOYS WITH HIGH SATURATION MAGNETIZATION
CHEN Jinchang;SI Hong Central Iron and Steel Research Institute;Beijing;SHEN Baogen;ZHAN Wenshan;ZHAO Jiangao Institute of Physics;Academia Sinica;Beijing
引用本文:

陈金昌;司红;沈保根;詹文山;赵见高. 高饱和铁基非晶态合金的磁性和热稳定性[J]. 金属学报, 1985, 21(3): 115-122.
, , , , . MAGNETIC PROPERTY AND THERMOSTABILITY OF Fe-BASE AMORPHOUS ALLOYS WITH HIGH SATURATION MAGNETIZATION[J]. Acta Metall Sin, 1985, 21(3): 115-122.

全文: PDF(612 KB)  
摘要: 非晶态Fe_80B_(20),Fe_(17.84)B_(16.81)Si_(3.49)C_(1.36),Fe_(65.66)Co_(17.3)B_(15.84)Si_(1.2)和Fe_(6(?).92)Co_(17)B_(19.29)Si_(1.59)C_((?).(?))P_((?).(?))合金用单辊急冷法制备.测量了饱和磁化强度与温度的关系.得到0K时的原子磁矩(?)都在2.03—2.07μ_B之间.非晶态Fe_(80)B_(20)和Fe_(77.84)B_(16.81)Si_(3.49)C_((?).(?))合金的室温饱和磁化强度σ_s(R.T.)和Curie温度Tc相近,而含Co样品的σ_s(R.T.)和T_c分别高于Fe_(80)B_(20)约6%和13%.由热磁、电阻率、差热分析和X射线衍射的测量结果分析了样品的晶化转变.含Co样品的晶化温度T_(cr)与Fe_(80)B_(20)相近,而Fe_(77.84)B_(16.81)Si_(3.49)C_(1.86)的T_(cr)高于Fe_(80)B_(20)约80K.用化学键、T_(cr)与e/α的关系以及晶化过程的复杂性讨论了影响高饱和非晶态合金稳定性的因素.
Abstract:The ribbon samples of Fe-base amorphous alloys Fe_(80)B_(20)(A),Fe_(77.84)B_(16.81)Si_(3.49)C_(1.86)(B),Fe_(65.66)Co_(17.3)B_(15.84)Si_(1.2)(C)and Fe_(65.92)Co_(17)B_(13.29)Si_(1.59)C_(1.1)P_(1.1)(D)wereprepared by melt spinning.Their saturation magnetization at 12 KOe was deter-mined by extracting sample magnetometer and magnetic balance in the tempera-ture range of 1.5—300 K or 300—1200K respectively.It was obtained that themean magnetic moment per atom of transition metal,μ,is(2.03—2.07)μ_R forall samples.Both alloys A and B have similar room temperature saturation mag-netization,σ_S(R.T.),and Curie temperature,T_C,but alloys C and D are higherabout 6% and 10% than those of A respectively.As the experimental results ofthe thermomagnetization,resistivity,DSC and X-ray diffraction,the crystallinephases were also analyzed.The crystallization temperature,T_(cr),of alloys C andD is similar to that of alloy A,and T_(cr)of alloy B is higher about 80 K thanthat of A.The effect of chemical bond,T_(cr)vs e/a and the complexity crystal-line phases on the stability of the Fe-base amorphous alloys has been discussed.
收稿日期: 1985-03-18     
1 Hasegawa,R.;O' Handley,R.C.;Mendelsohn,L.I.,AIP Conf.Proc.,34(1976) ,298.
2 Fukamichi,K.;Kikuchi,M.;Arakawa,S.;Masumoto,T.,Solid State Commun.,23(1977) ,955.
3 Hasegawa,R.;Ray,R.,J.Appl.Phys.,49(1978) ,4174.
4 Luborsky,F.E.;Becker,J.J.;Walter,J.L.;Liebermann,H.H.;IEEE Trans.Magn.,MAG-15(1979) ,1146.
5 沈保根;郭慧群;章志英;詹文山,待发表.
6 Hatta,S.;Egami,T.,J.Appl.Phys.,50(1979) ,1589.
7 Luborsky,F.E.;Walter,J.L.,IEEE Trans.Magn.,MAG-16(1980) 572.
8 Roy,R.;Majumdar,A.K.,J.Magn.Magn.Mater.,25(1981) ,83.
9 Liebermann,H.H.;Graham,C.D.,IEEE Trans.Magn.,MAG-12(1976) ,921.
10 Kissinger,H.E.,Anal.Chem.,29(1957) ,1703.
11 Mizoguchi,T.;Yamauchi,K.;Miyajima,H.,“Amorphous Magnetism”Proc.of Int.Symp.on Amorphous Magnetism,17-18,Aug.1972,Detroit,Michigan,Eds.Hooper,H.O.;DeGraaf,A.M.,Plenum Press,New York-London,1973,p.325.
12 詹文山;沈保根;郭慧群;章志英;潘孝硕,第五届全国磁学会议报告,会议文集,I,1983,p.95.
13 Mangin,Ph.;Marchal,G.,J.Appl.Phys.,49(1978) ,1709.
14 Chien,C.L.;Hasegawa,R.,Amorphous Magnetism II,Eds.Levy,R.A.;Hasegawa,R.,Plenum Press New York,1977,p.287.
15 Handrich,K.,Phys.State Solid,32(1969) ,K55.
16 Naka,M.;Tomizawa,S.;Masumoto,T.;Watanabe,T.,Proc.2nd Int.Conf.on Rapidly Quenched Metals,MIT Press,1976,p.273.
17 陈金昌;沈保根,待发表.
No related articles found!